• Title/Summary/Keyword: 용해작용

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Immunohistochemical Study on Role of the Monocyte Chemoattractant Protein-1 and Macrophage Subpopulations in the Rat Corpora Luteum (흰쥐황체에서 MCP-1과 큰포식세포아형의 역할에 관한 면역조직화학적 연구)

  • Cho, Keun-Ja;Kim, Won-Sik;Kim, Soo-Il
    • Development and Reproduction
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    • v.13 no.1
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    • pp.51-57
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    • 2009
  • Monocyte chemoattractant protein-1(MCP-1) is released from the macrophages and endothelial cells, regulated luteotropic and luteolytic actions of macrophages and induced luteolysis. However, the mechanisms of MCP-1 on the development and maintenance of pregnant corpora lutea are thoroughly unknown. In this experiment, TUNEL stain, ED1, ED2, and MCP-1 immunohistochemistry on the corpora lutea of pregnant rats were carried out to reveal the role of macrophages in the developing corpora lutea. In the postpartum corpora lutea, the number of macrophages was increased significantly, and the intensity of ED1 and ED2 immunoreactivity in macrophages were increased moderately, and MCP-1 immunoreactivity was also increased. In conclusion, macrophages in the postpartum corpora lutea may exert phagocytic action mainly, and the macrophages in the pregnant corpora lutea maintain the structure and function of lutein cells.

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Compressibility and Stiffness Characteristics of Vanishing Mixtures (지반 소실 혼합재의 압축성 및 강성 특성)

  • Truong, Q. Hung;Eom, Yong-Hun;Yoon, Hyung-Koo;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.24 no.12
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    • pp.103-111
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    • 2008
  • Soils naturally contain grains of different minerals which may be dissolved under chemical or physical processes. The dissolution leads changes in microstructure of particulate media, such as an increase in local void or permeability, which affects the strength and deformation of soils. This study focuses on the small strain stiffness characteristics of vanishing mixtures, which consist of sand and salt particles at different volume fractions. Experiments are carried out in a conventional oedometer cell (Ko-loading) integrated with bender elements for the measurement of shear waves. Dissolutions of particles are implemented by saturating the mixtures at various confining stresses. Axial deformation and shear waves are recorded after each loading stage and during dissolution process. Experimental results show that after dissolution, the vertical strain and the void ratio increase, while the shear wave velocity and small strain shear modulus decrease. The decrease of the velocity results from the void ratio increase and particle contact decrease. The process monitoring during dissolution of the particles shows that the vertical strain dramatically increases at the beginning of the saturation process and converges after vanishing process finishes, and that the shear wave velocity decreases at the beginning and increases due to the particle reorientation. Specimens prepared by sand and salt particles are proved to be able to provide a valuable insight in macro structural behaviors of the vanishings mixtures.

Effect of Hydraulic Pressure on Bubble Dissolution Rate of Ejector Type Microbubble Generator (수압이 자흡식 마이크로버블 발생장치의 산소 용해율에 미치는 영향)

  • Kim, Hyun-Sik;Lim, Ji-Young;Park, Soo-Young;Kim, Jin-Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.2
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    • pp.27-31
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    • 2017
  • This study was performed to estimate bubble dissolution rate by change of hydraulic pressure according to increase of water depth. Experimental results showed that airflow rate was decreased by increase of hydraulic pressure. Because the force which acts on outlet of nozzle was increased by increase of hydraulic pressure. Mass-transfer coefficient decreased with decreasing airflow rate and increasing effective volume due to increase of hydraulic pressure as water depth increased. On the contrary, as the water depth increased, the bubble dissolution rate was increased because longer residence time of microbubble which was generated by ejector type microbubble generator. However it was thought that if water depth for capacity of ejector type microbubble generator is excessively increasing, bubble dissolution rate would be reduced due to low airflow rate and mass-transfer coefficient. Therefore, it is importance to consider the water depth when operating ejector type microbubble generator.

Extraction of EPA and DHA from Tuna Oil Using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 참치유에서의 EPA 및 DHA 추출)

  • Yoon, Jung-Ro
    • Korean Journal of Food Science and Technology
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    • v.25 no.3
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    • pp.288-294
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    • 1993
  • Solubilities of urea-crystallized tuna oil methyl esters in supercritical carbon dioxide were determined by a flow through extraction reactor. Experimental results obtained under a quasi-equlibrium condition showed that at 150 bar, solubilities of the esters in supercritical $CO_2$ were 0.075, 0.028 and 0.006(w/w) at $40^{\circ}C,\;60^{\circ}C\;and\;80^{\circ}C$, respectively. In the pressure and temperature ranges $(100{\sim}200bar\;and\;40{\sim}80^{\circ}C)$, the solubility increased with the density of $CO_2$. However, selectivity of supercritical carbon dioxide on the extracted compounds was much better at low density than at high density. Supercritical fractionation with a temperature gradient $(50{\sim}75^{\circ}C)$ resulted in concentrates of EPA and DHA in purities of 12% and 85%, respectively.

