• Title/Summary/Keyword: 용액형

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CHEMICAL DEGRADATION OF LIGHT CURED COMPOSITE RESINS IN NAOH SOLUTION (NaOH 용액내에서의 광중합형 복합레진의 화학적 분해)

  • Kim, Jung-Ran;Jeong, Byung-Cho;Yang, Kyu-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.3
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    • pp.469-477
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    • 2002
  • One of the major deficiencies of composite restorative resins is their insufficient resistance to wear. Of the multitude of factors that have been associated with wear, subsurface degradation within the restoration is considered to be one. The aim of this study was to evaluate the resistance to degradation of four commercial composite resins in an alkaline solution. The brands studied were Z100(3M), Clearfil AP-X(Kuraray), Tetric Ceram(Vivadent), Aelit flo(Bisco). Resistance to degradation was evaluated on the basis of the following parameters: (a) mass loss(%) - determined from pre-and post-exposure specimen weights: (b) Si loss(ppm) - obtained from ICP-AE analysis of solution exposed to specimens; and (c) degradation depth(${\mu}m$) - measured microscopically (SEM) from polished circular sections of exposed specimens. The results were as follows: 1. The sequence of the mass loss was in ascending order by AE, EL, TC, Z100. There was statistically significant difference of mass loss between AE, CL group and TC, Z100 group(p<0.05). 2. The sequence of the degree of degradation layer depth was in ascending order by AE, CL, TC, Z100. But there was no statistically significant difference of degree of degradation layer depth between AE and CL(p<0.05). 3. For the Si concentration, Z100 was the highest of all. 4. The correlation coefficient between mass loss and degradation depth was relatively high(r=0.71 p<0.05).

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Comparative Study of Prolonged Preservation Methods in Rabbit Heart for Transplantation (이식을 위한 가토심장의 장기 보존방법에 관한 비교 연구)

  • Jo, Hyeong-Gon;Kim, Su-Hyeon;Kim, Song-Myeong
    • Journal of Chest Surgery
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    • v.30 no.1
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    • pp.1-10
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    • 1997
  • The successful cardiac transplantation depends partly on the donor heart preservation by a solution that will ensure recovery of myocardial function. The purpose of this study was to perform the evaluation of various preservation solutions and to accumulate the data on the requisites for ideal preservation solution. The experimental setup was the constant pressure Langendorffs perfusion system. Isolated rabbit hearts were perfused for 20minutes with unarm Krebs-Henseleit solution, stored for 4 hours in cold preservation solution after cardioplegia, and then were reperfused for 20minutes. The 4 experimental groups were prepared Hartmann's solution group (group 1, control), modified Euro-collins solution group(group II. MEC), modified University of Wisconsin group (group n, MUW), and CK solution(made by the author) group (group W, CK). The parameters for assessing the preservation ability were levels of enzymes in freezed myocardial tissues (lactate, creatine kinase-MB and adenosine deaminase), coronary flow. left ventricular developing pressure and dpldt. In conclusion, the ability of preservation for isolated rabbit heart was excellent in CK solution and modified University of Wisconsin solution, and poor in modified Euro-collins solution, compared with Hartmann solution. CK solution has low potassium concentrations(34.2mEq/L) and includes various substrates to be salutary on myocardial preservation. This fact may indicates the necessity of further refinements in selection or composition of electrolytes and substrates.

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Study of Excess Gibbs Energy for a Lattice Solution by Random Number Simulation (난수 모의실험을 통한 격자용액의 과잉깁스에너지에 대한 고찰)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.51 no.4
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    • pp.312-317
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    • 2007
  • Performing random number simulations, we approximated that the distribution of the number of ways for arranging molecules randomly on a lattice is a normal distributon for N12, the number of interactions between the nearest neighbors of different molecules. From this distribution, an approximate equation of the excess Gibbs energy GE for a lattice solution of nonrandom mixing was derived. Using the equation, liquid-vapor equilibria of several binary solutions were calculated and compared with the calculated result of other equations.

Dye Laser Oscillator with System Monitoring Longitudinal Mode of Lasing Frequency (발진된 주파수의 종모드를 모니터하는 시스템이 부착된 색소 레이저 발진기)

  • Im, Kwon;Ko, Do-Kyung;Park, Sung-Hee;Kim, Yong-Ki;Cha, Byung-Heon;Kim, Chul-Joong
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.62-63
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    • 2002
  • 파장가변 색소 레이저 발진기는 반사형 회절격자에 비스듬히 입사하는 Grazing Incidence형 공진기 구조로 설계되었다.[1-2] 색소용액이 고속으로 순환되는 색소 셀에 여기광인 레이저 광원을 입사시키는 방법은 색소 셀과 색소 용액 순환방향 및 펌핑 광의 방향이 서로 수직을 이루도록 구성되어 있다. 또한, 두 개의 펌핑 광을 양방향에서 동시에 입사시킬 수 있도록 함으로써, 색소 셀 내부의 색소 용액이 여기 광을 균일하게 흡수하도록 설계하였다. (중략)

