• Title/Summary/Keyword: 유기복합

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Characterization of electrochemical behaviour for supercapacitor based on porous activated carbon composite with various contents of metal-organic framework(MOF) (금속유기골격체(Metal-organic Framework)의 함량에 따른 다공성 활성탄소 복합재료 기반 슈퍼커패시터의 전기화학적 거동 분석)

  • Jeong, Hyeon Taek;Kim, Yong Ryeol
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.5
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    • pp.1200-1207
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    • 2020
  • We have fabricated the supercapacitor composed of porous activated carbon, metal-organic framework (MOF) with polymer based solid state electrolyte as a "ion gel" and characterized its electrochemical behaviour as a function of the MOF contents. The electrochemical properties of the supercapacitor were analyzed via cyclic voltammetry(CV), electrochemical impedance spectroscopy(EIS) and galvanostatic charge/discharge test. As a results, the supercapacitor based on porous activated carbon/MOF composite showed the highest capacitance value at 0.5 wt% of MOF contents and decreased capacitance with increase MOF contents over the 0.5 wt%. Consequently, the porous activated carbon/MOF composite based supercapacitor is applicable to various aspect for energy storage device.

Synthesis and Properties of High Impact Polystyrene Nanocomposites Based upon Organoclay Having Reactive Group (반응성 유기화 점토를 이용한 내충격성 폴리스티렌 나노복합재료의 합성 및 물성)

  • Hwang, Sung-Jung;Chung, Dae-Won;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.347-352
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    • 2008
  • High impact polystyrene (HIPS) nanocomposites with organically modified montmorillonite (organoclay) via in situ polymerization were synthesized, and the effects of organoclay incorporation on material properties were investigated. Organoclays having a reactive group, vinylbenzyltrimethyl clay (VBC) and octadecylvinylbenzyldimethyl clay (ODVC), were prepared by the ion-exchange reactions of sodium montmorillonite with vinylbenzyltrimethyl ammonium chloride (VBTMAC) and octadecylvinylbenzyldimethyl ammonium bromide (ODVBDAB), respectively, and a commercial organoclay, $Cloisite^{(R)}$ 10A(C10A), was used for comparison. It was confirmed that the X-ray diffraction (XRD) peak of the nanocomposites prepared by ODVC disappeared, which indicates the exfoliation of silicate layers. On the contrary, the XRD peak of the nanocomposites prepared by C10A shifted to lower angle, indicative of the intercalation of polymer chains into silicate layers. Rheological properties such as storage modulus and complex viscosity increased with increasing organoclay.

A Study on the Degradation of Isopropyl Alcohol with $TiO_2$-coated Plastic Optic Fibers (광촉매 코팅 광섬유의 IPA 분해 특성 연구)

  • Yu Dong-Si;Joo Hyun-Ku;Ha Jin-Wook
    • Proceedings of the KAIS Fall Conference
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    • 2005.05a
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    • pp.283-286
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    • 2005
  • 본 연구에서는 광촉매 $TiO_2$/p-25를 POF에 코팅하여 IPA 분해 활성을 고찰한 결과, 코팅 시 용매의 조건은 에탄올에서 IPA의 분해효율이 가장 우수하였고 무기바인더(KR-400), 유기바인더(A-9540) 및 무$\cdot$유기 복합바인더(GPTMS, TMOS)중에서 유기 바인더인 A-9540을 사용했을 때 효율이 가장 우수한 것으로 나왔다. 유기 바인더는 광분해반응에 의하여 바인더 자체가 분해되고 무기 바인더는 부착성이 떨어졌다. 유$\cdot$무기 복합 바인더 중에서 광분해 효율이 뛰어난 TMOS를 바인더로 선정하여 TMOS/P-25의 비율을 0.05부터 1로 바꾸어 광분해 실험을 수행한 결과, 바인더로써 TMOS의 첨가는 IPA분해 효율을 낮게 하였다.

