• Title/Summary/Keyword: 용존성 무기인

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Study of Characteristics of Seasonal Fluctuation of Water Quality and Sediment Environment in Kamak Bay in 2007 (2007년 가막만의 해양수질 및 저질의 계절 변동에 관한 연구)

  • Cho, Hyun-Seo;Cho, Geun-Ock;Park, Jeong-Chae;Kim, Hae-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2008.05a
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    • pp.129-132
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    • 2008
  • This study was performed to characterize the seasonal variation of water quality and sediment environment from May, 2007 to February, 2008 in 20 stations of Kamak bay. $4.83\sim11.07mg/L$ on surface and $4.70\sim11.19mg/L$ on bottom in DO, $0.16\sim2.03mg/L$ on surface and $0.10\sim1.55mg/L$ on bottom in COD, $0\sim3.04{\mu}g$-at/L on surface and $0\sim15.21{\mu}g$-at/L on bottom in DIN, $0\sim3.04{\mu}g$-at/L on surface and $0\sim2.01{\mu}g$-at/L on bottom in DIP. IN sediment the ranges were 3.80 to 9.78% in IL, $0\sim5.37mg/g$-dry in AVS and $3.09\sim41.01mg/g$-dry in COD.

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WQI Class Prediction of Sihwa Lake Using Machine Learning-Based Models (기계학습 기반 모델을 활용한 시화호의 수질평가지수 등급 예측)

  • KIM, SOO BIN;LEE, JAE SEONG;KIM, KYUNG TAE
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.27 no.2
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    • pp.71-86
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    • 2022
  • The water quality index (WQI) has been widely used to evaluate marine water quality. The WQI in Korea is categorized into five classes by marine environmental standards. But, the WQI calculation on huge datasets is a very complex and time-consuming process. In this regard, the current study proposed machine learning (ML) based models to predict WQI class by using water quality datasets. Sihwa Lake, one of specially-managed coastal zone, was selected as a modeling site. In this study, adaptive boosting (AdaBoost) and tree-based pipeline optimization (TPOT) algorithms were used to train models and each model performance was evaluated by metrics (accuracy, precision, F1, and Log loss) on classification. Before training, the feature importance and sensitivity analysis were conducted to find out the best input combination for each algorithm. The results proved that the bottom dissolved oxygen (DOBot) was the most important variable affecting model performance. Conversely, surface dissolved inorganic nitrogen (DINSur) and dissolved inorganic phosphorus (DIPSur) had weaker effects on the prediction of WQI class. In addition, the performance varied over features including stations, seasons, and WQI classes by comparing spatio-temporal and class sensitivities of each best model. In conclusion, the modeling results showed that the TPOT algorithm has better performance rather than the AdaBoost algorithm without considering feature selection. Moreover, the WQI class for unknown water quality datasets could be surely predicted using the TPOT model trained with satisfactory training datasets.

Application of Dissolved Air Flotation Technique to Improve Eutrophic Reservoir Water Quality (가압부상법을 이용한 부영양저수지의 수질개선)

  • Kim, Ho-Sub;Jung, Dong-Il;Lee, Il-Kuk;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.38 no.3 s.113
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    • pp.372-381
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    • 2005
  • This study was conducted to test the efficiency of water quality improvement using the dissolved air flotation (DAF) technique in a shallow eutrophic reservoir. The application of DAF was followed by the addition of a chemical coagulant (poly aluminum chloride; PAC). The experiment was conducted in the mesocosm scale (wide ${\times}$ length ${\times}$ depth: 6 m ${\times}$ 6 m ${\times}$ 3 m). Suspended solids (SS) and volatile SS (VSS) concentration decreased by 54 ${\sim}$ 71% and 57 ${\sim}$ 79% of the initial concentrations, respectively. Total phosphorus and Chl- a concentration also decreased by 74 ${\sim}$ 92% and 54 ${\sim}$ 98%, respectively. BOD decreased by>86% while COD decrease ranged 29 ${\sim}$ 63%. Dissolved inorganic P (DIP) and dissolved total P (DTP) concentration decreased by 34 ${\sim}$ 88% and 62 ${\sim}$ 88%, respectively. After DAF application further onto the sediment, DIP-release rates from the sediment decreased by 17% (0.82 ${\to}$ 0.68 mg $m^{-2}$$day^{-1}$ in the oxic condition and 23% (2.27 ${\to}$ 1.76 mg $m^{-2}$$day^{-1}$) in the anoxic condition, compared to the release rate from the untreated sediment. DTP-release rate from both the oxic and anoxic sediments also decreased by 33% (5.62 ${\to}$ 3.78 mg $m^{-2}$$day^{-1}$) and 20% (6.23 ${\to}$ 4.99 mg $m^{-2}$$day^{-1}$), respectively. These results suggest that the DAF application both to the water column and onto the sediment be effective to improve water quality by removing particulate matters in the water column as well as reducing P-release from the sediment.

