• Title/Summary/Keyword: 용융염 전해

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Performance Analysis of Pyrotechnic Devices on the Reliability of Thermal Batteries (열전지의 신뢰성에 미치는 파이로테크닉 부품의 특성분석)

  • Cheong, Hae-Won;Kang, Sung-Ho;Kim, Kiyoul;Cho, Jang-Hyeon;Ryu, Byungtae;Baek, Seung-Su
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.116-123
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    • 2019
  • Thermal batteries are also called molten-salt batteries as the electrolyte is mainly composed of molten salt. The molten-salt electrolyte is a solid that does not conduct electricity at room temperature, but when it is melted by a pyrotechnic heat source, it becomes an excellent ionic conductor. Thermal batteries are a kind of pyrotechnic battery because they operate only when the solid electrolyte is melted by the heat energy provided by pyrotechnic materials. Pyrotechnic components used in a thermal battery include heat sources, fuse strips, and an igniter. The reliability of these pyrotechnic components critically affects the reliability and performance of the battery that must supply electricity stably to guided munitions even under extreme environmental conditions. Different igniter types offer different advantages: notch-type igniters offer improved ignition probability, whereas film-type igniters offer improved safety. The addition of metal oxides to the heat paper could improve the burn rate, and the ignition reliability could be greatly improved by using it with a flame igniter at the same time. Using a two-step reduction process, high-purity Fe particles in coral form can be safely obtained.

Reductive reaction of U and Lanthanides using Cd-Li metal in LiCl-KCl Molten Salt (LiCl-KCl 용융염에서 Cd-Li 금속을 이용한 U 및 란탄족의 환원반응)

  • 우문식;이병직;김응호;유재형
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.339-339
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    • 2004
  • 원자로를 이용하여 장수명핵종(long lived nucleus)을 소멸처리하는 과정에서 초우라늄(TRU, transuranium)과 희토류(RE, rare earth) 금속에 포함되어 있는 소량의 핵분열성(fissile) 물질인 우라늄을 제거할 필요가 있다. 본 실험은 LiCl-KCl 용융염계에서 전해제련법(Electrowinning)을 이용하여 용융염욕에 존재하는 우라늄을 제거하기 위하여 필요한 Cd-Li 양전극 물질을 제조하였고, 제조된 금속을 이용하여 우라늄 및 란탄족(Dy, Ce, Y, Nd, Gd) 금속의 환원 특성을 파악하였다.(중략)

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Comparison of Two-Types Compositions of Mixed Salts in Fused Salt Electrolysis of Magnesium (마그네슘의 용융염전해시(熔融鹽電解時) 두 가지 염욕조성(鹽浴組成)의 비교실험)

  • Park, Hyung-Kyu;Park, Jin-Tae;Choi, Young-Yoon
    • Resources Recycling
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    • v.15 no.2 s.70
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    • pp.32-36
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    • 2006
  • Magnesium has been used as light and functional material, and its demand is increasing as a material for automobile engine and for mobile phone or notebook PC case. Fused salt electrolysis and thermal reduction are regarded as main methods for the extraction of magnesium, and choice for the method is firstly according to raw material. In this study, magnesium metal is obtained by an electrolysis of magnesium chloride. Two types of fused salt mixtures were used as electrolyte and electrolyzed at 7V with a graphite anode having the same depth, and their results were compared with each other. A mixed salt of $KCl/NaCl/MgCl_2$ was the more effective than $KCl/NaCl/CaCl_2/CaF_2/MgCl_2$ in current efficiency through the experiments at $760^{\circ}C$. Purity of the prepared magnesium metal was above 98%. Some basic data for scale-up of the magnesium electrolysis equipment, which would be necessary for a commercialization, could be obtained.

Preparation of La0.5Nd0.5Ni5 Alloy by an Electrochemical Reduction in Molten LiCl (LiCl 용융염에서 전해환원법을 통한 La0.5Nd0.5Ni5 합금 제조)

  • Lim, Jong Gil;Jeong, Sang Mun
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.145-149
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    • 2015
  • The electrochemical behavior of $Nd_2O_3-La_2O_3-NiO$ mixed oxide including rare earth resources has been studied to synthesize $La_{0.5}Nd_{0.5}Ni_5$ alloy in a LiCl molten salt. The $Nd_2O_3-La_2O_3-NiO$ mixed oxide was converted to $NiNd_2O_4$ (spinel) and $LaNiO_3$ (perovskite) structures at a sintering temperature of $1100^{\circ}C$. The spinel and perovskite structures led a speed-up in the electrolytic reduction of the mixed oxide. Various reaction intermediates such as Ni, $NiLa_2O_4$ were observed during the electrochemical reduction by XRD analysis. A possible reaction route to $La_{0.5}Nd_{0.5}Ni_5$ in the LiCl molten salt was proposed based on the analysis result.