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알루미나 ($Al_2O_3$) 나노입자-PVP 나노복합 절연체층을 이용한 연성 유기박막 트랜지스터(OTFT) 제작및 전기적 특성 연구

  • No, Hwa-Yeong;Seol, Yeong-Guk;Kim, Seon-Il;Lee, Nae-Eung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.04a
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    • pp.74-75
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    • 2007
  • 최근에는 휴대성과 유연성이 뛰어난 다목적 디스플레이의 연구가 활발히 진행되고 있는데, 이러한 기술의 핵심 능동소자로서 저비용, 대면적의 응용, 휘어짐 등의 장점을 가지는 유기박막 트랜지스터(Organic Thin Film Transistors)가 널리 연구되고 있다. 본 연구에서는 기존에 문제시 되는 유기 절연체의 저유전상수와 높은 누설전류를 보완하기 위하여 나노복합 (nanocomposite) 게이트 절연체에 대한 연구를 수행하였다. 기존의 유기물 절연체가 가지는 문제점인 높은 누설전류 특성을 보완하기 위하여 높은 전기적 절연성과 고유전상수를 가지는 알루미나 ($Al_2O_3$)의 나노입자와 유기절연체의 나노복합체 박막을 형성시키고 이를 적용한 결과 게이트 누설전류를 억제시키어 소자의 특성을 향상시킬 수 있었다.

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Effect of Dietary Organic Acid Mixture on Growth Performance, Organ Weight, Blood Immunological Parameter and Intestinal Villi Morphology in Broilers (유기산 복합물 급여가 육계 생산성, 장기무게, 혈액내 면역적 성상 및 장내 융모 형태에 미치는 영향)

  • Jang, H.D.;Yoo, J.S.;Kim, H.J.;Shin, S.O.;Hwang, Y.;Zhou, T.X.;Chen, Y.J.;Cho, J.H.;Kim, I.H.
    • Korean Journal of Poultry Science
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    • v.35 no.1
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    • pp.57-62
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    • 2008
  • The study was conducted to evaluate the effects of dietary organic acid mixture(lactic acid 12%, formic acid 9%, citric acid 5%, butyric acid 5% and phosphoric acid 6%) on growth performance, organ weight, blood immunological parameter and intestinal villi morphology in broilers. Dietary treatments included 1) CON (basal diet), 2) OA1 (basal diet + 0.1% organic acid mixture) and 3) OA2 (basal diet + 0.2% organic acid mixture). Four hundred eighty hatched Arbor Acre broiler chickens were housed in 24 pens of 20 birds each. Eight replicate pens were allotted into each treatment by completely randomized design. Daily weight gain, feed intake and feed/gain were not significantly different among the treatments. In organ weight, that of gizzard was significantly heavier in OA2 than CON (Linear effect = 0.034). However, those of spleen and intestine were not significantly different among the treatments. Blood immunological parameters such as RBC, WBC and lymphocyte were not significantly difference. In intestinal villi morphology, villi length was increased in OA1 compared to CON (Quadratic effect = 0.050). In conclusion, 0.2% organic acid mixture was effective to improve gizzard weight of broilers.

Difference of Agricultural Characteristics and Quality with Fertilizer Types in Wheat Cultivation (밑거름 종류에 따른 밀의 농업적 형질 및 품질 차이)

  • Kim, Hag-Sin;Kim, Young-Jin;Kim, Kyong-Hyun;Park, Hyung-Ho;Kang, Chon-Sik;Kim, Kyung-Ho;Hyun, Jong-Nae;Kim, Kee-Jong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.1
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    • pp.15-19
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    • 2013
  • This study was carried out to establish the optimum organic fertilization and microbial compost on wheat cultivation in order to reduce the use of chemical fertilizers and improve the quality of wheat. The tests resulted in a yield of organic fertilization of 2~6% lower than the yield of standard 4.16 Ton/ha (a yield more than that of microbial compost). The recession was not statistically significant. The trial which involved organic fertilizer that had a yield of 800 kg/ha and microbial compost which had a yield of 2,000 kg/ha resulted in 96% yield of standard trial. The quality of flour in the manure was 50% less during the trial and was not making a good result. In protein content and SDS-sedimentation volume, standard trial had the highest yield in test trial (standard > miccompost > organic fertilization). However, Ash content was not statistically significant.

