• The Transactions of the Korean Institute of Electrical Engineers
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• v.41 no.1
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• pp.56-62
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• 1992

The GaAs bulk crystals are grown by the Synthesis Solute Diffusion(SSD) method and its properties are investigated. The crystal growth rate at optimum condition is 0.28 cm/day and their temperature dependence is R(T) = 2.92 x 10S04T exp(-1.548eV/kS1BTT) [cmS02T/day.K]. Etch pits density distribution along radial direction is order of 10S04TcmS0-2T and 10S03TcmS0-2T at the edge and middle of the wafers, respectively, and it increased exponentially along vertical direction of ingot. Moreover,it is uniformly distributed as order of 10S03TcmS0-2T in radial direction of In doped GaAs. The carrier concentration and mobilities are measured to 0.34-2.1 x 10S016T cmS0-3T and 2.3-3.3x10S03T cmS02T/V.sec, respectively.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.99-110
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• 2020

It is a global trend to consider contaminated low-permeability zones as one of the primary management targets for the remediation of DNAPL contaminated sites. In addition, studies on the persistence caused by back diffusion of DNAPLs from low-permeability zones have been actively conducted worldwide. On the other hand, the studies for domestic groundwater contamination with the low-permeability zones are insufficient. Therefore, this study introduces the forward and back diffusions of DNAPL through low-permeability zones and suggests the importance of them by reviewing representative previous studies, especially on back diffusion and plume persistence. We proposed six diffusion scenarios and analytical solutions based on various boundary conditions of low-permeability zones. FI (forward diffusion into infinite domain) and BI (back diffusion form infinite domain) scenarios illustrate forward and back diffusion in which the depths of a low-permeability layer are assumed to be infinite. FFN (forward diffusion into finite domain with no flux boundary) and BFN (back diffusion from finite domain with no flux boundary) scenarios describe forward and back diffusion for a finite domain of a low-permeability layer with no flux boundary at the bottom. When the bottom of a low-permeability layer is considered as flux boundary, forward and back diffusion scenarios correspond to FFF (forward diffusion into finite domain with flux boundary) and BFF (back diffusion from finite domain with flux boundary). The scenarios and analytical solutions in this study may contribute to the determination of an efficient remediation method based on site characteristics such as a thickness of low-permeability zones or duration of contamination exposure.

• KSBB Journal
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• v.14 no.2
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• pp.230-234
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• 1999

To improve the crossflow untrafiltration flux, we applied periodic oscillations in transmembrane pressure gradient in order to promote fluid turbulence by inducing repeated compression and relaxation of the cake/gel layer. The oscillatory forms used were square-, sine-, triangle-wave, and pumping interruption. The permeate flux profiles were mathematically simulated and compared with the experimental data. The result showed the periodic pumping interruption most effectively improved the overall flux by up to about 32%. Enough pumping off-time, at least on the order of tens of seconds, was needed to allow the solutes in the layer to diffuse back to the bulk phase. It was better to start the oscillations earlier before the layer was fully established. The square-wave oscillation yielded about 11% increase, which was particularly pronounced in the later part of the filtration. Either the amplitude or the period of the oscillations resulted little influence on flux.actate ester, and lactate ester produced in esterification reaction was distilled simultaneously with hydrolysis reaction into lactic acid. When the yields of lactic acid recovered by batch reactive distillations with various alcohols were compared, the yield of lactic acid was increased as the volatility of lactate ester was increased. In this batch reactive distillation, because the mixtures condensed in partial condensor were flown to reboiler through distillation column, the recovery yield of lactic acid was affected by operation temperature of partial condensor. Hydrolysis reaction into lactic acid in distillation column rarelyoccurred because of short retention time of lactate ester and water. Lactate ester was reacted into lactic acid in reboiler.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.51-59
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• 1996

In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1021-1026
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• 2012