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Fabrication of CIS absorber layer by non-vacuum precursor solution coating technique (용액 코팅법에 의해 제조된 저가형 CIS박막의 특성연구)

  • Kim, Chae-Woong;Ahn, Se-Jin;Yun, Jae-Ho;Lee, Jeong-Chul;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.313-316
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    • 2007
  • 본 연구에서는 Cu와 In 성분을 포함하는 메탄올 용액을 닥터 블레이딩 방법으로 코팅한 후 이를 Se Evaporator 열처리하여 CIS 광흡수층을 제조하였다. $Cu(NO_{3})_{2}$, $INCl_{3}$ 를 출발 물질로 선정하고, 이를 메탄올 용매에 녹여 전구체 용액을 만든 후, 여기에 유기물 바인더 물질을 첨가하여 닥터 블레이드 코팅에 적합한 점도를 맞춘 후, 이를 Mo/glass 기판에 코팅하였다. 코팅된 Cu, In 함유 유기물 혼합체를 공기중에서 1차 열처리 한 후 Evaporator 를 이용해 Selenization 하여 태양전지용 CIS 광흡수층을 만들었다. 본 연구에서는 전구체 합성, 유기물 첨가, 공기중 열처리 및 Se 열처리 각 단계에서 광흡수층 막의 형상, 결정구조, 화학조성의 변화과정을 분석하여 CIS 박막의 형성 과정을 고찰하였다. 특히 Se 증발 온도가 CIS막의 특성과 조성에 미치는 영향을 분석하여, 최적의 셀렌화 조건을 도출하고자 하였다.

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Characteristics of Ag/AgCl Thin Film Reference Electrode in Urea Sensors (요소센서를 위한 은/염화은 박막 기준전극의 특성)

  • Jin, Joon-Hyung;Kang, Chul-Goo;Kang, Moon-Sik;Min, Nam-Ki;Hong, Suk-In
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1911-1913
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    • 2001
  • 전위차 측정형 바이오 센서는 기준전극에 대한 센서 전극의 전기화학적 전위를 정확하게 측정하여야 하므로 기준전극의 안정성이 매우 중요하다. 기준전극의 전위는 전해질 용액 내의 염소 음이온 농도에 영향을 받으나 다행히도 혈액 내의 염소 음이온 농도는 거의 변화가 없으므로 혈액 속에서의 은/염화은 기준전극의 전위도 거의 변화가 없다. 본 연구에서는, 사진석판 (Photolithography) 공정을 이용하여 실리콘 표면 및 다공질 실리콘 표면에 은/염화은 박막 기준전극을 제작하고 시료 용액에서의 drift, 안정성, 재현성 등에 대한 특성을 고찰하였고, SEM, AES, EDX 스펙트럼 등을 이용하여 전극의 표면을 분석하였다. 시료 용액의 염소 음이온 농도를 $10^{-4}$M에서 1M까지 변화시켜가며 기준 전극의 전위를 측정한 결과 약 50mV/pCl의 기울기를 얻었으며 이것은 Nernst식을 잘 따르는 결과이다.

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Simulation of the performance characteristics of the double effect Parallel flow cycle with secondary heat at the low temperature qenerator (저온재생기2열원2중효용(低溫再生器2熱源2重效用) Parallel Flow Cycle의 특성(特性) 해석(解析))

  • Choi, K.K.;Rie, D.H.
    • Solar Energy
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    • v.17 no.3
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    • pp.43-49
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    • 1997
  • Cycle simulaton of the double effect parallel flow model is applied to a Lithium-Bromide/water system, with the objective of evaluation the possibilities of effectively utilizing waste-heat as a secondary heat source for the low-temperature generator. In this study, cycle simulation has been carried out to clarify the effect heat exchange in order to predict the performance of absorption refrigeration cycles using waste heat.

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Shear Induced Homogenization Study of an Immiscible Polymer Blend Solution Using Fluorescence Microscope (형광 현미경을 이용한 비상용 고분자 블렌드 용액의 전단 균질화 연구)

  • 유재웅
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.413-420
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    • 2003
  • Fluorescence microscope technique was employed for the characterization of phase separation behavior of a 4-chloro-7-nitrobenzofurazan labeled polystyrene (PS) / polybutadiene (PB) blend in dioctyl phthalate under steady shear. It was confirmed that the fluorescence microscope images reflect the real phase morphology by comparing with the images of phase contrast microscope. Comparing the fluorescence intensities from the phase separated domain (PS rich) and continuous phase (PB rich), the composition difference between these two phases were deduced. The observed shear dependence of compositional change is then used to confirm that the phase diagram is indeed shifted under the steady shear.