• Polymer(Korea)
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• v.25 no.1
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• pp.122-132
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• 2001

Thermoplastic film infusion process was investigated by using a rubber tool, which intrinsically contains a thermally-expandable characteristic and effectively compensates for the pressure loss caused by thermoplastic polymer infusion. Increasing temperature up to the melting temperature of matrix, the polymer melt subsequently infused into the dry fabric, but the pressure was successfully sustained by the rubber tool. Even with the decreased resin volume, the rubber tool produced sufficiently high elastic force for continuous resin infusion. Combining D'Arcy's law with the compressibility of rubber tool and elastic fiber bed, a film infusion model was developed to predict the resin infusion rate and pressure change as a function of time. In addition, the film infusion process without the rubber tool was viewed and analyzed by a compression process of the elastic fiber bed and viscous resin melt. The compressibility of fiber bed was experimentally measured and the multiple-step resin infusion was well described by the developed model equations.

• Polymer(Korea)
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• v.24 no.4
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• pp.513-519
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• 2000

The effect of petroleum resin as a tackifier for polyalphaolefin (APAO) hot melt adhesive on thermal properties, crystallinity and adhesion strength was investigated. The presence of petroleum resin resulted in the melting temperature decrease in APAO/petroleum blend, especially, in APAO with low ethylene content/C$_{5}$ petroleum blend. It was also found that petroleum resin caused the decrease of crystallinity regardless of ethylene content in APAO. The maximum adhesion strength was found to be at 50/50 (APAO/petroleum) composition. $C_{5}$ resin was more effective to increase adhesion strength than $C_{9}$ for APAO with high ethylene content. In addition, it was found that the adhesion strength was improved with the decrease of crystallinity in APAO/petroleum resin hot melts.

• Fire Science and Engineering
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• v.31 no.6
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• pp.83-90
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• 2017

If an overcurrent exceeding the rated value is applied to an electric wire, the temperature of the electric wire increases, and the electric wire covering deteriorates to cause a short circuit. The upper limit temperature of the wire varies according to the magnitude of the overcurrent. When a short circuit occurs at each upper temperature limit, a cooling speed difference occurs during the solidification process due to the temperature difference between the short circuit temperature and the wire surface temperature. At this time, the pattern characteristics of the dendritic structure formed on the molten cross section are different. In this study, the upper temperature limit, which varied according to the overcurrent magnitude, was measured. At the time a short circuit occurred, the second branch spacing (dendrite Arm Spacing : DAS) of the dendrite was analyzed and the numerical value was quantified. The experimental results showed that the upper temperature limit increases with the magnitude of the overcurrent, and that the second branch spacing increases with increasing wire temperature.

• Journal of Adhesion and Interface
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• v.15 no.4
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• pp.145-150
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• 2014

Dicyclopentadiene (DCPD)-based hydrocarbon resins are widely used as tackifiers in many applications. In particular, hydrogenated DCPD-based hydrocarbon resins are widely used in premium hot-melt-type adhesives such as hot melt adhesives (HMAs) and/or hot melt pressure-sensitive adhesives (HMPSAs), because are water-white in color and possess excellent stability to light and heat. This article discusses the adhesive performance of various hydrogenated DCPD resins when they are used as tackifiers in styrene-block-copolymer (SBC)-based HMPSAs. This article shows the correlation between the characteristics of tackifiers and the adhesive performance of SBC-based HMPSAs. The higher the softening point of the tackifier, the higher is the $T_g$, softening point, and crossover temperature of the PSAs. High aromatic H wt% content reduces the high-temperature resistance of PSAs, as suggested by the decrease in the crossover temperature and softening point of the PSAs.

• Composites Research
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• v.16 no.2
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• pp.33-40
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• 2003

In order to overcome one of the most pronounced shortcomings of conventional laminated composites, such as the low damage tolerance due to delamination, the thermoplastic materials and 3D (three-dimensional) preforms have been utilized in the manufacture of composite materials. From the newly developed process termed as the co-braiding, hybrid yarns of the thermoplastic fibers (PEEK) and reinforcing fibers (carbon) have been fabricated. In order to further enhance the delamination suppression, through thickness fibers have been introduced by way of 3D weaving technique in the fabrication of textile preforms. The preforms have been thermoformed to make composite materials. Complete impregnation of the PEEK into the carbon fiber bundles has been confirmed. For the comparison of mechanical performance of 3D woven composites, quasi-isotropic laminates using APC-2/AS4 tapes have been fabricated. Tensile and compressive properties of both the composites have been determined. Furthermore. the open hole, impact and CAI(Compression After Impact) tests were also carried out to assess the applicability of 3D woven textile reinforced thermoplastic composites in aerospace structures.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.397-401
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• 2008

To verify model adaptation and flexibility, non-isothermal simulation for perlite expansion has been carried out. Temperature-dependent perlite properties are applied to energy equations for bubble temperature change and perlite melt temperature gradient. Bubble temperature is changed with volume change, water evaporation, and heat flux from melt. Temperature gradient of perlite melt is affected by decreasing bubble temperature. As a result, prediction model and code have been developed below 1100 K with 5% accuracy. At 1100~1400 K, lower 7% accuracy has been obtained from the calculation results.

