• Title/Summary/Keyword: 유기성 메탄

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Methane Gas Emission from an Artificial Reservoir under Asian Monsoon Climate Conditions, with a Focus on the Ebullition Pathway (아시아 몬순 기후지역에 위치한 대형 인공호에서 기포형태로의 메탄 (CH4) 가스 배출량)

  • Kim, Kiyong;Jung, Sungmin;Choi, Youngsoon;Peiffer, Stefan;Knorr, Klaus-Holger;Kim, Bomchul
    • Korean Journal of Ecology and Environment
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    • v.51 no.2
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    • pp.160-167
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    • 2018
  • The role played by reservoirs in the biogeochemical cycles of elements is a subject of ongoing debate. Recent research has revealed that reservoirs emit significant levels of greenhouse gases. To assess the importance of reservoirs in monsoon climate areas as a source of methane gas into the atmosphere, we investigated variations in organic carbon (OC) input into the reservoir, oxic state changes, and finally the amount of methane emitted (focusing on the ebullition pathway) in Lake Soyang, which is the largest reservoir in South Korea. Total organic carbon (TOC) concentrations were higher during summer after two years of heavy rainfall. The sedimentation rates of particulate organic carbon (POC) and particulate organic nitrogen (PON) were higher in the epilimnion and hypolimnion than the metalimnioin, indicating that autochthonous and allochthonous carbon made separate contributions to the TOC. During stratification, oxygen depletion occurred in the hypolimnion due to the decomposition of organic matter. Under these conditions, $H_2S$ and $CH_4$ can be released from sediment. The methane emissions from the reservoir were much higher than from other natural lakes. However, the temporal and spatial variations of methane ebullition were huge, and were clearly dependent on many factors. Therefore, more research via a well-organized field campaign is needed to investigate methane emissions.

Evaluation of Resource Recovery from Sorted Waste by MBT System (MBT시스템에 의해 선별(選別)된 생활폐기물(生活廢棄物)의 자원화(資源化) 평가(評價)에 관(關)한 연구(硏究))

  • Lee, Byung-Sun;Han, Sang-Kuk;Lee, Nam-Hoon;Kang, Jeong-Hee;Wie, June
    • Resources Recycling
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    • v.22 no.5
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    • pp.20-28
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    • 2013
  • This study was carried out to evaluate the possibility of resource recovery for municipal solid waste(MSW) that sorted by a MBT system. First, physical property of MSW was similar to wastes carried into Sudokown landfill site. However, moisture of MSW was little higher than that. As a result of BMP test using organic fraction of MSW(OFMSWs), approximately 60 ~ 80 mL $CH_4/g$-VS of methane was occurred. Compared to the other studies, the value of methane is lower. It seems to be caused that high ratio of vinyl/plastic in OFMSWs. The other BMP test using sample of MBT system located in Sudokwon landfill was conducted each physical properties. According to the result of experiment, food waste makes 193 mL $CH_4/g$-VS, and paper is 102 mL $CH_4/g$-VS. However, there was not methane production in vinyl and rubber. Additionally, others that can't sort no more show 30 m $CH_4L/g$-VS of methane production. From the result of experimental data OFMSWs has high fraction of vinyl, rubber and other substance that difficult for biodegradation. Therefore it is need to sort of them.

Effect of Sulfate and Heavy Metals on Methanogenic Activation of in the Anaerobic Digestion of Tannery Wastes (피혁폐수의 혐기성 소화시 황산염과 중금속이 메탄균 활성에 미치는 영향)

  • Shin, Hang Sik;Oh, Sae Eun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.1
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    • pp.13-21
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    • 1996
  • For treating tannery wastewater containing high sulfate and heavy metals, test was performed to assess their performance, competition between SRB (sulfate reducing bacteria) and MPB (methane producing bacteria), and the activity of MPB according to change of chromium concentrations. COD removal efficiency was above 70% at VLR (volumetric loading rate) of 2.0 gCOD/I.day and HRT (hydraulic retention time) of 18hrs at $35^{\circ}C$. In the competition between SRB and MPB, about 15% of the removed COD was utilized by SRB in the begining, but it became 43% at the end. It indicated that MPB was strongly suppressed by the occurrence of significant sulfate reduction since a large electron flow was uptaken by SRB. For the entire experiment, removal efficiencies of chromium concentration were more than 90%. Despite high removal efficiencies of chromium concentration, performance of reactor did not change significantly during the experimental periods. Expecially, chromium (III) is tannery wastewater is less toxic than chromium (VI).

