• Title/Summary/Keyword: 용융결합

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Effect of glass-infiltration treatments on the shear bond strength between zirconia and ultra low-fusing porcelain veneer (글라스 용융침투 처리가 지르코니아와 초저온 소성 도재와의 전단결합강도에 미치는 영향)

  • Yim, Eun-Kyung;Park, Sang-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.56 no.4
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    • pp.269-277
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    • 2018
  • Purpose: This study examined the effects of glass infiltration treatments on the shear bond strength (SBS) between zirconia core and ultra low-fusing porcelain veneer. Materials and methods: The zirconia specimens were classified into 4 groups (n = 12): Untreated zirconia (group Z), zirconia coated ZirLiner (group ZL), glass-infiltrated zirconia (group ZG), glass-infiltrated and sandblasted zirconia (group ZGS). A cylinder of ultra low-fusing veneer porcelain was build up on each disk ($6mm{\times}3mm$). SBS was measured using a universal testing machine. Scanning electron microscope and Energy Dispersive X-ray spectroscopy were used to evaluate the surface of zirconia and failure pattern after SBS. Results: SBS value of group ZGS was significantly lower than that of other groups (P < .05). No significant differences were detected among group ZL, group Z and group ZG. Conclusion: Glass infiltration is not effective to the bond strength between zirconia and ultra low-fusing porcelain veneer. Sandblasting also dramatically decreased the bonding strength.

Effect of Sodium Stearoyl Lactylate on Complex Formation with Amylopectin and on Gelatinization and Retrogradation of Wheat Starch (Sodium Stearoyl Lactylate가 아밀로펙틴과의 결합물 형성 및 밀전분의 호화와 노화에 미치는 영향)

  • Jang, Jae-Kweon;Lee, Yun-Hyung;Lee, Seok-Hoon;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.500-506
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    • 2000
  • The effects of sodium stearoyl lactylate(SSL) on the thermal properties of wheat starch and amylopectin, and the crystallinity properties of amylopectin were investigated using differential scanning calorimetry(DSC) and X-ray diffractometer. On the rescan(second heating), amylopectin produced the featureless thermogram shown at the second heating, and SSL alone melted at $40{\sim}55^{\circ}C$, while the mixture of amylopectin containing 8% water and SSL(10:1), presenting the evidence of AP-SSL complex, showed differentiate melting temperature(other crystallinity) from SSL alone. Also, the melting enthalpy of AP and SSL mixture by subsequent heating and cooling were continuously increased. Further, the mixtures of wheat starch: SSL (5:1, w/w) and amylopectin: SSL(5:1, w/w), indicated AP-SSL complex, showed the reversible melting peak at temperature range of $60{\sim}70^{\circ}C$ together with melting peak of SSL observed at temperature range of $40{\sim}55^{\circ}C$. AP-SSL complex in the X-ray diffraction, compared V-form of amylose-lipid complex, exhibited characteristic peaks($2{\theta}$, 5.57, 20.903, 23.227). The gelatinization enthalpy value of wheat starch in the presence of SSL, observed at temperature range of $50{\sim}70^{\circ}C$, was decreased at total water content 60%, whearas had no significant effect at total water content 40, 50%, and also, SSL increased melting enthalpy of amylose-lipid complex. The extent of AP and wheat starch retrogradation wasreduced significantly by SSL.

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Semi-Continuous Electrowinning of LiCl-$Li_2O$ Molten Salt (LiCl-$Li_2O$ 용융염에서의 리튬의 반연속적 전기정련)

  • Jin-Mok, Hur;Chung-Seok, Seo;Sun-Seok, Hong;Dae-Seung, Kang;Seong-Won, Park
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.211-217
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    • 2004
  • A Li recovery technology has been developed and related experimental verification efforts were carried out to improve the economical viability and environmental friendliness of the 'Advanced Spent Fuel Conditioning Process' being developed at KAERI. This technology is characterized by the combination of 1) the electrolysis of $Li_2O$ in a molten salt by using a porous non-conducting magnesia container at the cathode, 2) the separation of the Li in the container from the molten salt by elevating the container above the level of a molten salt, 3) the transport of the Li in the container by using a vacuum siphon to a separated reservoir. Li was semi-continuously recovered from a LiCl-$Li_2O$ molten salt with a more than 95% yield by using the developed technology.

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Elastic Response of Filled and Unfilled Green Rubbers (충전 및 미충전 미가교 고무의 탄성반응)

  • Lee, K.Y.;Shin, S.;Chung, K.H.;Yoon, T.H.;Kaang, S.
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.273-280
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    • 2003
  • Elastic responses on both pure natural rubber melts with different molecular weights and the rubber compounds mixed with various types of carbon blacks were investigated in this study. Furthermore, the degree of bound rubber was measured for various carbon blacks with different sizes and structures in order to study the interaction between the rubber and carbon blacks, and to study the correlation between the interaction and the elastic responses. As a loading amount of carbon black increased, the degree of bound rubber became higher, particularly far carbon-black particles with smaller sizes and higher structures. The elastic responses of the rubber melt filled with carbon black remarkably improved, as compared with those of unfilled rubber melt, specially in carbon black showing higher contents of bound rubber. Stress relaxation was more delayed and recovery behavior became more elastic, as the molecular weight of the rubber melt increased and the size of carbon-black particles was decreased. Permanent set became higher, as the molecular weight of the rubber melts decreased and the size of carbon-black particles increased.