Environmental factors Affecting Distribution of Heterotrophic Bacteria and Chlorophyll a Content in The (마산만과 행암만 수층의 종속양양세균과 엽록소 a 함량 분포에 미치는 환경요인)

  • Sohn Jae-Hak;Ahn Tae-Young;Kim Sang -Jin
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.4
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    • pp.65-75
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    • 2000
  • The roles of environmental factors affecting on heterotrophic bacterial distribution at Hangam Bay and Masan Bay in which occurred frequently red tide, during June to November 1996 were investigated. The aquatic environment of Masan Bay and Haengam Bay showed difference in the contents of inorganic nutrients. Haengam Bay may be defined as nitrogen limited aquatic environment. On the other hand, Masan Bay appeared to the appropriate N/P molar ratio of mean 15.9 during the periods of study. By the results of simple regression, chlorophyll a showed significant correlation with precipitation (r=0.813, P<0.05) and phosphorus (r=0.846, P<0.05) at Haengam Bay, but not showed significant correlation with parameters at Masan Bay. The heterotrophic bacteria showed significant correlation with many environmental parameters at Masan Bay (Precipitation, r=0.990, P<0.01 : NO₃-N, r=0.901, P<0.05 : Dissolved inorganic nitrogen, r=0.899, P<0.05 ; N/P molar ratio, r=0.952, P<0.05 : Salinity, r: -0.934, P<0.05) than Haengam Bay (SiO₃-Si, r=0.960, P<0.01). By the results of multiple regression, the chlorophyll a was varied with only 2 factors in Masan Bay (R²=0.100) and 3 factor in Haengam Bay (R²=0.903). The major factor which affected to chlorophyll a was SiO₃-Si (R²%=67.8) in Masan Bay, and -N/P (R²%=37.6) in Haengam Bay. The heterotrophic bacteria were varied with 4 factors in Masan Bay (R²=100) and 2 factor in Haengam Bay (R²%=0.878). The major factor, which affected to heterotrophic bacteria, was SiO₃-Si (R²%=42.3) and salinity (R²%=32.1) in Masan Bay, and SiO₃-Si (R²%=76.3) in Haengam Bay. Resultingly, the influx of freshwater in Masan and Haengam Bay was enriched in inorganic nutrients, and plays an important role in the change of heteroterophic bacteria and chlorophyll a during early summer to autumn.

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Environmental Conditions of Sediment and Bottom Waters near Sediment in the Downstream of the Nagdong River (낙동강 하류 수계에서 저층수 및 저질퇴적층의 환경)

  • Jung, Ha-Young;Cho, Kyung-Je
    • Korean Journal of Ecology and Environment
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    • v.36 no.3 s.104
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    • pp.311-321
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    • 2003
  • We surveyed physico-chemical properties of bottom water and sediment to evaluate the influence of sediment on the eutrophication in the downstream of Nagdong River from 1998 to 2000. From May to August, DO concentration of bottom waters dropped below 5 mg $O_2/l$ and $NH_4\;^+$ and $PO_4\;^{3-}$ concentrations significantly increased in the bottom waters, resulting in the great differences between surface and bottom waters. Fluxes across water-sediment interface would be substantially active in this period. The serial orders of the water fertility or eutrophication were Joman River > Sonagdong River > Nagdong River. The organic nutrient contents of sediment increased toward the lower parts of the river system. Organic contents of the sediment would be under the influence of water pollution and exhibited a negative correlation with sediment bulk-density or particle size. The concentrations of exchangeable inorganic nutrients of sediment were greater than those of pore waters, and $PO_4\;^{3-}$, $NH_4\;^+$ and $SiO_2$ increased along the sediment depth. $PO_4\;^{3-}$ and $NO_3\;^-$ concentrations of the pore water were less than the overlying waters, while NH4+ and $SiO_2$ concentrations showed opposite trends. Exchangeable nutrients of sediment could be the repository for t]me nutrient exchange in the water-sediment interface.