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Analysis of Middle School Students' Verbal and Physical Interactions of Group Size in Small Group Learning Using Augmented Reality (소집단 크기에 따른 중학생의 증강현실을 활용한 소집단 학습에서 나타나는 언어적·물리적 상호작용)

  • Nayoon, Song;KiDoug, Shin;Taehee, Noh
    • Journal of The Korean Association For Science Education
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    • v.42 no.5
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    • pp.557-566
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    • 2022
  • This study analyzed paired middle school students' verbal and physical interactions in small group learning using augmented reality. Twelve 8th graders were paired to take classes of solubility and melting/boiling points based on augmented reality. These classes were videotaped and recorded. After the classes, all the students participated in a semi-structured interview. The results were analyzed in three sections; individual statement units of verbal interaction, interaction units of verbal interaction and physical interaction. In the individual statement units of verbal interaction, the proportion of information question/explanation was found to be high. In the interaction units of verbal interaction, the proportion of simple interaction was the highest, followed by elaborated interaction. Beneath the elaborate interaction, the proportion of cumulative interaction was found to be the highest, followed by reformative interaction. In the physical interaction, writing a worksheet and gazing at a virtual object were higher. On the basis of the results, effective ways to form a proper environment in small group learning using augmented reality are discussed.

Hydrochemical Characteristics of Natural Mineral Water in the Daebo and Bulguksa Granites (대보화강암과 불국사화강암지역 먹는샘물의 수리화학적 특성)

  • 조병욱;성익환;추창오;이병대;김통권
    • The Journal of Engineering Geology
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    • v.8 no.3
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    • pp.247-259
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    • 1998
  • Groundwater quality of the natural mineral water was investigated in hydrochemical aspects in order to ensure that mineral water meets stringent health standards. There exist 20 mineral water plants in the Daebo granite and 4 mineral water plants in the Bulguksa granite, respectively. Both granite areas show some differences in water chemistry. The pH, EC, hardness, total ionic contents in groundwater of the Daebo granite area are higher relative to those of the Bulguksa granite area. The content of major cations is in the order of Ca>Na>Mg>K, while that of major anions shows the order of $HCO_3>SO_4$>Cl>F. The fact that the $Ca-Na-HCO_3$ type is most predominant among water types may reflect that the dissolution of plagioclase that is most abundant in granitic rocks plays a most important role in groundwater chemistry. Representative correlation coefficients between chemical species are variable depending on geology. In the Daebo granite area, $Ca-HCO_3(0.84),{\;}Mg-HCO_3(0.81),{\;}SiO_2-Cl(0.74),{\;}Na-HCO_3(0.70)$ show relatively good correlationships. In the Bulguksa granite area, fairly good correlationships are found among some components such as K-Mg(0.93), $K-HCO_3(0.92)$, Mg-Cl(0.92), $Cl-HCO_3(0.91)$, and K-F(0.90). According to saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. Groundwater is slightly undersaturated with respect to calcite, whereas it is still greatly undersaturated with respect to dolomite, gypsum and fluorite. Based on the phase equilibrium it is clear that groundwater is mostly in equilibrium with kaolinite and becomes undersaturated with respect to feldspars, evolved from the stability area of gibbsite during water-rock interaction. While the activity of silica increases, there is no remarkable increase in the acivities of alkali ions and pH, which indicates that some amounts of silicic acid dissolved from silica phases as well as feldspars were provided to groundwater. It is concluded that chemical evolution of groundwater in granite aquifers may continue to proceed with increasing pH.

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Heavy Metal Retention by Secondary Minerals in Mine Waste Rocks at the Abandoned Seobo Mine (서보광산 폐광석 내 2차 광물에 의한 중금속 고정화)

  • 이평구;강민주;최상훈;신성천
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.177-189
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    • 2003
  • The main purposes of this study are to utilize mineralogical studies such as optical microscope, XRD and SEM/EDS analyses to characterize the oxidation of sulfide minerals and the mechanisms controlling the movement of dissolved metals from waste rocks at the abandoned Seobo mine. Mineralogical research of the waste rocks confirms the presence of anglesite, covellite, goethite, native sulfur and nsutite as secondary minerals, suggesting that these phases control the dissolved concentrations of As, Cu, Fe, Mn, Pb and Zn. The dissolved metals are precipitated, adsorbed and/or coprecipitated with(or within) Fe(Mn)-hydroxides and Mn(Fe)-hydroxides. The main phases of secondary mineral, Fe-hydroxide, can be classified as amorphous or poorly crystalline and more crystallized phases(e.g. goethite) by crystallinity. Amorphous or poorly crystalline Fe-hydroxide has relatively high As contents(9-24 wt.%). This poorly crystalline Fe-hydroxide changes toward more crystallized phase(e.g. goethite) which contains relatively low As(0.6-7.7 wt.%). These results are mainly due to the progressive release of As with the crystallization evolution of the As-trapping poorly crystalline Fe-hydroxides. It is also attributed to the differences of specific surface areas between the poorly crystalline Fe-hydroxides and well crystallized phases. The dissolved metals from waste rocks at Seobo mine area are naturally attenuated by a series of precipitation(as Fe, Mn, Cu, Pb), coprecipitation(Fe, Mn) and adsorption(As, Cu, Pb, An) reactions. The results of mineralogical researches permit to assess the environmental impacts of mine waste rocks in the areas, and can be used as a useful data to lay available mine restoration plan.

