• Title/Summary/Keyword: 원환

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Synthesis of a Platinum-Pincer Complex and Application to Catalytic Silylcyanation (백금 핀서 화합물의 합성 및 Silylcyanation 촉매반응에 대한 응용)

  • Kim, Yun Tae;Yoon, Myeong Sik
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.366-370
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    • 2016
  • A platinum(II) pincer complex composed of two six-membered fused metallacycles was directly synthesized using 1,3-bis(2-pyridyloxy)benzene and $K_2PtCl_4$. The structure of the complex was elucidated via NMR and X-ray crystallography analysis. The stable complex was formed due to the six-membered fused cycle structure around the Pt(II) center which reduced the bond angle strain. The complex was applied to the silylcyanation reaction of aldehydes and imines and showed an efficient catalytic activity with 99% yield.

Ultimate Strength Analysis of Ring-stiffened Cylinders Using Commercial Softwares (상용소프트웨어를 이용한 원환보강 원통의 최종강도 해석(I))

  • 박치모;이승훈
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.10a
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    • pp.271-274
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    • 2000
  • Despite the increasing necessity of accurate estimation of ring-stiffened cylinders' ultimate strength, the complex structural behavior of cylinders has made their design mainly depend on empirical formulas mostly based on insufficient test data rather than theoretical background. This paper has developed the imperfection method which enables the ultimate strength analysis of buckling sensitive structures by combining two general functions of common commercial finite element softwares, linear elastic buckling analysis and nonlinear stress analysis. Developed method was applied to two of the world most renowned commercial softwares, MSC/NASTRAN and ABAQUS, for the analysis of ring-stiffened cylinders and unexpectedly big difference in their analysis results was found. This tells that many widely used commercial softwares has their different strong points and week points and the choice of commercial software should be cautiously made after thorough inspection. This paper ends with some useful information about which of the aforementioned two softwares is more appropriate respectively for linear elastic buckling analysis and ultimate strength analysis of ring-stiffened cylinders.

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Ultimate Strength Analysis of Ring-stiffened Cylinders Using Commercial Softwares(II) (상용소프트웨어를 이용한 원환보강 원통의 최종강도 해석(II))

  • 박치모;이승훈
    • Journal of Ocean Engineering and Technology
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    • v.16 no.1
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    • pp.36-40
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    • 2002
  • Despite the frequent use of ring-stiffened cylinders as a submarine pressure hull or members of various types of offshore structure, their ultimate strength analysis methods have not been well established because of their complex structural characteristics. This paper has established the method how to use commercial softwares based on the finite element method to implement the ultimate strength analysis of ring-stiffened cylinders covering both types of initial imperfection, i.e. initial deformation and initial stress by combining two separately offered functions of common commercial finite element softwares, linear elastic buckling analysis and nonlinear stress analysis. Developed method was applied to one of the world-widely used commercial softwares. ABAQUS for the analysis of ring stiffened cylinders. This paper ends with some useful information about the imperfection sensitivity of ultimate strength ring stiffened cylinders.

Three-Dimensional Analysis of Chaotic Mixing in Chaos Single-Screw Extruder (카오스 단축 압출기의 3차원 카오스 혼합해석)

  • 권태헌
    • The Korean Journal of Rheology
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    • v.10 no.3
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    • pp.121-130
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    • 1998
  • 본 연구에서는 카오스 스크류에 대해 비선형 동력학적 모델을 도입하여 카오스가 일어나는 경로를 밝히고 이를 수치적으로 증명하였다. 배리어가 계속존재하는 경우를 적분 가능계로 정의하고 공간주기적 상공간에서 두 개의 호모클리닉 궤도를 포함하는 원환체를 적분가능계의 모델로 도입하였다. 주기적으로 삽입된 배리어 없는 영역을 교란 으로 취급하 여 해 사상을 도입하여 면적 보존의 포인카레 단면을 정의 하였다. 호모클리닉 궤도가 깨어 져 칸토로 집합을 이룸을 설명했고 내부의 원환체는 공진띠와 KAM띠를 이루며 혼합을 방 해함을 설명했다. 다변유한요소를 이용한 완전 3차원수치해석을 통해 회전수 x/3에 해당하 는 공진띠의 존재를 보이고 교란이 큰 경우에는 거의 모든 영역이 무작위적인 혼합을 보여 주는 카오스 영역으로 바뀜을 보였다.