A Study on the Inflowing Pollution Load and Material Budgets in Hampyeong Bay (함평만의 유입오염부하량 및 물질수지에 관한 연구)

  • Kim, Jong-Gu;Jang, Hyo-Sang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.1
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    • pp.1-10
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    • 2016
  • In this paper, an analysis of the inflowing pollution load of the rivers in Hampyeong bay showed the average organic matter pollution loads of BOD, COD, and TOC to be 79.7 kg-BOD/day, 144.06 kg-COD/day, and 93.0 kg-TOC/day, respectively. The inflowing organic matter pollution load was the heaviest in Sonbul dike, followed by Jupo bridge and Yangman complex. With regard to season, the load characteristics were outstanding in July, the rainy period in the summer. The average inflowing pollution loads of nutrients were 20.9 kg-DIN/day, 17.1 kg-DIP/day, 148 kg-TN/day, and 37.4 kg-TP/day A comparison of the inflowing nutrients loads for each river showed the load to be the heaviest in Yangman complex, followed by Baegok bridge and Jupo bridge. In the experiment on the material budgets of Hampyeong bridge conducted using a box model, the detention time of fresh water was found to be 52.4 days, with the bay displaying the characteristics of a so dissolved inorganic nitrogen (DIN) in the nutrients material budgets, ${\Delta}DIN$ values were found to be negative, indicating the tendency of consumption and open sea leak by photosynthesis to be higher than the nitrogen that flowed in. As for dissolved inorganic phosphorus (DIP), ${\Delta}DIP$ showed positive values, indicating a tendency for accumulation as the supply through organic matter decomposition, elution load of sediments, and inflowing load of the river turned out to be higher than the consumption by phytoplankton and outflow to open sea.

A Study on the Quantitative Recovery of Dissolved Inorganic Carbonates in Ground Water for Radiocarbon Measurement (방사성탄소 측정을 위한 지하수 중에 용존된 무기탄소 화합물의 정량적 회수 연구)

  • Chun, Sang-Ki;Woo, Hyung-Joo;Cho, Soo-Young;Kim, Nak-Bae;Lee, Jong-Dae
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.284-289
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    • 1999
  • Dissolved inorganic carbonates in ground water were quantitatively recovered by using gas evolution method. Gas evolution method was found to be less time-consuming, less susceptible to the contamination fromatmospheric $CO_2$ and little affected by the sulfate ions in comparison to the direct precipitation method. Extraction efficiency of nearly 99% could be achieved by gas evolution method in two hours using recirculated gas at a sweeping rate of 4 liter per minute. Samples for carbon isotope fractionation study were collected in three fractions with collection times. The evolution time for the first fraction was one hours, and then second and third fractions were collected at intervals of 30 minutes, respectively. A small portion of each fraction was analyzed to evaluate ${\delta}^{13}C$ values, which were measured to be -7.9‰, -3.0‰ and +0,4‰ for the each fraction. The result clearly indicated that gas evolution method generates isotopically lighter carbon at the beginning of the purging process and heavier isotopes at the end. However, this isotope fractionation effect could be neglected by the almost complete recovery of carbonates.

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Studies on Ciliary Activity of Bivalve, Tapes philippinarum , During Developmental Stages (성장단계에 따른 이매구, Tapes philippinarum 의 직모 연동능에 관한 연구)

  • 최기철;이춘구
    • The Korean Journal of Zoology
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    • v.4 no.2
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    • pp.1-6
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    • 1961
  • 바지락(Tapes philippinarum) 직모연동능에 미치는 몇가지 중요한 환경 요인의 영향에 관하여 생리학적 방법으로 조사하였다. 1. 산화환워전위 측정결과, 치매일수록 성매에 비하여 무기상태에 대한 저항성이 낮았다. 2. 치매의 직모연동능은 17$\pm$1$^{\circ}C$에서 산소장력 저하상태로 \ulcorner긴 20분후, 성매의 약 1/2 이하로 감소되었따. 3. 한편 수온 13$\pm$1$^{\circ}C$dpt는 직모운동능이 같은 산소장력의 저하에 의하여서도 성매 치매 모두가 비슷한 경향으로 급격히 억제되었다. 4. 수온 1$0^{\circ}C$에서 20 $^{\circ}C$로 옮겼을 때 성매와 치매의 직모연동능은 수온으로 인하여 거의 평행하게 최고치 약 2305까지 촉진되었다. 5. 특히 치매에 있어서는 부유토분자의 낮은 혼촉도에 의하여 직모연동능이 감소되었다. 6 바지락은 광감성물질임을 밝혔다. 7 . 이들 결과로서 치매의 높은 치사율은 해저서식지의 불리한 환경요인 특히 중량요인에 좌우되는 것임이 확실하다. 치사율을 좌우하는 가장 중요한 요인은 용존산소의 결지, 저온 그리고 심한 부유토의 온촉도이며 반하여 약간의 염도변동은 그리 치명적인 것이 아니다.

