• Title/Summary/Keyword: 용해 평형

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Copper Solubility in Al2O3-CaO-SiO2-MgO Slag (Al2O3-CaO-SiO2-MgO계 슬래그 중 Cu의 용해도)

  • Han, Bo-Ram;Kim, Eung-Jin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.23 no.1
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    • pp.33-39
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    • 2014
  • In this study, the solubility of Cu, which is a main metal component of wasted PCB, in $CaO-SiO_2-Al_2O_3-MgO$ slag system was investigated. Each 20 grams of Cu chips and the quaternary slag manufactured was placed in an carbon crucible and melted for 10 hours in the temperature between 1673 K and 1825 K to confirm the equilibrium state. The oxygen partial pressure was controlled by the ratio of CO and Ar gas in the range of $10^{-17.23}$ to $10^{-15.83}$ atm. The concentration of Cu in the slag increased with increasing oxygen partial pressure, slag basicity, and MgO content in the slag. The concentration of Cu in the slag decreased with increasing temperature. The Cu dissolution reaction in the slag is an exothermic reaction.

전력 공급 방식에 따른 유도 결합 플라즈마 특성 변화 연구

  • Kim, Hyeon-Jun;Jeong, Jin-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.521-521
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    • 2012
  • 공정용 유도 결합 플라즈마에서 강자성체 페라이트를 이용하여 평형전력 공급 변압기를 사용하여 안정적인 고밀도 플라즈마 발생원 개발에 관한 연구를 수행하였다. 실험에서는2개의 평형전력 공급 변압기를 이중 구조 안테나에 설치하였다. 20-100 mTorr 압력 범위의 아르곤 기체에 30-150 W범위의 전력을 인가하여 반응용기의 중앙에서 부유 탐침법을 이용하여 플라즈마 밀도와 전자 온도를 측정하였다. 동일한 압력과 전력이 인가되었을 때, 평형전력 공급 변압기의 연결 유무에 따른 플라즈마 밀도를 비교하였으며, 본 연구에서 제시한 플라즈마 발생원에서의 플라즈마 밀도가 더욱 높음을 보였다. 또한 전자 온도와 부유 전위는 평행전력 공급방식을 이용한 플라즈마 발생원이 상대적으로 낮은 값을 가졌다. 이는 플라즈마 전위의 감소를 나타내며, 챔버 벽으로 빠져나가는 이온과 전자의 손실이 줄어들었음을 알 수 있다.

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Two Dimensional Analysis for Equilibrium Core of CANDU-PHWR (CANDU형 원자로의 평형로심에 대한 이차원적 해석)

  • Keung Koo Kim;Seong Yun Kim;Chang Hyun Chung
    • Nuclear Engineering and Technology
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    • v.15 no.2
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    • pp.87-97
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    • 1983
  • The WBURN (2-D, 2-group, coarse mesh) code is developed to analyze the equilibrium core characteristics of CANDU-PHWR. The equilibrium characteristics of Wolsung reactor computed by using WBURN are compared with the values given in the Wolsung FSR. The changes of equilibrium core characteristics caused by the variation of design parameters for operating conditions are also investigated. The numerical results indicate that the average discharge irradiation in the Wolsung reactor can be increased up to about 5%.

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Absorption Properties of Carbon Dioxide in Aqueous 2-Amino-2-methyl-1-propanol Solution (2-Amino-2-methyl-1-propanol 수용액에 대한 이산화탄소의 흡수특성에 관한 연구)

  • Park, Sang Hyun;Kim, Sung Hyun;Min, Byung Moo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.107-114
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    • 1998
  • The solubilities of $CO_2$ in 20wt% and 30wt% aqueous AMP solution were obtained from experiments at 40, 50, 60, 70, $80^{\circ}C$. Using the modified Kent-Eisenberg model, equilibrium constants and correlations were determined from the regression of experimental results of 30wt% aqueous AMP solution. There were good agreements between the predicted $CO_2$ solubilities in 20wt% aqueous AMP solution and experimented values. The prediction was conducted at the condition in the literature and the predicted values calculated from the model and correlations which were obtained from this work agree well with the prediction from Deshmukh-Mather model. Thus, the modified Kent-Eisenberg model and correlated equations suggested by this work, resonably well represent vapor-liquid equilibrium of $CO_2$ with aqueous AMP solution. The calculation of chemical species concentration in the liquid phase was performed uslng equilibrium model and from this calculation, we confirm that good absorption capacity is due to the formation of unstable carbamate. Heat of solution(${\Delta}Hs$) was calculated from the solubility data using the Gibbs-Helmholtz equation.

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Absorption of [Cn-min] with Addition of Various Dilutes (희석제 혼합에 따른 [Cn-min]의 흡수특성)

  • Baek, Geun-Ho;You, Seung-Han;Lee, Jeung-Hyuk;Cha, Wang-Seog
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.284-287
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    • 2010
  • 본 연구논문에서는 주요 온실가스인 이산화탄소의 제거를 목적으로 이온성 액체를 실험실규모로 제조한 후 기-액 흡수평형장치를 이용하여 이산화탄소의 용해도 및 재생특성 그리고 희석제첨가에 따른 영향을 조사하였다. 이산화탄소 용해도는 흡수평형압력 25bar조건에서 두 이온성 액체 모두 0.6 mole $CO_2$/mole ILs의 비슷한 흡수력을 보였다. 재생성능의 경우 탈착 전 후의 흡수력 차가 약 7%로 양호한 재생력을 나타냈다. 점도 감소를 위하여 sulfone 희석제를 첨가하여 조사한 결과 흡수력에서 약 15%가량 감소함을 알 수 있었다.

