• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.07b
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• pp.1037-1041
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• 2004

공액계 유기가교로서 butadiene을 사용한 이핵 유기금속착체를 합성하였고, 합성된 유기금속착체 화합물에 대한 구조적 특징과 두 금속간의 전기화학적 특성에 관한 연구를 수행하였다. $[Cp*Fe(CO)_2]_2-({\mu}-CH=CH-CH=CH)$ 착체는 $Cp*(CO)_2$FeK와 cis-3,4-dichlorocyclobutene과의 반응으로 합성하였고, 이 착체에 결합된 CO기는 UV 광반응하에서 $PPh_3$로 치환시켜 $[Cp*Fe(CO(PPh)_3]_2-({\mu}-CH=CH-CH=CH)$를 합성하였다. 합성된 착체에 대한 전기화학적 특성을 파악하기 위해 CV 실험결과, 전위차 ${\Delta}E^{\circ}=0.575{\sim}0.605$ V이고 $K_c$값은 $109{\sim}1010$으로 매우 큰 값을 얻음으로서 두 금속간의 상호작용이 탄화수소사슬을 통해 활발하게 이루어지고 있음을 알수가 있었다.

• Journal of Food Hygiene and Safety
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• v.1 no.2
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• pp.163-169
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• 1986

소, 돼지, 닭 및 염소의 근육, 지방조직 및 내장부위에서 11가지 유기염소계 잔류농약을 분석하여 다음과 같은 결과를 얻었다. 1. 육류시료 모두에서 검출된 유기염소계의 잔류량은 $\alpha$-BHC, $eta$-BHC, pp'-DDE, Heptachlor epoxide, ${\gamma}$-BHC순으로 검출되었고, Heptachlor, pp'-DDE 및 pp'-DDD는 극미량 내지는 흔적 정도 검출되었고 Drins류는 검출되지 않았다. 2. Total BHC 잔류량의 범위는 소의 경우 0.389ppb~1.111ppb로 평균 0.713ppb였고, 돼지는 0.139ppb~0.150ppb로 평균 0.631ppb였으며 닭은 0.312ppb~0.80ppb로서 평균 0.517ppb였다. 그리고 염소의 경우에는 0.238ppb~1.134ppb로써 평균 0.586ppb의 수준이었다. 3. 육류별 잔류량은 소, 돼지, 염소, 닭의 순서이고 부위별 잔류량은 지방조직이 가장 많았고 그 다음이 근육, 그외 부위별 잔류량의 차이는 거의 없었다.

• Journal of Life Science
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• v.27 no.11
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• pp.1381-1392
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• 2017

This review described solvent-tolerant lipases and their potential industrial, biotechnological and environmental impacts. Although organic solvent-tolerant lipase was first reported in organic solvent-tolerant bacterium, many organic solvent-tolerant lipases are in not only solvent-tolerant bacteria but also solvent-intolerant bacterial and fungal strains, such as the well-known Bacillus, Pseudomonas, Streptomyces and Aspergillus strains. As these lipases are not easily inactivated in organic solvents, there is no need to immobilize them in order to prevent an enzyme inactivation by solvents. Therefore, the solvent-tolerant lipases have the potential to be used in many biotechnological and biotransformation processes. With the solvent-tolerant lipases, a large number insoluble substrates become soluble, various chemical reactions that are initially impossible in water systems become practical, synthesis reactions (instead of hydrolysis) are possible, side reactions caused by water are suppressed, and the possibility of chemoselective, regioselective and enantioselective transformations in solvent and non-aqueous systems is increased. Furthermore, the recovery and reuse of enzymes is possible without immobilization, and the stabilities of the lipases improve in solvent and non-aqueous systems. Therefore, lipases with organic-solvent tolerances have attracted much attention in regards to applying them as biocatalysts to biotransformation processes using solvent and non-aqueous systems.

• Proceedings of the Membrane Society of Korea Conference
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• 1992.04a
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• pp.33-34
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• 1992

현재 이용되는 막들은 대부분 유기계 혹은 고분자계로 열적인 안정성이 적고 내약품성이 낮다. 그래서 본 실험에서는 내열, 내약품성이 우수한 무기기와 유기기를 조합하여 복합막을 제조하려 시도하였다. 이때 유-무기 복합상의 반응은 졸-겔 법을 이용하였는데 이 졸-겔 법이란 출발물질인 금속알콕사이드를 용액상에서 가수분해하여 졸을 얻고 축합반응을 통해 겔을 형성하여 무기고분자를 제조하거나 소결하여 필름, 분말, 섬유상, 괴상 등의 다양한 형태로 산화물을 제조하는 공정이다. 이는 분자적 차원에서 혼합하여 반응하므로 산화물간의 반응보다 반응성의 입장에서 훨씬 유리하며 또한 용액상에서 저온반응 하므로 기존에는 유기-무기기를 조합하는데 존재하는 문제를 해결 할 수 있다.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.504-507
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• 2010