Mineraloty and Genesis of the Sericite Ore from the Samsung Mine Area (삼성광산 일대의 견운모광화작용에 대한 광물학적 및 성인적 연구)

  • Kim Won-Sa;Choi Jun-Kyu
    • Journal of the Korean earth science society
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    • v.26 no.7
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    • pp.674-682
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    • 2005
  • The Samsung mine is located in Jeongsan-myeon, Cheongyang-gun, Chungcheongnam-do, and is produces sericite ores. The purpose of this study is to investigate the geology and mineralogy of sericite one and its host-rock together with the alteration processes and age of sericitization. Geological survey, polarizing microscopy, X-ray powder diffraction, electron microprobe analysis, X-ray fluorescent analysis, differential thermal analysis, and K/Ar isotope study have been employed for this study. The mine area is composed of Precambrian granite-gneiss and mica schist, and also Jurassic biotite granite. Serictization has occured within the granite-gneiss, and is interpreted to be formed by hydrothermal alteration. The sericite was formed by the breakdown of orthoclase, plagioclase, and biotite, respectively. With sericitization intensity increase, $SiO_2\;and\;Na_2O$ contents are decreased, while $Al_2O_3\;and\;K_2O$ increased. The formation age of sericite has been determined to be Jurassic, which corresponds well to the intrusion age of the biotite granite nearby.

Effect of Pressure on the Solubilities of Protein Model Compounds (단백질 모델 화합물들의 압력에 따르는 용해도의 변화)

  • Sun Ho Song;Keon Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.1
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    • pp.31-37
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    • 1985
  • N-Acetyl-1-phenylalanyl-1-phenylalanine methyl ester (APhPhMe), N-acetyl-l-phenylalanine methyl ester (APhMe) and N-acetyl-1-phenylalanyl-1-alanine methyl ester (APhAlMe) were used as model compounds to investigate a protein denaturation under various temperatures and pressures. Overall, the solubility of APhPhMe in water increased with increasing pressure and that of APhMe decreased. However, the solubility of APhAlMe was nearly same. The values of volume change of APhPhMe were -0.9, -1.47, -1.09, -1.52 ml/mole at 20, 30, 40 and 50$^{\circ}C$, respectively, and those of APhMe were +6.0, +7.0, +7.5 ml/mole at 20, 30 and 40$^{\circ}C$, respectively. But those of APhAlMe were nearly zero at the measured temperature. The experimental result seems to be explained by the hydrophobic interaction and hydrogen bond of peptide bonds. In the compounds which have only peptide bonds and which have both a pretty large hydrophobic group and a peptide bond in the molecules, the hydrogen bond between peptide bonds is more dominant than the hydrophobic interaction. However, when the number of peptide bond and hydrophobic group increase simultaneously, the hydrophobic interaction seems to be more dominant.

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Geochemical Environments of Copper-bearing Ore Mineralization in the Haman Mineralized Area (함안지역 함 동 광화작용의 지화학적 환경)

  • Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.42 no.1
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    • pp.1-8
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    • 2009
  • The Haman mineralized area is located within the Cretaceous Gyeongsang Basin along the southeastern part of the Korean peninsula. Almost all occurrences in the Haman area are representative of copper-bearing polymetallic hydrothermal vein-type mineralization. Within the area are a number of fissure-filling hydrothermal veins which contain tourmaline, quartz and carbonates with Fe-oxide, base-metal sulfide and sulfosalt minerals. The Gunbuk, Jeilgunbuk and Haman mines are each located on such veins. The ore and gangue mineral paragenesis can be divided into three distinct stages: Stage I, tourmaline + quartz + Fe-Cu ore mineralization; Stage II, quartz + sulfides + sulfosalts + carbonates; Stage III, barren calcite. Equilibrium thermodynamic data combined with mineral paragenesis indicate that copper minerals precipitated mainly within a temperature range of $350^{\circ}C$ to $250^{\circ}C$. During early mineralization at $350^{\circ}C$, significant amounts of copper ($10^3$ to $10^2\;ppm$) could be dissolved in weakly acid NaCl solutions. For late mineralization at $250^{\circ}C$, about $10^0$ to $10^{-1}\;ppm$ copper could be dissolved. Equilibrium thermodynamic interpretation indicates that the copper in the Haman-Gunbuk systems could have been transported as a chloride complex and the copper precipitation occurred as a result of cooling accompanied by changes in the geochemical environments ($fs_2$, $fo_2$, pH, etc.) resulting in decrease of solubility of copper chloride complexes.