• Title/Summary/Keyword: 용해장치

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Visualization and Quantification of Dissolution of Dense Nonaqueous Phase Liquid Entrapped in Porous Media (다공성 매체내 유기용매(DNAPL)의 용해현상 시각화 및 정량화 연구)

  • Ju, Byung-Kyu;Jeong, Seung-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.1
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    • pp.46-52
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    • 2008
  • Oils and chlorinated solvents leaking to the subsurface are entrapped in the soil pore and these are called as nonaqueous phase liquids (NAPL). NAPL entrapped in porous media acts as a continuous source for surface and ground water contamination. This study visualized dissolution of trichloroethylene (TCE) entrapped in porous media and quantified the velocity of TCE dissolution using an image analysis technique. As the water velocity increased, the level of dissolution increased. The results imply that a TCE contaminated region having a high infiltration rate and groundwater velocity may result in severe groundwater contamination. Microscopic images of TCE entrapped in porous media showed that TCE present in the preferential flow paths was easily dissoluted into the water phase. However, TCE present in the stagnant flow region was visualized for long time. The results imply that TCE would be still present in the soil if TCE is detected in goundwater.

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Solubility of Carbon Dioxide in Poly(ethylene glycol) Dimethyl Ether (Poly(ethylene glycol) Dimethyl Ether에 대한 이산화탄소의 용해도)

  • Lee, Eun-Ju;Yoo, Jung-Deok;Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.230-236
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    • 2017
  • Solubility data of carbon dioxide ($CO_2$) in poly(ethylene glycol) dimethyl ether (PEGDME) are presented at pressures up to about 50 bar and at temperatures between 303 K and 343 K. The solubilities of $CO_2$ were determined by measuring the bubble point pressures of the $CO_2+PEGDME$ mixtures with various compositions using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. To observe the effect of the PEGDME molecular weight on the $CO_2$ solubility, the $CO_2$ solubilities in PEGDME with two kinds of molecular weight were compared. As the equilibrium pressure increased, the $CO_2$ solubility in PEGDME increased. On the other hand, the $CO_2$ solubility decreased with increasing temperature. When compared at the same temperature and pressure, the PEGDME with a higher molecular weight gave smaller $CO_2$ solubility on a mass fraction and molality basis, but gave greater $CO_2$ solubilities on a mole fraction basis.

A Cytochemical Study on the Vacuolar Apparatus Participating in the Transport of Bile Acids in the Rat Hepatocytes (Cytochemical Study on the Vacuolar Apparatus for Bile Acid Transport) (담즙산 분비과정에 관여하는 흰쥐 간세포내 소기관에 관한 세포화학적 연구)

  • Shin, Young-Chul
    • Applied Microscopy
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    • v.28 no.2
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    • pp.171-180
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    • 1998
  • In the present study, the vacuolar apparatus were investigated in the hepatocytes of rats treated with DA by transmission electron microscopy of conventional and cytochemical thin sections. In the rats after 20 min of dehydrocholic acid treatment, the cis Golgj cisterns were sacculated in line. The saccule occasionally occured by elongation and attenuated neck. The lysosomes also showed protrudent saccule. The vesicles were observed near the cis Golgi cisterns, lysosome and bile canaliculi. Some of the vesicles appeared to be fused to bile canaliculi. The cis Golgi cisterns usually faced toward the bile canaliculi both in normal and experimental groups. The cis Golgi cisterns, protrudent saccule and vesicles were almost devoid of visible contents. The osmium deposits were heavy on the protrudent saccule as well as on the cis Golgi cisterns or on the vesicles isolated near by, but they were light or not observed on the vesicles in the immediate vicinity of bile canaliculi. The acid phosphatase activities appeared on the lysosome and vesicles located near by, but did not appear on the vesicles as approaching closer to the bile canaliculi. The evidence suggests that the vesicles are derived from the cis Gogi cistern and lysosomes and fuse to bile canaliculi for exocytosis, and that the activity in the vesicles is diminished as approaching closer to the bile canaliculi.

