• Title/Summary/Keyword: 용존유기질소

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폐비닐 재생메디아를 이용한 생물막공정에서의 하수처리 특성

  • Jang, Seong-Ho;Seo, Jong-Hwan;Park, Jin-Sik
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.375-379
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    • 2007
  • 폐비닐 여재(Synthetic Waste Polyethylene Media)를 적용한 부착성장식 공정의 유기물 및 질소${\cdot}$인 제거특성에 관한 Pilot Plant 실험 결과 다음과 같은 결론을 얻을 수 있었다. 1) 제거효율은 $RUNI1{\sim}3$에서 $COD_{cr}$ 91.4, 92.4, 93.9%, T-N 56.9, 61.4, 65.1%, T-P는 모든 단계에서 약 45%이상 제거되어 부하변동시에 강한 대처능력을 나타내었다. 2) BOD용적부하 $0.18{\sim}0.40kg/m^3{\cdot}d$, COD용적부하 $0.28{\sim}0.53kg/m^3{\cdot}d$, ${NH_4}^{+}-N$용적부하 $0.12kg/m^3{\cdot}d$을 나타내었다. 3) 도시하수 처리를 위한 생물학적 질소 및 인 제거공법을 본 여재를 이용하여 공정설계시 고려할 사항들과 적절한 대처방법을 다음과 같이 제시할 수 있다. - 1차 침전지에서 유기질소 및 유기인 농도가 높다면 유기질소 및 인 부하량을 감소시키기 위하여 1차 침전지를 설치하되 질소 및 인제거에 유리한 $BOD_5/T-N$, $BOD_5/T-P$를 유지할 수 있도록 체류시간을 1시간미만으로 설계하는 것이 경제적이라고 판단된다. 만일 유기질소와 유기인의 함량이 낮다면 1차 침전지는 제외하는 것이 유리할 것이다. - 여재의 배치는 폭기조에서 용존산소의 균일분포와 슬러지의 적정탈리를 위해 여재를 상하로 배치하거나 또는 여재끼리 일정 간격을 두어 배치하는 것이 바람직하다. 농촌에서의 처분이 문제시 되고 있는 폐비닐을 적용한 본 연구에서의 수처리특성은 기존 하수처리공정에서의 제거효율에 상응하는 처리특성을 나타내었다. 또한 폐비닐 처분의 문제를 해결할 수 있을뿐만 아니라 하수처리시에도 부하변동 등에 강한 대처능력을 나타내어 기존의 하수처리공정에 대체가능성을 나타내었다.

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Solids and Nitrogen Removal in the Sludge Digestion using a Sequencing Batch Reactor (연속회분식반응조를 이용한 슬러지 소화에서 고형물과 질소의 제거)

  • Kim, Sung Hong;Lee, Yoon Heui
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6B
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    • pp.669-675
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    • 2006
  • Intermittent aerobic digestion experiments using a sequencing batch reactor (SBR) were carried out in this study. Aeration ratio was found to be an important operation factor for the reduction of solids and nitrogen. As the sludge digested, organic nitrogen was released from the solids and oxidized to nitrate nitrogen. Biological denitrification was also significant and the denitrification rate was limited by aeration ratio. Under the condition of 0.25-0.75 of aeration ratio, acclimation of ammonia nitrogen was not observed and pH were preserved near neutral in the intermittent aerobic digestion. As the aeration ratio increased, solids reduction was increased whereas dissolved nitrogen removal was decreased. Based on the experiments, 17-2% of VSS reduction and over 80% of dissolved nitrogen removal were practicable by intermittent aerobic digestion using a SBR when the MSRT were designed 8-32 days and aeration ratio was operated about 0.25-0.75.