Preparation of Poly(vinyl Alcohol) Film by Melt Process Using Powder Iodinated at Aqueous Solution (수용액 상태에서 요드화한 폴리비닐알코올 분말의 용융가공에 의한 필름성형)

  • 임현희;신은주;이양헌
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.447-450
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    • 2002
  • 폴리비닐알코올(PVA)은 -OH기에 의한 강력한 분자간 및 분자내 수소결합으로 인해결정화가 잘되고 유리전이온도(T$_{g}$) 및 융점(T$_{m}$ )이 높다는 장점을 가지지만, 같은 이유로 가공성이 좋지 못하다는 문제점을 지니고 있어, 선상 고분자임에도 불구하고 용융가공이 불가능하여 거의 대부분 용액가공을 이용하고 있어 가공성에 제한을 받는다[1]. 그러나 비 결정영역 뿐 만 아니라 결정영역까지 침투할 수 있다고 알려진 요드를 가소제로 사용하면 고분자 분자들 사이의 간격을 넓히고 분자간 결합을 약화시킴으로써 T$_{g}$뿐 아니라 T$_{m}$ 도 저하시킬 가능성이 있다. (중략)

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Effect of Surface Treatments and Glazing Temperatures on Bond Strength and Color Reproducibility in Titanium-Ceramic Prosthesis (티타늄의 표면처리와 저온용융도재의 글레이징 온도에 따른 티타늄-세라믹 보철물의 전단결합강도와 색조재현성)

  • Chung, In-Sung;Lee, Do-Chan
    • The Journal of the Korea Contents Association
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    • v.10 no.11
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    • pp.243-250
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    • 2010
  • The bonding strength and color reproducibility of titanium-ceramic prosthesis were analyzed the effect according to the surface treatments of titanium and the glazing temperatures of the low fused porcelain. The result of bonding strength compared with respect to the surface treatments was observed that the STB1 group coated by TiN had strongest boding strength and then came the SB1 group used special bonding agent, the SGB1 group coated by gold in that order. The bonding strength by the glazing temperature was indicated that the group with $770^{\circ}C$ of glazing temperature was observed increasing the bonding strength as compared with it of the other group, and the group with $810^{\circ}C$ of glazing temperature was observed to be decreased the bonding strength. Glazing temperature increases, the color by the surface treatment of titanium influenced the color of titanium-ceramic on account of getting higher brightness(${\Delta}L$). As a this result, the SB1 and SGB3 groups was evaluated to has the best color reproducibility.

Transmissivity property of condition of melting temperature and added quantity of copper of phosphate glass for ir filter (Ir-filter용 인산계 유리의 용융조건과 Cu 첨가량에 따른 투과율 특성)

  • Kim, Seong-Il;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Jin-Ho;Choi, Duck-Kyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.337-337
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    • 2009
  • 가시광선영역에서 매우 균일한 높은 투과성뿐만 아니라 근적외선영역에서 가파른 홉수성 엣지와 함께 낮은 투과율을 제공하는 산화구리(II)를 함유하는 포스페이트 유리는 컬러 비디오 카메라의 컬러 보정 필터, 발광 컬러 디스플레이용 보호판(sheild), 모노크로메이터의 미광 필터, 플라스틱 복합재 필터의 무기 성분 및 CCD(전하 결합 소자) 및 CMOS(상보성 금속 산화물 반도체) 카메라 및 검출기 분야용 필터 유리로서 사용된다. 용융온도 및 산화구리(II) 첨가량에 따른 투과율을 측정하기 위해 포스페이트 유리 시료를 $1100\sim1500^{\circ}C$ 용융한 후 $400^{\circ}C$에서 2시간 동안 어닐링 공정을 거쳐 제조하였다. 제조된 시료는 두께 0.3mm로 폴리싱하여 자외선-적외선 분광 광도기를 이용하여 광학적 특성을 측정하였다. 본 실험을 통하여 용융온도에 따라 가시광선영역 및 근적외선영역에서의 투과율 거동을 비교한 결과 $1100\sim1200^{\circ}C$에서의 우수한 투과율 특성을 나타냈다. 용융온도가 내려감에 따른 가시광선영역 (400~600nm)에서 높은 투과율 및 근적외선영역 (750~1100nm)에서 낮은 투과율과 가파른 흡수성 엣지를 나타냈다.

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High Temperature Properties of Cold Bonded Pellets Based on Dusts from Steel Plants (제천 dust를 활용한 비소성펠릿의 고온특성)

  • 이상호;김석기;이창희
    • Resources Recycling
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    • v.8 no.4
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    • pp.30-38
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    • 1999
  • High 1emperiltur.e propeitles o i cold bonded pellet based on lroll beanng dusts wele invesligaled prim to using as a burden m blasl furnaces, Major conclusions ould be summarized Io llows: the cold bonded pellet needed to bc produced by the characteristic criterion on high lempemhIre prapcrttes as well as a compressive sncnglh. Basicity of cold bonded pellel shruld be linted to be appoxiiniltely 1.7 in order to maintain appropriate softcn~nga nd rnelt~ngp ropcrlies. On thc other hand. basiciq greater than 2.6 showed exce\ulcornersive puessure drop due to powder gelleratlon. Potcntialil], of blast fi~rnaccs lag as binding malerial in m a h g cold ba~~deprel llels !\.us also certified in viewpoinls of high temperature properly.

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