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A Study on Dissolved Ozone Decomposer in Ozonated Water for Semiconductor Process (반도체 공정용 기능수의 용해오존 분해장치에 관한 연구)

  • Moon, Se-Ho;Chai, Sang-Hoon;Son, Young-Su
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.48 no.5
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    • pp.6-11
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    • 2011
  • We have developed dissolved ozone decompose system in the used ozonated water for the semiconductor and LCD fabrication processes, which will be base of obtaining core process technology in the high performance, low price semiconductor and LCD fabrications. Using this technology, it is possible for the semiconductor wafer and LCD planer to process more rapid and chip, and productivity will be improved.

Solubility Measurement of Carbon Dioxide in Alkylcarbonates and Triacetin at High Pressure (고압에서 알킬카보네이트와 트리아세틴의 이산화탄소 용해도 측정)

  • Kim, Ji Won;Hong, Won Hi;Hong, Yeon Ki
    • Clean Technology
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    • v.21 no.2
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    • pp.124-129
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    • 2015
  • The constant-volume method was used to determine the solubility of CO2 in various physical absorbents such as DMPEG (dimethyl ether of polyethylene glycol), DEC (diethyl carbonate), DMC (dimethyl carbonate), and TAT (triacetin) in the total pressure range from 5 to 30 bar. The Peng-Robinson equation of state has been used to describe the equilibrium behavior of these mixtures. It was found that the solubility of absorbents was in the of DMPEG250 > TAT > DEC > DMC at the same temperature. Futhermore, the solubiity of blended absorbent of DMPEG250 and DEC is higher than that of DMPEG 250 alone. Therefore, blended absorbent of DMPEG250 and DEC is expected to be an effective and low cost absorbent for physical absorption in precombustion CO2 capture.

A Process for Recycling of Used Steel Can and Automatic Treatment System (스틸 폐캔 再活用방법과 自動化 처리장치)

  • 박형규
    • Resources Recycling
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    • v.9 no.6
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    • pp.53-57
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    • 2000
  • In the present paper, a current technical progress for recycling of used steel can is described. The developed technology was a kind of pre-treatment through an automatic equipment system to increase recycling and melting efficiency of used steel co. The process consisted of several unit processes such as breaking of steel can bale, removing dust, separation of aluminum can, delacquering, and compressing to bale. Also, aluminum powders were recovered as a by-product at the delacquering step. The process was carried out automatically through by use of the developed equipment system. The automatic system could be very available in mass treatment of used steel can.

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Estimation of gas diffusion coefficients through membrane considered by standing time (유지시간을 고려한 막내 기체 확산계수의 추정)

  • 민벙희;이우태
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.04a
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    • pp.45-46
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    • 1994
  • 기체분리막의 성능을 평가하기 위한 Manometric method의 몇가지 투과측정장치 중, High-Vacuum technique는 기체 투과계수, 확산계수 및 용해도계수의 정확한 값을 얻는데 가장 유용한 장치이다. 그러나 이 장치는 비용이 비싸고, 조작법이 복잡하며, 투과실험시 계 내의 투과측의 농도를 분석할 수 없고, 측정시간이 많이 걸리는 단점이 있다. 따라서 보다 간단하고 일반적인 측정장치는 막내 기체 확산계수의 측정에는 정확도가 떨어지지만, Low-Vacuum Technique 측정장치가 더 많이 사용되고 있다. Volumetric method는 조작법이 간단하며, 계 내의 농도분석이 가능하고, 측정시간이 빠르며, 비용이 적게 드는 장점이 있다. 일반적으로 Volumetric 투과특정장치로 투과계수는 얻었지만, 확산계수에 대해서는 극소수의 연구자들만이 언급하고 있다. 이는 실험하는 방법의 어려움과 기체의 막내 농도분포에 대해 수학적으로 적합한 모델의 해를 얻지 못한데 있다. 최근데 Lee 등은 Volumetric method을 이용한 확산계수의 평가에 대해 연구하여 신뢰성 있는 결과를 보여주었다. 따라서 본 실험은 Volumetric method를 이용하여 막내 기체 확산계수의 측정을 위해 온도, 압력및 분자직경에 따라 Standing time의 예측에 대해 검토하였다.

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