• Polymer(Korea)
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• v.24 no.6
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• pp.820-828
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• 2000

In this study, biaxially oriented film process was used to improve barrier property of polypropylene (PP)/ethylene-vinyl alcohol copolymer (EVOH) blends by inducing a laminar morphology of the dispersed phase in the matrix phase. In order to examine the extent of deformation during melt extrusion process, the rheological properties of the resins were measured and the viscosity ratio of the dispersed phase to the continuous phase was determined. The effects of compatibilizer content, draw ratio, and draw temperature on the oxygen permeability and morphology of biaxially drawn blend films were studied. The laminar morphology of the EVOH phase with a larger area of thinner layer induced by biaxial orientation was found to result in a significant increase in oxygen barrier property of PP/EVOH (85/15) blends by about 10 times relative to the pure PP When both PP-g-MAH and ionomer were used as the compatibilizers, there existed an optimum level of compatibilizer content for obtaining improved barrier properties with a well developed laminar structure. In addition, higher draw ratio and draw temperature were found to be more favorable processing conditions in obtaining higher barrier blends.

• Proceedings of the KIEE Conference
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• 2015.07a
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• pp.1130-1131
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• 2015

팰릿 형태의 XLPE (Cross-Linking Polyethylene)를 Hot Press로 시험편을 제작하여 열분석 데이터 처리장치를 이용하여 시차 주사 열량법 (differential scanning calorimetry, DSC)과 열 중량 분석 (Thermo gravimetric analysis, TGA) 등으로 열적 특성을 분석하였다. 분석 결과, XLPE의 전이온도 피크는 $61^{\circ}C$, 용융온도에 해당하는 피크는 $102^{\circ}C$에서 나타났으며 XLPE의 TG 분석 결과 $470^{\circ}C$ 근처에서 한 번의 급격한 열중량 감소를 보였으며 $800^{\circ}C$까지 측정 후 잔류물은 완전 분해되어 거의 존재하지 않았음을 알 수 있었다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.10
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• pp.42-47
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• 2017

In this study,we conducted an injection molding analysis of metal powder materials for the development of flanges, which are necessary adapters for optical communication. The metal powder injection molding process is a technique for producing an injection molded article having a complicated shape by mixing ceramic or stainless powder and binders. It is used to produce products which require complex processing technology or for which the productivity is low. The purpose of this study is to minimize the manufacturing processing of products which are manufactured through existing mechanical processing procedures. For the injection molding analysis, we mixed stainless STS316 metal powder with binders at a ratio of 6 to 4 to make molding materials consisting of granular pellets. Then, three-dimensional modeling and meshing were carried out to obtain the optimal injection molding analysis conditions(molding temperature, melting temperature, injection time, injection temperature, injection pressure, packing time and cooling time). As a result of the analysis, it was discovered that the inlet became available 13.29 seconds after the first injection. Also, as the flowing and packing in the melt through the sprue, runner and gate were stable, it is expected that good molds can be manufactured.

• Elastomers and Composites
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• v.38 no.3
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• pp.213-226
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• 2003

The cure and rheological behavior of diglycidyl ether of bisphenol F/nadic methyl anhydride resin system with the kinds of imidazole were studied using a differential scanning calorimeter (DSC) and a rotational rheometer. The isothermal traces were employed to analyze cure reaction. The DGEBF/ anhydride conversion profiles showed autocatalyzed reaction characterized by maximum conversion rate at $20{\sim}40 %$ of the reaction. The rate constants ($k_1,\;k_2$) showed temperature dependance, but reaction order did not. The reaction order (m+n) was calculated to be close to 3. There are two reaction mechanisms with the kinds oi catalyst. The gel time was determined by using G'-G" crossover method, and the activation energy was obtained from this results. From measurement of rheological properties it was found that the logarithmic 1:elation time of fused silica filled DBEBF epoxy compounds linearly increased with the content of filler and decreased with temperature. The highly filled epoxy compounds showed typical pseudoplastic behavior, and the viscosity of those decreased with increasing maximum packing ratio.