• Proceedings of the Korean Society for Rock Mechanics Conference
• /
• 2000.09a
• /
• pp.129-137
• /
• 2000

This paper presents groundwater flow characteristics in discontinuous rock mass using fracture network program(NAPSAC) by statistical approach. Equivalent permeability coefficients are estimated from borehole data around Mabuk test tunnel site and fracture map on the arch of the tunnel. The reliability of fracture network model is obtained from determination of input data for statistical fracture network analysis from the real data(data of fracture network, data of hydraulic tests). The variation of permeability and mean anisotropic permeability coefficients are calculated from the realized model by increasing the size. As a result of analysis, a strong anisotropy of permeability is observed according to the direction of the fracture sets around the test tunnel.

• Tunnel and Underground Space
• /
• v.10 no.3
• /
• pp.378-386
• /
• 2000

This paper presents groundwater flow characteristics in discontinuous rock mass using fracture network program(NAPSAC) by statistical approach. Equivalent permeability coefficients are estimated from borehole data around Mabuk test tunnel site and fracture map on the arch of the tunnel. The reliability of fracture network model is obtained from determination of input data for statistical fracture network analysis from the real data(data of fracture network, data of hydraulic tests). The variation of permeability and mean anisotropic permeability coefficients are calculated from the realized model by increasing the size. As a result of analysis, a strong anisotropy of permeability is observed according to the direction of the fracture sets around the test tunnel.

• Journal of Soil and Groundwater Environment
• /
• v.17 no.5
• /
• pp.31-39
• /
• 2012

Chemical and isotopic variations of snowmelt provide important clues for understanding snowmelt processes and the timing and contribution of snowmelt to catchment or watershed in spring. The newly developed model includes a hydraulic exchange between mobile and immobile water (${\omega}$), and isotopic exchanges between both mobile water and ice ($f_1$) and immobile water and ice ($f_2$). Since the new model is based on the mobile-immobile water conceptualization, which is widely used for describing chemical tracer transport in snow, it allows simultaneous calculations of chemical as well as isotopic variations in snowpack discharge. We compare the model results with a study of solute transport and isotopic evolution of snowmelt in snow, using artificial rain-on-snow experiments with conservative anion ($Br^-$). These observations are used to test the newly developed model and to better understand physical processes in a seasonal snowpack where our model simulates the chemical and isotopic variations.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
• /
• 2005.09a
• /
• pp.83-88
• /
• 2005

유기 절연층을 갖는 유기 박막트랜지스터 (organic TFT)를 제작하여 소자 성능을 조사하였다. 유기 절연층의 형성에서는 polyvinyl 계열의 PVP(poly-4-vinylphenol)와 PVT(polyvinyltoluene)를 용질로, PGMEA (propylene glycol mononethyl ether acetate)를 용매로 사용하였다. 또한, 열경화성 수지인 poly(melamine-co-formaldehyde)를 경화제로 사용하여 유기 절연층의 cross-link 를 시도하였다. MIM 구조로 유기 절연층의 특정을 측정한 결과, PVT는 PVP에 비해 절연 특성이 떨어지는 경향을 보였다. 게이트 절연막의 제작에서 PVP를 cobpolymer 방식과 cross-linked 방식으로 실험 해 본 결과, cross-link 방식에서 낮은 누설전류 특성을 나타내었다. OTFT 제작에서는 PVP를 용질로, poly(melanine-co-formaldehyde)를 경화제로 사용한 cross-linked PVP 를 게이트 절연막으로 이용하였다. PVP copolymer($20\;wt\%$)에 $10\;wt\%$ poly(melamine- co-formaldehyde)를 혼합한 cross-linked PVP 를 게이트 절연막으로 사용하여 top contact 구조의 OTFT를 제작한 결과 약 $0.23\;cm^2/Vs$의 정공 이동도와 약 $0.4{\times}10^4$의 평균 전류점멸비를 나타내었다.

• Economic and Environmental Geology
• /
• v.42 no.6
• /
• pp.561-574
• /
• 2009

Unsaturated/saturated groundwater flow and solute transport model, VSFRT2D(Variable Saturated Flow and Reactive Transport model) was developed considering effects of pumping, irrigation, and denitrification. VSFRT2D employed Richards equation as governing equation for groundwater flow and previously existing unsaturated models modified by including computational procedure of evapotranspiration at surface using Thornthwaite method when precipitation doesn't occur. Bioremediation processes based on monod kinetics are described using four nonlinear contaminant transport equations and three nonlinear microbes transport equations. The developed model was applied to field data in Hongsung area contaminated with nitrate. In order to identify the effect of precipitation, pumping, evapotranspiration, irrigation, fertilizer application, and various bioremediations on groundwater flow and contaminant transport, individual processes were separated and simulated. Then all results obtained from the individual processes are compared with each other. The simulation results show that bioremediation had a negligible effect on nitrate concentration change. However, pumping for irrigation, precipitation, and nitrogen fertilizer application showed profound influences on nitrate concentration change.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.10 no.4
• /
• pp.237-246
• /
• 2012

In this study, numerical model for transport of radionuclide and colloid was developed. In order to solve reaction-migration governing equation for colloid and radionuclide, Strang-splitting Sequential Non-Iterative (SNI), which is one of Operator Splitting Method, was used for numerical method and this was coded by MATLAB. From the verification by comparing the simulation results with analytical solution considering only solute transport and rock diffusion, the Pearson's correlation coefficient was greater than 0.99 which demonstrates the accuracy of the model.