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Study on the Pressure Balance of the Hybrid Safety Injection Tank (피동충수용 혼합형 안전주입탱크의 압력평형에 관한 이론적 해석 및 시험적 연구)

  • Ryu, Sung Uk;Ryu, Hyobong;Byun, Sun-Joon;Jeon, Woo-Jin;Park, Hyun-Sik;Lee, Sung-Jae
    • Journal of Energy Engineering
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    • v.25 no.1
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    • pp.185-191
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    • 2016
  • The Hybrid Safety Injection Tank is a passive safety injection system that enables the safety injection water to be injected into the reactor pressure vessel throughout all operating pressures by connecting the top of the SIT and the pressurizer(PZR). In this study, the condition for balancing the pressure between the Hybrid SIT and PZR was derived theoretically. The pressure balancing condition was set at the point where the velocity of the Hybrid SIT coolant injected into the Direct Vessel Injection(DVI) line was at or above zero. If the condition was derived from a pressure network for the Hybrid SIT, pressurizer, and reactor pressure vessel, the pressure difference between the pressurizer and SIT is less than 0.07 MPa.

Cation Nonstoichiometry in CaTi$O_3$ (CaTi$O_3$에서 양이온 비화학양론)

  • Han, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.2 no.3
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    • pp.207-212
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    • 1992
  • The defect structure of calcium titanates with CaO excess or $TiO_2$ excess was studied by measuring electrical conductivities as a funcition of oxygen partial pressure at $85O^{\circ}C$ to $1050^{\circ}C$. Execess CaO may divide itself equally between A and B sites, resulting in $Ca_{Ti}$" and Vo", while excess $TiO_2$ form $V_{Ca}$" and Vo". The equilibrium electrical conductivity data indicate that the solubilities of CaO and $TiO_2$ in $CaTiO_3$ are 5000ppm and 2000ppm, respectively. Oxygen vacancies contributed to the ionic conduction which flatten the conductivity minima and did not make any defect association with oppositely charged defects.ely charged defects.

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Plate Type New Distributor Development for Hydraulic Motors and Pumps (유압모터 및 펌프용 판 형태의 새로운 분배기 개발)

  • Jin, Seong-Mu;Kim, Hyeong-Ui
    • 한국기계연구소 소보
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    • s.18
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    • pp.75-85
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    • 1988
  • The distributor for hydraulic pumps or motors, particularly radial piston motors, include rotary member which has equally both surface shape for dynamic balance and two fixed members, located in both side of rotary member, which have equal surface shape for dynamic balance and circular ring which use to retain predetermined clearance between two fixed members. Rotary member must have valve part for flow-distribution and can have hydrostatic bearing for excellently dynamic balance. At least two annular steps located on said pressure plate which use in compensation of bolt expansion.

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Thermodynamic Prediction of Groundwater-Rock Interaction Products around Underground Disposal Sites (심부 처분장 주변 지하수-암석 반응 생성물의 열역학적 예측)

  • Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.48 no.2
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    • pp.131-145
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    • 2015
  • Thermodynamic prediction of weathering products from primary aquifer minerals around underground disposal sites was investigated. The distribution of solubility quotients for kaolinite-smectite reactions showed the trend of reaching at equilibrium with Ca-, Mg-, and Na-smectite for deep groundwaters in granitic aquifers. The values of $10^{-14.56}$, $10^{-15.73}$, and $10^{-7.76}$ were proposed as equilibrium constants between kaolinite and Ca-, Mg-, and Na-smectite end members, respectively. On stability diagrams, most of deep groundwaters were located at equilibrium boundaries between stability fields of kaolinite and smectites or on stability fields of smectites and illite. Shallow groundwaters in basic rock aquifer were plotted at the same stability areas of deep granitic groundwaters on stability diagrams. The results indicated that the primiary mineralogical composition may be important to predict weathering products in deep aquifers.

Radiative Properties of King Sejong Station in West Antarctica with the Radiative Transfer Model: Climate Change using Radiative Convective Equilibrium Model (대기 복사 모형에 의한 세종기지에서의 복사학적 특징: 복사 대류 평형 모형을 이용한 기후 변화 연구)

  • Lee, Gyu-Tae;Lee, Bang-Yong;Jee, Joon-Bum;Yoon, Young-Jun;Lee, Won-Hak
    • Journal of the Korean Geophysical Society
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    • v.9 no.1
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    • pp.27-36
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    • 2006
  • The radiative convective equilibrium (RCE) temperature was calculated for the climate change study at King Sejong Station in West Antarctica. As a result of RCE model sensitivity test, the increases of surface albedo, solar zenith angle, and cloud optical thickness decrease surface temperature. On the other hand, the increases of carbon dioxide and cirrus cloud amount are caused by surface warming due to the greenhouse effect. According to the model calculation result, annual mean surface temperature shows a upward trend of 0.012oC/year during the period of 1958-2001. During the period of 1989∼2001, the trend of monthly mean surface temperature by model calculation is 0.01oC/month and the observation trend is 0.005oC/month.

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