• Title/Summary/Keyword: 원소분석

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Geochemical Relationship Between Stream Sediments and Regional Geology of the Upstream for the Hahn River Drainage Basin, Korea. (한강상류 하상퇴적물과 인근유역육상지질과의 지화학적 상관관계)

  • 이연희;지정만;오재경
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.153-171
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    • 2004
  • This study was carried out to define the geochemical and mineralogical relationship between stream sediments and regional geology on upstream of Hahn river area. Geochemical characteristic including for major elements, trace elements and rare earth elements of the South and North Hahn river bed sediments are similar to those of acid igneous rocks which are distributed around both Hahn river basin. The chemical variation of major elements against SiO$_2$ and trace elements contents between South and North Hahn river bed sediments doesn't show the difference. REE patterns of both area show a distinct negative Eu anomaly, but total contents of rare earth elements are higher in North Hahn river sediments than South Hahn river sediments. The heavy minerals in the river bed sediments in this study area are identified as tremolite-actinolite, hematiteㆍmagnetite, common hornblende, ilmenite, garnet, epidote, rutile and sphene. In conclusion, it is elucidated that South and North Hahn river bed sediments are being originated from igneous rocks or metamorphic rocks which contains medium-high grade metamorphic minerals and components of originated from sedimentary rocks those of politic or calcareous rocks are eroded away as solution or suspended load.

Optimization of Parameters for Simultaneous Multielemental Analysis by Atomic Absorption Spectrometry (원자흡수분광법에 의한 다원소 동시분석시 조건의 최적화)

  • Kim, Hyo Jin;Kang, Jong Seong
    • Analytical Science and Technology
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    • v.6 no.4
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    • pp.359-362
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    • 1993
  • To find compromise experimental conditions that will allow a group of elements to be run on flame atomic absorption spectrometer without changing the burner height or gas flow rates, measurements were carried out. The optimum absorbance for simultaneous analysis of ten elements was observed at high flow rate of air-$C_2H_2$ as fuel and at 2mm of burner height. At the condition, 73% of mean relative absorbance were achieved.

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The Problems of Science Textbook Contents Related to Element and Atom in the Viewpoint of Science History (원소와 원자 개념에 대한 과학 교과서 진술의 문제점 분석. 과학 개념의 역사적 변천을 중심으로)

  • Paik, Seoung Hey;Ryu, Oh Hyeon;Kim, Dong Uk;Park, Kuk Tae
    • Journal of the Korean Chemical Society
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    • v.45 no.4
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    • pp.357-369
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    • 2001
  • This study aimed to analyze the evolution of general ideas concerning the element and the atom. In the scientific viewpoint, the modern idea of the element has been variously revised by the ancient Greeks, Boyle-Lavoisier, and Dalton. The definition of the atom was confused with that of the element from the ancient Greecian era to Lavoisier's era. The definition was also changed by Dalton and Rutherford. An analysis of the definitions of element and atom as presented in science textbooks for secondary school students and in general chemistry textbooks revealed that these definitions from diverse eras are confusing and inadequately explicated. The definition presented in one textbook was contradictory to the definitions in other textbooks. This tendency has been sustained in the textbooks from the 4th to 6th science curriculum. Therefore, we need to clarify the definitions of element and atom in order to help the students gain a better understanding of these scientific concepts.

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A short study of uncertainty for post column isotope dilution method in HPLC-ICP/MS (HPLC-ICP/MS에서 후 컬럼 동위원소 희석법의 기초적인 불확도 연구)

  • Joo, Mingyu;Pak, Yong-Nam
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.269-276
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    • 2014
  • A short study for the uncertainty of post column isotope dilution method has been performed for the analysis of Selenomethionine in HPLC-ICP/MS. Major error sources studied were concentration and the flow rate of Se isotope solution, atomic weights of Se in spike and sample, and isotope ratio measured for the spiked sample. Uncertainties were obtained for each factor and the contribution for the total concentration uncertainty was 54.4% and 0.61%, 0.0072% and 0.018%, and 45.0%, respectively. The biggest contribution factor was concentration of the spike solution and the second was the isotopic ratio measured for the spiked sample solution. The mass flow rate of spike and atomic weights did not show much contribution. The calculated total uncertainty was $1.46ng{\cdot}g^{-1}$ for the standard SeMet ($126.30ng{\cdot}g^{-1}$). The experimental result was $127.09{\pm}1.46ng{\cdot}g^{-1}$ and the relative uncertainty was 1.20%.