본 논문에서는 저온용 오스테나이트계 스테인리스강(ASS)의 온도 및 변형률 속도의 영향을 고려한 통합 구성 방정식 및 손상 모델을 제안하였다. 저온 영역에서, 304L ASS의 온도 및 변형률 속도별 인장 실험을 시행하였다. 그 결과, 변형 유기 마르텐사이트 상변태에 의해 상변태 유기 소성(TRIP)이 저온에서 현저히 나타났으며 온도 및 변형률 속도의 영향이 지대하였다. 실험 결과를 바탕으로 ASS의 저온 거동 및 특성을 규명하여 수치 모델에 반영하였다. 저온에서 일어나는 2차 경화 현상을 표현하기 위해, Bodner/Partom 점소성 구성 방정식을 수정하고 Tomita/Iwamoto 변형 유기 상변태 모델을 구성 방정식에 적용시켰다. 저온 연성 파단 현상을 표현하기 위해, Bodner/Chan 손상모델을 수정하여 접목시켰다. 제안된 모델을 유한요소 프로그램에 탑재시키고, 온도 및 변형률 속도 의존 재료 정수를 결정하였다. 저온 영역에서, 온도 및 변형률 속도별 재료 거동을 시뮬레이션하고 이를 실험 결과와 비교 및 검증하였다.

• Tribology and Lubricants
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• v.28 no.3
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• pp.117-123
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• 2012

Tribological properties of hybrid type friction materials were studied. Hybrid friction materials were produced by combining non-steel(NS) and low-steel(LS) type friction materials. The emphasis of the investigation was given to possible synergistic effects from the two different friction materials, in terms of friction stability at high temperatures and the amplitude of friction oscillation, also known as stick-slip at low sliding speeds. The high temperature friction test results showed that the friction effectiveness of the hybrid friction material was well sustained compared to LS and NS friction materials. Wear resistance of the hybrid type was similar to LS friction materials. Examination of the rubbing surfaces after tests revealed that the friction characteristics of the hybrid friction material were attributed to the wear debris produced from low-steel friction materials, which were migrated to the surface of the non-steel friction material, forming new contact plateaus. The stick-slip amplitude and its frequency were pronounced when non-steel friction material was tested, while hybrid and low-steel types showed relatively small stick-slip amplitudes. These results suggest possible improvement of tribological properties by designing a hybrid composite of low-steel and non-steel friction materials.

• Magazine of the Korea Concrete Institute
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• v.27 no.1
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• pp.41-44
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• 2015

• Journal of the Korea Institute of Building Construction
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• v.17 no.2
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• pp.157-166
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• 2017

In general, carbonation and chlorine ions are the most harmful causes of deterioration of concrete structures. Recently, a method has been developed to control the corrosion of rebar in concrete containing chloride by impregnating a Surface coating material with a inhibitor. In this study, accelerated carbonation and differential thermogravimetric analysis (TG-DTA) and CASS tests were carried out to evaluate the characteristics of Surface coatings containing Organic Corrosion inhibitors which are excellent in corrosion inhibition and fix degradation causes $CO_2$ and $Cl^-$. As a result of the experiment, TG-DTA analysis and accelerated carbonation showed that $CO_2$ was directly reacted with amine derivative in concrete by the incorporation of Organic Corrosion inhibitor. In other words, $CO_2$ was immobilized and carbonation inhibition effect was confirmed. In addition, in the CASS test, the specimen coated with the Surface coating material containing the Organic Corrosion inhibitor with $Cl^-$ fixing property showed no corrosion until the 28th day and had excellent performance in preventing corrosion of a rebar by the chloride ion.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.6 no.5
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• pp.418-422
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• 2005

The degradation of IPA according to coating conditions was examined by $TiO_{2}$/p-25-coated aluminium metal plate. Inorganic(KR-400), inorganic$\cdot$ organic hybrid(TMOS) and organic(A-9540) resins were used as binder $TiO_{2}$ coated surface of aluminum metal plate was clear with all binders, and the adhesion of binders was good except inorganic binder. The activity for IPA degradation appeared to range in order A-9540>TMOS>KR-400. The optimum activity was obtained when the ratio of TMOS and P-25 was 1.6:10, and when the ratio of A-9540 and P-25 was 1.0:6.0, respectly.

• Journal of the Korean GEO-environmental Society
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• v.14 no.8
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• pp.5-9
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• 2013

In this study, it was examined a strength characteristic of organic acid material that is eco-friendly and low energy as a soil improving material. The object of this study is to analysis of strength changes with observing the clay mixed organic acid material through the unconfined compression strength test and triaxial compression test during 28 days. As a result of the tests, the strength of clay mixed organic acid material is increased when the more ages are prolonged, the more organic acid material mixture ratio growed. Therefore, in grasping the strength improvement effects of clay by organic acid material mixing, it confirmed that organic acid material as soil improving material is effective through unconfined compression strength test and triaxial compression test. Through this test, the definite strength increase is confirmed according to the mixture of the organic acid material and the possibility of soil improvement is also confirmed based on this result. From now on, detailed examination and field test will help closely to definite strength characteristics.