The transient mass transfer in a single droplet system consisting of 1-octanol (continuous phase)/aqueous succinic acid solution (dispersed phase) was investigated in the presence of chemical reaction, which is acid/anion exchange reaction of succinic acid and tri-n-octylamine (TOA). This succinic acid extraction by TOA can be considered to occur at the interface between organic and aqueous phase, that is, heterogeneous reaction system. The basic properties of the system such as viscosity, density, distribution coefficient, terminal velocity of droplet, and diffusion coefficient were measured experimentally or calculated theoretically, and used for theoretical calculation of characteristic parameters of mass transfer later. The effects of succinic acid concentration on the terminal velocity was negligible in the existence of TOA, although the terminal velocity increases with succinic acid concentration in the absence of TOA. On the contrary, the terminal velocity decreases with TOA concentration. While droplets falls through organic phase, the trajectory of droplets is observed to oscillate around its vertical path. A mass trnasfer cell was prepared to monitor the mass transfer behavior in a single droplet and used to measure the mean concentration of succinic acid inside droplet. The results are expressed with dimensionless parameters. Under 50 g/L succinic acid condition, the system with 0.1 mol/kg TOA showed that the molar flux decreases in proportion to the decrease of concentration gradient, while in the case of 0.5 mol/kg TOA Sh increases rapidly with time indicating the molar flux of succinic acid decreases relatively slowly compared to the decrease in concentration gradient.

• Journal of Korea Foundry Society
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• v.43 no.6
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• pp.286-293
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• 2023

In this study, we investigated the microstructural evolution of Al-Mg-Zn aluminum alloy billet during homogenization treatment using OM, SEM, EDS and DSC. There were numerous phases found, such as; AlMgZn, AlMgFe, and AlMgZnSi phases, in the grain of the cast billet. After 6 hours homogenization treatment, Zn was mostly dissolved, whereas, Mg and Si were only partly dissolved. Accordingly, only AlMgFe and AlMgSi remained. After 18 hours, all of the leftover Mg and Si were dissolved, leaving only AlMgFe, which was also found after 24 hours. The results of the alloy design program, JMatPro showed that Mg dissloved more rapidly than Zn. According to the homogenization kinetic equation, Mg and Zn are completely dissolved within 1.9 and 3.5 hours, respectively.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.707-711
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• 2007

낙동강과 밀양강의 합류지점에 위치한 김해시 딴섬 지역의 지표면하 $25{\sim}35\;m$ 구간에 형성되어 있는 고투수성 충적층 내 염소이온의 수리분산특성을 연구하기 위한 수렴흐름 추적자시험(convergent flow tracer test)이 수행되었다. 추적자로는 IW-1공과 IW-2공에서 각각 염소이온 5kg이 순간주입(instantaneous injection) 되었으며, PW공에서 일정한 양수율(2,500 m3 /day)로 채수하면서 염소이온농도를 관측하였다. 염소이온 주입 후 경과시간에 따른 염소이온농도 자료를 이용하여 농도이력곡선과 누적질량회수곡선이 산출되었으며, 관측된 염소이온농도의 정규분포를 검증하기 위한 일반통계분석이 수행되었다. 그리고, 농도이력의 증가/감소 구간에서의 함수를 추정하였으며, 두 시험에서 동일한 시간에 관측된 염소이온농도의 상관성이 분석되었다. 본 현장에서 수행된 추적자시험에 의한 종분산지수의 추정은 CATTI 코드(Sauty and Kinzelbach, 1992)에 의해 해석되었다. 추정된 종분산지수는 IW-1공과 PW공 구간에서는 0.4152 m, IW-2공과 PW공 구간에서는 0.4158 m 로서 매우 유사한 값으로 나타났다. 이는 추적자시험이 수행된 충적층에서의 용질이송이 방사상으로 비교적 균일함을 의미하는 것이다. 본 연구에서 수행된 추적자시험의 규모(2 m)를 Xu and Eckstein(1995)이 제시한 방정식에 대입하여 산정된 종분산지수는 0.0458 m 이었다. 이러한 결과는, 본 연구지역에서 수렴흐름 추적자시험에 의해 추정된 고투수성 충적층의 종분산지수가 일반적인 자연대수층에 비해 9.1배 정도 높다는 것을 의미한다. 이는 시험대수층의 투수성이 매우 높아 염소이온의 용질이송이 매우 빠르게 발생되었기 때문이다. 본 연구에서 추정된 종분산지수를 Gelhar et al.(1992)의 연구 결과와 비교 분석한 결과에서도 시험규모에 비해 매우 높은 수리분산이 발생된 것으로 나타났다. 그리고 염소이온의 확산면적을 추정하기 위해, 수렴흐름 추적자시험에 의한 종분산지수와 시험대수층의 평균선형유속을 이용하여 종분산계수를 구하였다. 현장에서 수행된 양수시험에 의한 평균선형유속 22.44 m/day와 평균 종분산지수 0.4155 m를 적용하여 산정된 종분산계수는 $9.32\;m^2/day$이었다. 따라서, 시험부지 내 충적층에서 일정한 양수율$(2,500\;m^3/day)$로 지하수를 개발할 시에 양수정 주변지역으로 유입되는 염소이온의 확산면적은 1일 $9.32\;m^2$ 정도일 것으로 나타났다.