The Contents of Nitrogen, Phosphorus, Silicon Nutrient and Algal Growth Potential (AGP) in the Sediment of Taechong Reservoir (대청호 저토의 N, P및 Si 영양염 함량과 조류생장잠재력)

  • Cho, Kyung-Je;Shin, Jae-Ki
    • Korean Journal of Ecology and Environment
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    • v.34 no.2 s.94
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    • pp.106-118
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    • 2001
  • The chemistry of porewater and exchangeable nutrients of sediment was determined to define potential influence of sediment nutrients on the water quality and the phytoplankton growth in Taechong Reservoir in March and May of 2000. The sediment-water interface showed almost anoxic state, < 0.5 mg $O_2/l$. Conductivity of the porewater was higher 1.9${\sim}$2.6 fold than that of sediment, and its variation was greater in the shallow water. Eh ranged from -12mV to -148 mV and bulk density from $1.17\;g/cm^3$ to $1.30\;g/cm^3$ and they did not differ among stations. The water content in the sediment ranged from 58% to 72% and organics from 8% to 13%, and they were higher toward the lower part of reservoir. Soil texture was in the order of sand>clay>silt and sandy sediment accounted for 97% of the total sediment. The total bacterial numbers and diatom abundance were high in the downstream of the reservoir. In porewater and exchangeable nutrients of sediment, nitrogen and phosphorus were mostly consist of the particulate form. Inorganic nitrogen was mostly composed of $NH_4$. Nitrogen of porewater was mostly an inorganic form while exchangeable nutrients were composed an organic form. However, phosphorus was composed of dissolved organic fraction in the porewater while inorganic fraction in the exchangeable nutrients. Silicon content of sediment was much exchangeable nutrients with 63%, and it was higher than in the porewater. In summary, the sediments of Taechong Reservoir were mostly composed of organics and assessed to be a eutrophic state.

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Effect of Aeration Mechanism on Livestock Manure Liquid Fertilization (폭기형태가 돈분뇨 액비 부숙특성에 미치는 영향)

  • Jeong, Kwang-Hwa;Khan, Modabber Ahmed;Kim, Chang-Hyun;Lee, Dong-Hyun;Choi, Dong-Yoon;Yu, Yong-Hee
    • Korean Journal of Organic Agriculture
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    • v.20 no.4
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    • pp.703-713
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    • 2012
  • Three types of aeration system were installed in experimental liquid fertilization tanks to investigate the change of characteristics of pig slurry used as a raw material for making livestock liquid fertilizer. The aeration systems of the reaction tanks were composed of three major part: the air suppling part (blower), the air pipe part, and the air diffuser part. In the first tank (reactor A), the air was supplied from the bottom of the reaction tank through air pipe system connecting air diffuser with commercial ordinary blower. In the second tank (reactor B), the air diffuser was located 10cm above the bottom of the reactor. In the third tank (reactor C), the pure air was supplied with circulating pjg slurry. The oxygen content of pure air was about 90%. The pure air was mixed with pig slurry by mechanically in the air suppling part (blower) and the air pipe part. The agitation effect was highest in the reactor C than other reactors. The contents of SS, COD, T-N and T-P of each samples collected at middle part of all reactors were 8,500, 4,188, 694 and 422mg/L; 9,000, 4,247, 813 and 356mg/L; 8,667, 6,910, 973 and 269mg/L, respectively.

Effect of Freshwater Discharge on the Seawater Quality (Nutrients, Organic Materials and Trace Metals) in Cheonsu Bay (여름철 천수만 해수에서 담수 대량 방류에 따른 영양염, 유기물 및 미량금속의 변화)

  • LEE, JI-YOON;CHOI, MAN-SIK;SONG, YUNHO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.4
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    • pp.519-534
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    • 2019
  • When the fresh water from the artificial lakes (Ganwolho and Bunamho) were discharged to Cheonsu Bay in summer to prevent the flood over the reclaimed farmland near the lakes, the impact on water qualities (nutrients, organic matters, trace metals) within the bay was investigated through four surveys (June, July, August and October, 2011). Dissolved inorganic nitrogen (DIN) increased about as much as 3-4 times over the whole water column when the freshwater was discharged. And the main species composition of DIN changed from ammonia to nitrate. Dissolved inorganic phosphorus (DIP) decreased as much as 2 times in surface waters, but increased as much as 1.5 times in deep waters, and also silicate concentrations increased as much as 3-4 times in deep waters of the inner bay. The N/P ratios in Chunsu bay seawaters were much higher (2 to 7 times) than the Redfield ratio when the freshwaters were discharged, which indicated the phosphorus limiting in the phytoplankton growth. Dissolved organic carbon (DOC) and nitrogen (DON) increased as much as about 2 times. In addition, particulate organic matters (POC, PON, POP, Bio-Si) increased as much as above 2 times in the surface waters of the inner bay. Trace metals (Fe, Mn, Co, Ni, Cu) increased in the surface waters of the inner bay, but dissolved Cd concentrations decreased as much as 2 times. Therefore, when the contaminated fresh waters from the artificial lakes were discharged into the bay, nutrients, organic matters and trace metals generally increased compared to normal period. Since the phytoplankton bloom occurred in the surface waters of the inner bay, dissolved oxygens at the surface waters were oversaturated and hence hypoxic in the deep waters. Highly enriched nutrients concentrations were found in deep waters of the inner bay, which was accompanied with the hypoxic condition. Finally, the water quality in the inner bay of the Chunsu bay was deteriorated from less than grade 3 in normal periods to grade 5 when the freshwaters from the artificial lakes were discharged in summer.