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Influence of COD/Nitrate-N Ratio on Denitrification and Methanogenesis in Anaerobic Sludge (COD/Nitrate-N비가 혐기성 슬러지에서 탈질과 메탄화에 미치는 영향)

  • Park, Sang-Min;Jun, Hang-Bae;Choi, Chang-Ok;Lee, Joon-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.739-745
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    • 2005
  • Simultaneous denitrification and methanogenesis at various influent COD/Nitrate-N(below C/N) ratio was investigated with two different anaerobic sludges of which one was inoculated with glucose only and the other was inoculated with glucose and nitrate. Three different C/N ratios of 30, 20, and 10 were applied with each anaerobic sludge in serum bottles agitated in a rotary shaker to monitor the time related changes of amount of gas production and gas composition. Glucose was used as a single carbon source, which was adjusted to 1,000 mg/L as COD and potassium nitrate was used as a nitrogen source to adjust the each C/N ratio. COD removal by methanogenesis was dominant at higher C/N ratios, while COD removal by denitrification was dominant at lower C/N ratios. With the sludges cultured at C/N ratios below 10, SMA and SDNR rising different carbon substrates were investigated. The most efficient carbon substrate was acetate and the highest SMA and SDNR were 0.76 g COD/g VSS day with pure anaerobic sludge and 1.38 g ${NO_3}^--N/g$ VSS day with sludge cultured at C/N ratio of 5, respectively.

Anaerobic Acid and Methane Fermentation using Paper Wastes (폐지를 이용한 혐기성 산 발효 및 메탄발효 특성)

  • 조건형;김중곤;김성준;김시욱
    • KSBB Journal
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    • v.18 no.4
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    • pp.318-323
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    • 2003
  • This study was carried out to investigate the possibility of reusing newspaper or paperbox waste by methane fermentation. When 15 g of newspaper and box wastes were digested separately for 24 days by batch fermentation, the amount of total organic acids produced were 2461 and 4978 mg/L, respectively. The tCOD removal rates were found to be 60.9 and 62.4%, respectively. In addition, the removal efficiencies of total solid were 34.8 and 33.4%, and those of volatile solid were 40.0 and 39.2%, respectively. During this period, the amounts of biogas produced were 6.95 and 6.43 L. In a semicontinuous reaction, tCOD removal efficiencies for newspaper and box wastes were 64.7 and 65.0%, respectively, after 14 days of digestion. After 25 days, which were needed to stabilize the methane fermentation, the amounts of biogas produced daily were 0.31 and 0.30 L/g.dry wt, respectively. Methane contents were 57.3 and 56.2%, respectively, and the pHs in the anaerobic acidogenic and methanogenic fermenters were 5.0 and 7.5, respectively.

Biochemical Studios on the Chemical Components of Korean Ginseng:(I) Effects of Components of Ginseng on the Activity of Aminoacyl-tRNA Synthetase (한국 인삼 성분들에 관한 생화학적 연구 (1) 인삼 성분들이 아미노아실-tRNA합성 효소의 활동성에 미치는 영향)

  • 장세희;박인원
    • Journal of Ginseng Research
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    • v.1 no.1
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    • pp.19-24
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    • 1976
  • Ginseng extracts were frnctionelod into several fractions with carious organic solvents, and the effects of these fractions on the activity of aminoacyl-tRHA synthetase was examined. Fractions which showed positive effect on the activity of the aminoacyl-tRNA synthetase were obtained both from white ginseng and red ginseng. The total methanol extract of whit ginseng and the ether extract from the total methanol extract of red ginseng gave Positive results. Therefore it may be Presumed that the Positive components have rather nonpolar nature.

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Decomposition Characteristics of Methane and VOC Using Electron Beam (전자빔을 이용한 메탄과 VOC의 분해특성)

  • Kim, Jo-Cheon;Kim, Gi-Jun;Lee, Gi-Wan;Jeon, Jin;Lee, Jae-Hyung;Han, Beom-Su;Lim, Su-Gil
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.289-290
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    • 2001
  • 비메탄계 휘발성 유기화합물(Non-Methane Volatile Organic Compounds; NMVOCs)은 많은 부분이 용제를 사용하는 공정에서 발생되어 광화학적 산화물 형성 등의 대기질 악화를 초래시키는 것으로 알려져 있다. 반면에 메탄가스는 지구온난화의 원인물질로 환경에 많은 영향을 미치는 것으로 알려져 있고, 국내의 쓰레기 매립지에서 발생되는 양은 년간 112만톤으로 추정되어 메탄의 자원화나 처리에 대한 연구가 매우 필요한 실정이다. (중략)