Isolation and Concentration of Organic Components from a Complex Matrix into Three Fractions of Different Volatilities (복합 유기혼합물체로부터 휘발성이 서로 다른 세 유기화합물 그룹의 분리 농축방법의 연구)

  • Kyoung Rae Kim
    • Journal of the Korean Chemical Society
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    • v.25 no.1
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    • pp.30-37
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    • 1981
  • A simple micro-sampling system is described which facilitates isolation and concentration of complex organic constituents into three fractions of different volatilities. The method involves the headspace trapping of very volatile components from a complex matrix onto a porous polymer, Tenax GC, followed by the solvent elution of the matrix and the subsequent fractions of the eluate into volatile and less-volatile fractions. The headspace and the volatile fractions are then analyzed by high-resolution capillary gas chromatography. The less-volatile fraction is analyzed by high-performance liquid chromatography. Experimental details and the results obtained using tobacco leaves as a complex organic matrix are presented.

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Engineering Properties of HPFRCC Including Both Organic and Inoranic Fibers (유·무기 섬유를 복합사용한 HPFRCC의 공학적 특성)

  • Lee, Jong Tae;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.6
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    • pp.615-620
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    • 2015
  • The high performance fiber reinforced cementitious composite (HPFRCC) controls the cracking development of the structure by inducing micro-cracking and strain hardening behavior after the initial cracking under the tensile conditions. Although, in Korea, the research about manufacturing the single-fiber reinforced cementitious composite or the mechanical properties of hardened status has been conducted, the research to apply the HPFRCC with multi-fiber is not sufficient. Hence, in this research, considering the workability and economic aspect for practical applications, the engineering properties of HPFRCC with combined long steel fiber (SL) and long organic fiber (OL) are evaluated such as workability and strength. As a result of evaluating the engineering properties of HPFRCC, the most favorable performance was obtained when the mixture contained 1.5% of combined SL and OL.

Impact Properties of Organic Fiber Reinforced Thermoplastic Composites (유기섬유강화 열가소성고분자 복합재료의 충격특성)

  • Im, Seung-Soon;Lee, Seung-Bae;Lee, Yong-Moo;Choi, Hyeong-Ki
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.424-432
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    • 1996
  • The fiber reinforced thermoplastic composites(FRTP) were prepared with polypropylene fiber(PPF) as matrix and vinylon(VF), Aramid(KF) or nylon fiber(PAF) as reinforcing materials using the integrated fiber mixing apparatus. The composite sheets were prepared by compression molding and their impact and morphological properties were characterized. VF/PP system showed the maximum value in Izod impact strength, while KF/PP system showed the maximum value in high rate impact properties. Ductility Index(DI) order was VF/PP>KF/PP>PAF/PP. A maximum DI for VF/PP, 2.43, was obtained when the weight fraction of VF was 20%. The optimum amount of the reinforcing organic fiber was found to be 20~30%. As a result, it is concluded that VF/PP system has better interfacial adhesion properties than either KF/PP or PAF/PP.

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가교 키토산 복합막을 이용한 알코올 수용액의 농축

  • 남상용;이병렬;우동진;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.36-37
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    • 1995
  • 투과증발법은 기존의 증류법에 의해 분리되기 어려운 혼합물(공비혼합물이나 끓는점이 비슷한 혼합물)이외에 열에 민감한 생성물의 분리, 과익쥬스의 농축, 불순물 찌꺼기의 제거, 정량 검출을 위한 유기 오염물질의 농축 등에 이용되었으며 특히 물과 에탄올의 공비혼합물의 분리와 물로부터 희박 유기물질을 회수하는데 행해져 왔다. 본 연구에서 사용된 키토산은 친수성기들을 가지고 있기 때문에 물과 알코올의 분리에서 물을 선택적으로 투과시켜 효과적인 투과증발막으로 사용될 수 있으며 투과속도를 높이기 위해서 활성층이 매우 얇은 복합막을 제조하였다. 또한 키토산 복합막을 다양한 가교제 (glutaraldehyde, glyoxal, terephthalaldehyde, 황산등)로 가교한 막들을 열처리를 하거나 키토산과 PVA를 블렌드하여 제조한 키토산/PVA 블렌드 복합막을 이용하여 에탄올/물, IPA/물 혼합용액에서의 탈수 실험을 실시하여 이에 따른 투과성능의 영향을 살펴보았다.

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