Hybrid Water Treatment of Tubular Alumina MF and Polypropylene Beads Coated with Photocatalyst: Effect of Nitrogen Back-flushing Period and Time (관형 알루미나 정밀여과와 광촉매 코팅 폴리프로필렌 구의 혼성 수처리: 질소 역세척 주기와 시간의 영향)

  • Park, Jin Yong;Choi, Min Jee;Ma, Jun Gyu
    • Membrane Journal
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    • v.23 no.3
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    • pp.226-236
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    • 2013
  • The effect of $N_2$ back-flushing period (FT) and time (BT) was compared with the previous result used PES (polyethersulfone) beads loaded with titanium dioxide photocatalyst in hybrid process of alumina microfiltration and PP (polypropylene) beads coated with photocatalyst in viewpoints of membrane fouling resistance ($R_f$), permeate flux (J), and total permeate volume ($V_T$). The reason of nitrogen back-washing instead of the general air back-washing method is to minimize the possible effect of oxygen included in air on water quality analysis. As decreasing FT, $R_f$ decreased and J and $V_T$ increased. Treatment efficiency of dissolved organic matters (DOM) was 82.0%, which was the higher than 78.0% of the PES beads result. This means that PP beads coated with photocatalyst was the more effective than PES beads loaded with photo-catalyst in the DOM removal. As increasing BT, the final $R_f$ decreased and the final J increased, but $V_T$ was the maximum at BT 15 sec. The average treatment efficiency of turbidity did not have any trend as changing BT. As BT increasing from 6 sec to 30 sec, the treatment efficiency of DOM increased 11.8%, which was a little higher than the result of PES beads.

A Study on the Parameters of WASP5 Model in Daechung Reservoir (대청호에서 WASP5 모델 매개변수에 관한 연구)

  • Han, Woon Woo;Kim, Kyu-Hyung;Ahn, Tae-Bong
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.3
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    • pp.69-77
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    • 2003
  • This study was carried out to evaluate the WASP5 model parameters and to analyze the sensitivity of parameters in Daechung Reservoir. The values predicted by the model and tendency were very similar to the observed data at Daejeon intake, so it is possible to predict water quality of the Daejeon intake region in the future. Results from the sensitivity analysis showed that Chlorophyll-a was sensitive to variations in saturated growth rate of phytoplankton, endogenous respiration rate of phytoplankton, extinction coefficient and temperature. T-N was sensitive to mineralization rate of dissolved organic nitrogen and temperature. T-P was affected by T-P load, temperature, extinction coefficient, mineralization rate of dissolved organic phosphorus and saturated growth rate of phytoplankton. BOD was influenced by deoxygenation rate and temperature, and DO was influenced by temperature. Adequate input data was applied and assessed through the model sensitivity analysis. So it is possible to distinguish the input data which need careful attention when it has application to model.

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Characteristics of Nonpoint Source Pollution from a Reclaimed Rice Paddy Field (계화 간척지구 강우 유출수의 비점오염원 유출특성에 관한 연구)

  • Lu, Weiwei;Yi, Qitao;Yu, Jianghua;Kim, Young-Chul
    • Journal of Wetlands Research
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    • v.11 no.3
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    • pp.9-19
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    • 2009
  • This research addressed nonpoint source (NPS) pollution characteristics in a reclaimed rice paddy field. The paddy has an area of around 2,998 ha and is divided as two sub-watersheds, whose areas are 1,181 ha and 1,817 ha, respectively. Monitoring of hydrologic runoff and NPS pollution was undertaken during three-month period from June to August, 2008. Totally, three sampling trips were made when rainfall depth were 66.0 mm, 23.5 mm, and 23.0 mm, respectively. Generally pollution load increased with the heavier cultivation activity in Korea. Exported pollutants from the rice paddy, including TSS, TN and TP, have same levels as forest discharge. Organic nitrogen is main pattern but it mainly exists in the forms of dissolved organic nitrogen (DON). For phosphorus, dissolved inorganic phosphorus (DIP) takes the main part although part of them is associated with fine particles. This is different compared with other watersheds, where particles-associated phosphorus is the main form.