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Two-stage Biological Hydrogen Production form Organic Wastes and Waste-waters and Its Integrated System (유기성 폐기물 및 폐수로부터 2단계 생물학적 수소생산 및 통합화 시스템)

  • Kim, Mi-Sun;Yoon, Y.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.1
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    • pp.52-64
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    • 2002
  • 유기성 폐기물을 이용하여 생물학적 수소생산 통합화 시스템 연구를 수행하였다. 통합화 시스템은 유기성폐기물의 전처리, 2단계 혐기발효 및 광합성 배양으로 구성된 생물학적 수소생산 공정, 초임계수 가스화 공정, 생산된 가스의 저장, 분리 및 연료전지를 이용한 전력 생산으로 구성되었다. 실험에 사용된 유기성 폐자원은 식품공장 폐수, 과일폐기물, 하수슬러지이며, 전처리는 폐기물에 따라 열처리 및 물리적 처리를 하였으며, 전처리된 시료는 생물학적 수소생산 공정에 직접 적용되었다. Clostridium butyricum 및 메탄 생성조에서 발생하는 하수슬러지중의 미생물 복합체는 수소생산 혐기 발효공정에 사용되었으며, 광합성 수소생산 미생물인 홍색 비유황 세균은 광합성 배양에 사용되었다. 생물학적 공정에서 발생하는 미생물 슬러지는 초임계수 가스화 공정으로 수소를 발생하였으며, 슬러지 중의 COD를 저하시켰다. 생물학적 공정 및 초임계수 가스화 공정에서 발생하는 수소는 가스탱크에 가입상태로 저장한 후, 95%순도로 분리하였으며, 정제된 수소는 연료전지에 연결하여 전력 생산을 하였다.

Performance Evaluation of ABR and ASBR for Anaerobic Methane Fermentation (ABR과 ASBR 형태에 따른 혐기성 메탄 발효 운전 성능 평가)

  • Lee, Chae-Young;Lee, Se-Wook
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.49-54
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    • 2011
  • This study was conducted to evaluate the performance of methane fermentation from effluent of hydrogen fermentation reactor in anaerobic baffled reactor (ABR) and anaerobic sequencing batch reactor (ASBR). Two reactors were operated at organic loading rate of $1.0kg\;COD/m^3{\cdot}d$ and hydraulic retention time (HRT) of 20 day. Methane production rates of ABR and ASBR for start-up periods were 0.04 L/L/d and 0.19 L/L/d, respectively, whereas maximum methane production rates of ABR and ASBR were 0.25 L/L/d and 0.31 L/L/d, respectively. Removal rates of chemical oxygen demand (COD) in ABR and ASBR for start-up periods were 89% and 92%, respectively. After startup periods, removal rates of COD and volatile solids (VS) in ABR and ASBR were maintained over 90%. The specific methanogenic activity (SMA) increased as microorganism acclimated to the substrate.

Inhibitory Effects of Copper on the Anaerobic Degradation of Propionate (프로피온산의 혐기성 분해시 구리의 저해 효과)

  • Shin, Hang-sik;Lee, Chae-young
    • Journal of the Korea Organic Resources Recycling Association
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    • v.7 no.2
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    • pp.25-34
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    • 1999
  • The effects of copper on the anaerobic degradation of propionate were studied using anaerobic batch reactors. The apparent inhibitory effects of copper on the anaerobic degradation of propionate could be observed from behaviors of intermediates, ultimate methane yield(UMY) and specific methanogenic activity(SMA) There was little inhibition at the concentration of $2.5mg\;Cu^{2+}/L$. Beyond this concentration, the inhibitory effects increased with increasing dose of coppers. The 50% inhibition of UMY and SMA occurred at copper dosage of 33.8 and $24.1mg\;Cu^{2+}/gVSS$, respectively. The inhibitory effect based on the UMY was gradually reduced with the operation time dueprobably to the acclimation of microorganisms and/or binding of the added copper by ligands(and possibly ion exchange sites)contained on the cell membrane and extracellular polymer matrix whereas it based on the SMA might exclude the this phenomena. Therefore, the methodology for interpretation of inhibition data based on the SMA was more accurated than the UMY. There was no inhibitory effect in batch reactors supplemented with sulfate due to an antagonistic action of the sulfate reducing bacteria. Propionate degradation was initially retarded for copper inhibited samples but it gradually degraded afterward. Based on the mass removal considering take into account the propionate to acetate conversion, propionate degradation may appeal more affected than acetate. This result revealed that the hydrogenotrophic methanogens were the most affected by copper.

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