• Korean Journal of Soil Science and Fertilizer
• /
• v.32 no.4
• /
• pp.365-374
• /
• 1999

To obtain informations on vertical movements of water and solute in rice paddy field during the growing season, soil water contents and bulk electrical conductivities (${\sigma}_a$) were monitored using Time Domain Reflectometry. Soil water contents with depth showed ${\varepsilon}$-shaped profiles constituting of partly saturated zones at top and bottom layers and unsaturated zones (20-100cm) between them. Analysis by fitting with a van Genuchten-type model showed that soil water contents at 60cm were affected by both water supplied from surface water and groundwater, but at 80cm mainly affected by groundwater. Water percolation at the rate of 2cm $day^{-1}$ rates were, but large fluctuation from 10 to 38cm $day^{-1}$ in C1 layer (60-90cm). Therefore, it can be said that any water or solute entering C1 layer is very rapidly transported to C2 layer, especially during the period of high groundwater table staying, and retarded to a relatively constant percolation rate in C2 layer. This can be manifested by the fact that rapid decrease and steady increase of electrical conductivities at 50 and 110cm depth respectively, were found around that period.

• Journal of Korea Water Resources Association
• /
• v.30 no.1
• /
• pp.23-34
• /
• 1997

The Nanji-Do ladnfill is an ill-conditioned reclaimed land without pollution intercepting facilities, and has high ground water table and deep stratum. The purpose of this study is to analyze the solute transport in steady-state groundwater flow and to predict the solute dispersion in Nanji-Do landfill using HST-3D model. As results, the groundwater flows radially outward from the center of No. 1 and No. 2 landfills, and large amount of runoff is moved into Han River. The predicted relative concentration of total dissolved solute(TDS) at two years later was 0.25 in the weathering zone, 0.26 in the lower alluvium, and 0.28 in the upper alluvium. Thus, the further pollution to bottom rock and Han River was predicted by comparing the corresponding present values of 0.29, 0.32 and 0.35.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.40 no.2
• /
• pp.163-170
• /
• 2014

Lipid membranes composed of phosphatidylcholine (PC) are used in biophysical study to mimic cellular membranes and interactions between the membrane and chemicals, where organics solvents are used in dissolving lipids or chemicals. Later, solvents are removed from the solution under nitrogen gas at room temperature, followed by the further removal of the solvent at vacuum condition for several hours. In this process, some solvents are easily removed under described conditions above and others are required more severe conditions. In this study, $^{31}P$ solid-state nuclear magnetic resonance (SSNMR) techniques and differential scanning calorimetry (DSC) were used to see any changes in the line shapes of $^{31}P$ NMR spectra of multilamellar vesicles (MLVs) samples of POPC and in the phase change temperature of multilamellar vesicles (MLVs) of DPPC in DSC thermogram with or without any residual solvents. The thermodynamic parameters associated with the solvents did exhibit noticeable changes depending on solvent types. Thus, it is concluded that solvents should be carefully chosen and removed completely and experimental results should also be interpreted with caution particularly for the experiments investigating lipid phase changes and related topics.

• Korean Chemical Engineering Research
• /
• v.50 no.6
• /
• pp.1021-1026
• /
• 2012

The transient mass transfer in a single droplet system consisting of 1-octanol (continuous phase)/aqueous succinic acid solution (dispersed phase) was investigated in the presence of chemical reaction, which is acid/anion exchange reaction of succinic acid and tri-n-octylamine (TOA). This succinic acid extraction by TOA can be considered to occur at the interface between organic and aqueous phase, that is, heterogeneous reaction system. The basic properties of the system such as viscosity, density, distribution coefficient, terminal velocity of droplet, and diffusion coefficient were measured experimentally or calculated theoretically, and used for theoretical calculation of characteristic parameters of mass transfer later. The effects of succinic acid concentration on the terminal velocity was negligible in the existence of TOA, although the terminal velocity increases with succinic acid concentration in the absence of TOA. On the contrary, the terminal velocity decreases with TOA concentration. While droplets falls through organic phase, the trajectory of droplets is observed to oscillate around its vertical path. A mass trnasfer cell was prepared to monitor the mass transfer behavior in a single droplet and used to measure the mean concentration of succinic acid inside droplet. The results are expressed with dimensionless parameters. Under 50 g/L succinic acid condition, the system with 0.1 mol/kg TOA showed that the molar flux decreases in proportion to the decrease of concentration gradient, while in the case of 0.5 mol/kg TOA Sh increases rapidly with time indicating the molar flux of succinic acid decreases relatively slowly compared to the decrease in concentration gradient.