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The Distribution of phosphorus in the Gomso Bay Tidal Flat (곰소만 조간대에서 인의 시공간적 분포)

  • 양재삼;김영태
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.7 no.3
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    • pp.171-180
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    • 2002
  • The temporal and spatial distributions of phosphorus have been investigated in the Gomso Bay, Korea. TP, PIP, TOP and DIP in sediment were found 548.8mg P kg$^{-1}$ , 426.1mg P kg$^{-1}$ , 122.6mg P kg$^{-1}$ , and 0.217mg P kg$^{-1}$ , respectively with a decreasing order of PIP>TOP>DIP. Any temporal or spatial trend has not been found on the distribution of TP in the sediment, except the high TP values near the mouth of Julpo-chun. We found seasonal patterns high TOP(28.90% of TP) and low TIP(71.10% of TP) in August, but low TOP(15.63% of TP) and high TIP(84.38% of TP) in November. There were three times higher DIP concentration in August than in November. Such case is probably not only due to the enhanced supply of DIP directly from the decomposition of organic matter from overlying water in summer, but also the released phosphate from the adsorbed particulate matter such as PIP under the low pH and Eh conditions at the subsurface layers of the sediment induced by the active microbial respiration of increased organic materials in summer. Primarily, the source of phosphorous from municipal sewage strongly influenced the early stage of the distribution of all the phosphorous in the Gomso tidal flat. Notwithstanding, through the processes of diagenesis in sediment, water temperature and organic contents probably functioned as the key parameters to control the temporal distributions of TOP, TIP and DIP in the Gomso tidal flat.

The Significance and Management of Hyporheic Zone (지표수-지하수 혼합대 의의와 관리 필요성)

  • Ko, Dongwoo;Lee, Namjoo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.283-283
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    • 2021
  • 혼합대는 지표수와 지하수의 수리적 교환이 일어나는 경계부로써 1) 수문학적 관점에서는 하도와 하상간의 물교환이 이루어지는 공간으로 다양한 물리적·화학적 작용이 발생, 2) 생지화학적인 관점에서는 하상 간극수 흐름에 의한 전이대(ecotone)를 형성하여 용존산소·영양물질·용존유기탄소의 이동뿐만이 아니라 지하수로부터 열에너지·무기염류의 공급을 유도하면서 높은 생지화학적 활동과 변환을 야기하는 산화·환원 반응구역, 3) 생태적인 관점에서는 저서생물과 지하 유기체종을 특징으로 하는 서식지이나 잠재적인 레퓨지움(refugium) 등의 관점에서 해석될 수 있다. 국내 하천환경의 생태학적 지속가능성을 위한 지표수-지하수 혼합대 관리에 대한 중요성이 점차 증대되고 있지만 우리나라는 여전히 지하수의 이용 및 보전과 지하수의 안정적인 수량·수질 확보를 목표로 관리를 추진하고 있다. 따라서, 실질적인 지표수-지하수 혼합대에서 발생하는 다양한 현상의 이해나 관리방안에 관한 연구는 아직 미비한 상황이다. 지표수-지하수 혼합대에 관한 보고서, 논문 등을 종합하여 혼합대의 영향인자를 살펴보면 1) 수리수문 특성에는 수리전도도·하천 수위·하천 유속·하천수 수온, 2) 수질 특성에는 유기오염물질·영양염류, 3) 수생태 특성에는 대형무척추동물 등으로 분류할 수 있다. 지금까지 단일 연구분야의 접근방법으로 다양한 현장측정기법 및 모델링을 통한 혼합대 연구가 수행되고 있지만, 혼합대가 가지는 환경적 중요성에 대한 이해와 인식이 부족하고, 혼합대 내부에서 발생하는 복합적인 프로세스로 인해 전문가들조차 연구에 어려움을 가질 것이다. 지표수-지하수 혼합대의 효율적인 관리를 위해서는 수리수문·수질·수생태 등 다양한 시각에서 접근하여 학제간 융합연구를 통해 기초 데이터를 상호교환하고, 기존의 혼합대 조사에 부족한 부분을 해결할 필요가 있다. 향후 하천 기저유출 및 혼합대 기초자료 구축, 혼합대 흐름 정량화, 하천복원사업에 의한 혼합대 영향 규명 등의 연구를 수행함으로써 혼합대를 체계적으로 관리할 수 있는 기술 방안을 제시할 필요가 있다.

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