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Removal of Dissolved Organic Matters in Drinking Water by GAC adsorption using RSSCT (RSSCT를 이용한 GAC의 상수원수 내 용존유기물질 제거)

  • Kim, Young Il;Bae, Byung Uk
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.5
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    • pp.727-736
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    • 2006
  • Granular activated carbon (GAC) has been identified as a best available technology (BAT) by the United States Environmental Protection Agency (USEPA) for removal disinfection by-product (DBP) precursors, such as dissolved organic carbon (DOC) and dissolved organic nitrogen (DON). Rapid small-scale column test (RSSCT) were used to investigate four types of carbon (F400, Norit1240, Norit40S, and Aquasorb1500) for their affinity to absorb natural organic matter (NOM). DOC, $UV_{254}$, and Total dissolved nitrogen (TON) concentrations were measured in the column effluent to track GAC breakthrough. DOC and $UV_{254}$ breakthrough occurred at around 3500 bed volumes (BVs) of operation for all GACs investigated. The $UV_{254}$ breakthrough curves showed 33% to 48% at 8000 BVs, when the DOC was 48% to 65%. All GACs showed greater removal in DOC than $UV_{254}$. The NORIT1240 GAC was determined to have the highest adsorption capacity for DOC and $UV_{254}$. The removal of nitrate (NOTN) had not broken through over BVs. The initial TON breakthrough curves were started around 50%, when the DOC breakthrough was only 10 % at 500 BVs. The curves were gradually increased after 3500 BVs and approximately 69% through 81% of TON breakthrough occurred at 8000 BVs. All of the GACs were able to remove TON, in the case of this investigation the majority of the TON was present as DON. Because nitrate nitrogen was seldom removed and ammonium nitrogen ($NH_3-N$) was not detected in the effluent from RSSCTs even though raw water. The carbon usage rate of DOC was from 2 to 6 times less than that of TON. The NORIT1240 GAC demonstrated the best performance in terms of DOC removal, while the F400 GAC was best in terms of TON removal. Excitation emission matrix(EEM) analysis was used to show that GAC adsorption successfully removed most of Humic-like DOC and Fulvic-like DOCs. However, soluble microbial product(SMP)-like DOC in the absence of raw water were detected in the NORIT40S and Aquasorb1500 GAC. The authors assumed that this results is due probably to the part of GAC in the RSSCT which was converted into biological activated carbon(BAC). To compare with organics removal by GAC according to preloading, the virgin GACs had readily accessible sites that were adsorbed DOC more rapidly than preloaded GACs, but the TDN removal had not showed differences between those GACs.

Analysis on Nitrogen Faction of Influent Sewage in Domestic STP Based on Long-term Incubation Method (장기 배양법을 이용한 국내 하수처리장 유입 하수의 질소 성상 분석)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.19 no.2
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    • pp.216-222
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    • 2017
  • Recently, opinions on the need for revision regarding the nitrogen effluent standard of nitrogen from sewage treatment plant(STP) are consistently suggested. However, it is axiomatic that if nitrogen effluent standard is strengthened without a clear basis, it will cause confusion in domestic STP. In this research, nitrogen fraction was analyzed based on a long-term incubation method, according to STP capacity, and the linked treatment of industrial wastewater. As a result, NBDDON, which is difficult to treat in STP, ranged from 1.0 to 1.9 mg/L. larger DON and NBDDON/DON was detected in small STP (under 10,000 m3 /d) as opposed to the large STP. NBDDON/DON in industrial STP was about 0.7 and it was higher than municipal STP. This research result will be used in the important raw data for revision of nitrogen effluent standard of nitrogen from STP.