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Ultimate Strength Analysis of Ring-stiffened Cylinders Using Commercial Softwares(II) (상용소프트웨어를 이용한 원환보강 원통의 최종강도 해석(II))

  • 박치모;이승훈
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.114-118
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    • 2001
  • Despite the frequent use of ring-stiffened cylinders as a submarine pressure hull or members of various types of offshore sutructures, their ultimate strength analysis methods have not been well established because of their complex structural characteristics. This paper has established the method how to use commercial softwares based on the finite element method to implement the ultimate strength analysis of ring-stiffened cylinders covering both types of initial imperfections, I. e. initial deformation and initial stress by combining two separately offered functions of common commercial finite element softwares, linear elastic buckling analysis and nonlinear stress analysis. Developed method was applied to one of the world-widely used commercial softwares, ABAQUS for the analysis of ring-stiffened cylinders. This paper ends with some useful information about the imperfection sensitivity of ultimate strength of ring-stiffened cylinders.

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Effect of Initial Shape Imperfection and Residual Stress on the Ultimate Strength of Ring-Stiffened Cylinders under Hydrostatic Pressure (수압을 받는 원환보강원통의 최종강도에 대한 초기 형상결함과 잔류응력의 영향)

  • 조상래;김승민
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.139-143
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    • 2001
  • Ring-stiffened cylinders are widely used as the pressure hull of submarines and underwater vehicles. For large ring-stiffened cylinders cylindrical shells are fbricated by cold rolling of flat plates and then welding of curved shells. After forming cylinders ring-stiffeners are welded on th the cylinders. Due to these cold roiling and welding initial shape imperfections and residual stresses exists in fabricated ring-stiffened cylinders. It is well known that the initial shape and material imperfections affect the ultimate strength of ring-stiffened cylinders significantly. In this paper previous researches on the effects of initial shape imperfections and residual stresses are briefly reviewed Recently a numerical analysis computer program was developed to predict the ultimate strength of ring-stiffened cylinders subjected to hydrostatic pressure, which is based on the Dynamic Relaxation technique. This program was employed to numerically investigate those effects. The numerical predictions were substantiated with relevant experimental results.

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Ultimate Strength Analysis of Ring-stiffened Cylinders Using Commercial softwares (I) (상용소프트웨어를 이용한 원환보강 원통의 최종강도 해석(I))

  • 박치모;이승훈
    • Journal of Ocean Engineering and Technology
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    • v.15 no.2
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    • pp.120-123
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    • 2001
  • Despite the increasing necessity of accurate estimation of ring-stiffened cylinders'ultimate strength, the complex structural behavior of cylinders has made their design mainly depend on empirical formulas mostly based on limited test data rather than theoretical background. This paper has developed the imperfection method which enables the ultimate strength analysis of buckling-sensitive structures by combining two separate functions covered by common commercial finite element softwares, which are linear elastic buckling analysis and nonlinear stress analysis. Developed method was applied to two of the world most renowned softwares, MSC/NASTRAN and ABAQUS, for the analysis of ring-stiffened cylinders and unexpectedly big difference in their analysis results was found. This tells that many widely used commercial softwares have their different strong points and weak points and the choice of commercial software should be cautiously made after thorough inspection. This paper ends with some useful information about which of the two aforementioned softwares is more respectively for the linear elastic buckling analysis and the ultimate strength analysis of ring-stiffened cylinders.

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