• Journal of the Korean Chemical Society
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• v.37 no.1
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• pp.22-35
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• 1993

The transport phenomena of the free amino acids through poly(hydroxyethyl methacrylate)[P(HEMA)] have been investigated with and without various kinds of surfactants solution and in the mixed surfactants solution. Glutamine has the highest diffusivity among 4 amino acids at 1CMC of cetyldimethylethylammonium bromide(CTABr) surfactant. Glutamic acid is not affected by the concentration of CTABr. Methionine and Lysine shows slight decreased diffusivity at 0.5 CMC, but increase its diffusivity at 1CMC and 2CMC due to the structure change of membrane and the viscosity change of surfactant solution. Glutamic acid has the highest diffusivity among four amino acids at sodium dodecyl sulfate(SDS) and Triton X-100 surfactant. In mixed surfactant solution, each amino acids shows high diffusivity through 45% water content membrane at the 0.5 mole fraction of SDS in the SDS/TX-100 surfactant mixtures. It has been found that not only the property of membrane but also the effects of solute-solvent interactions and solvent effect are very important as the permeation of amino acids occurs through P(HEMA) membrane. The diffusivities of free amino acids through membrane depend upon their molecular shape, size and charge.

• Electrical & Electronic Materials
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• v.5 no.3
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• pp.284-294
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• 1992

합성용질확산법으로 GaP단결정을 성장시키고 몇가지 성질을 조사하였다. 정지상태에서 결정의 성장속도는 1.75[mm/day]이었고 결정성장용 석영관을 전기로내에서 하강시키므로써 양질의 GaP 단결정을 성장하였다. 에치피트밀도는 결정의 성장축 방향으로 3.8*$10^{4}$[$cm^{-2}$]부터 2.3*$10^{5}$[$cm^{-2}$] 까지 증가하였다. 성장된 GaP결정의 이동도와 캐리어농도는 실온에서 197.49[$cm^{2}$/V.sec]와 6.75*$10^{15}$[$cm^{-3}$]이었고 77K의 온도에서는 266.91[$cm^{2}$ /V.sec]와 3.13*$10^{14}$[$cm^{-3}$]이었다. 에너지갭의 온도의존성은 실험적으로 $E_{g}$(T)=2.3383-(6.082*$10^{-4}$) $T^{2}$/(373.096+T)[eV]로 구하여졌다. 저온에서 측정된 광루미네센스 스펙트럼은 구속된 여기자의 복사재결합과 재결합 과정에 포논의 참여로 인하여 에너지갭 부근의 복잡한 선 스펙트럼이 나타났고 얕은 준위의 Si도너와 Zn억셉터준위 사이에서의 복사재결합 및 이에 대한 1LO, 2LO의 포논복제가 나타났으며 S $i_{Ga}$ -S $i_{p}$의 쌍방출에 의하여 1.8932[eV]에서 넓은 반치전폭의 피크가 나타났다. GaP의 적외선 흡수는 TO, LO, LA, T $A_{1}$, T $A_{2}$ 포논들의 이중결합모드와 G $a_{2}$O의 진동모드 및 Si도너와 Zn억셉터들에 의하여 일어났다. Zn를 확산시키어 제작한 p-n GaP발광다이오드는 실온에서의 발광중심피크가 6250[.angs.]이었고 최대광출력은 0.0916[mW], 양자효율은 0.51%이었다.이었다.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.3
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• pp.111-115
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• 1997

Discrete fracture model has become one of the alternatives for the classical continuum model to simulate the irregular aspects of the fluid flow and the solute transport in fractured rocks. It is based on the assumptions that the discharge in a single fracture is proportional to the cube of the aperture and the fractured rock can be represented by the statistical assemblage of such single fractures. This study is intended to evaluate the effect of the fracture junction on the cubic law. Numerical solution of flow in junction system was obtained by using the Boundary-Fitted Coordinate System (BFCS) method. Results with different intersection angles in crossing fractures show that the geometry of the junction affects the discharge pattern under the same simulation conditions. Therefore, strict numerical and experimental examinations on this subject are required.