Estimating the Higher Heating Value of Eco-fuel mixed Biomass with Municipal Organic Wastes from Ultimate Analysis Data (원소분석을 통한 바이오매스에 도시형 유기성 폐기물을 혼합한 신연료의 고위발열량 예측)

  • Oh, Song-Yul;Kim, Lae-Hyun;Han, Hee-Joon;Moon, Jang-Soo;Kim, Hee-Joon
    • Journal of Energy Engineering
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    • v.16 no.4
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    • pp.194-201
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    • 2007
  • HHV (Higher Heating Value) of biomass fuel is calculated by using ultimate analysis data and has been proposed by using correlation equation, and compared with the experiment the adequacy about each correlation equation with measured HHV and examined. Samples used for experiment are prepared by mixing biomass (i.e. rice husk and sawdust) with organic waste (i.e. polystyrene polypropylene and waste paper) of 10, 30, 50 wt% of composition. Ultimate analysis and measurement of HHV are respectively measured by using KS standard method. The average error value of estimated HHV results is about 880 kJ/kg(about 3.8% of measured HHV). The corresponding correlation coefficients ($R^2$) of experimental result and estimated HHV result are $0.957{\sim}0.996$.

Molybdenum Isotope Analysis of Standard Reference Materials (표준물질을 이용한 몰리브덴 동위원소 분석)

  • Jo, Yunsoo;Kil, Youngwoo;Ryu, Jongsik;Seol, Junghwan;Nguyen, The Cong;Jung, Woochul;Park, Sanghee
    • Economic and Environmental Geology
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    • v.49 no.2
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    • pp.89-95
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    • 2016
  • Mo isotope, one of highly redox-sensitive isotopes, has been shown to be useful tracers of geochemical processes. Many studies for Mo isotope have documented with the help of recently developed analysis tools, but it has not yet been documented in the Korea. In this study, we introduce two-stage column separation method of Mo using column tube (BioRad PolyPrep(R) column, 10 ml) and anion exchange resin (BioRad Resin AG(R) 1-X8, 200-400 mesh). Mo isotope ratios in the solid SRMs (BHVO-2, SDO-1, PACS-2) and liquid SRM (IAPSO) were measured on MC-ICP-MS (Multi-collector Inductively Coupled Plasma Mass Spectrometer) and then compared with reference Mo isotope ratios. Mo isotope ratios in our study overlap with reference Mo isotope ratios within analytical error.

Sr Isotopic Composition of Apatite from the Yeongju and Andong Granites: Isotopic Distinction between the Two Granites and Location of the Boundary (영주화강암과 안동 화강암의 인회석 Sr 동위원소 조성: 두 암체의 동위원소적 구분과 경계의 위치)

  • Yoon, Rina;Lee, Seung-Gu;Park, Kye-Hun;Song, Yong-Sun
    • The Journal of the Petrological Society of Korea
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    • v.25 no.1
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    • pp.89-93
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    • 2016
  • Yeongju and Andong granites, located in the northeastern Yeongnam massif, reveal very similar emplacement ages but distinct initial isotopic compositions of strontium. However, previous studies used different boundaries to distinguish these batholiths. In this study, we determined Sr isotopic compositions of apatite separated from the granites of the area to find out the proper boundary and propose the location of such boundary based upon analysis.

Analysis of Trace Elements in Mud Flat with Neutron Activation Analysis (NAA) and Atomic Spectroscopy (중성자 방사화 분석법과 원자 분광법을 이용한 갯벌 시료 중 미량원소 분석법에 관한 연구)

  • Nam, Sang-Ho;Kim, Min-Jae;Chung, Yong-Sam;Kim, Sun-Ha
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.521-528
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    • 2002
  • Neutron Activation Analysis (NAA) and Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) have been applied for the determination of inorganic elements in mud flat of south seaside in Korea. The analytical results of Al, Ca, Fe, Mg, K and Na by NAA were compared with those by ICP-AES. The results show that NAA is superior to ICP-AES for the determination of minor elements in sediment. Accordingly, NAA will play an important role in the analysis of environment samples such as mud flat and sediment having complex matrix.

Development of Controlling and Analyzing Software for Portable Atomic Emission Spectrometry (휴대용 원자 방출 분광계를 위한 제어 및 분석용 소프트웨어 개발)

  • Lee, Sang Chun;Lee, Chang-Soo;Jung, Min-Soo;Ryu, Dong-Hang
    • Analytical Science and Technology
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    • v.11 no.1
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    • pp.1-7
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    • 1998
  • This study focuses on developing a controlling and analyzing software for the portable atomic emission spectrometer equipped with an electrothermal vaporizer(ETV) that can perform the in-situ trace analysis of heavy metal ions dissolved in water. The software works well for a notebook PC and it is exclusively developed for the real time analysis with a line filter and a photomultiplier light detector. The program is designed to operate under Windows 95 environment and either Korean or English can be used as a main language. The Delphi 2.0 language software is mainly used for programing. The program is designed to make a calibration curve and the system users can get the analytical data in a short time. And a final report can be generated without having difficulties. This software can be easily modified for other analytical atomic spectrometers.

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