• The Korean Journal of Food And Nutrition
• /
• v.12 no.6
• /
• pp.582-587
• /
• 1999

감자절편을 고농도용액에 침지하여 탈수시킨 결과 침지용액을 구성하는 용질의 분자량에 따라 탈수형태가 다르게 나타났다. 저분자 용액인 NaCl, PEG 400 용액에 침지한 경우 조직의 뒤틀림현상(cytorrhysis) 은 나타나지 않고 부피의 감소와 수분의 탈수현상이 나타난 반면 고분자 용액인 PEG 4000, PEG 6000용액에 침지한 경우 cytorrhysis 현상을 동반한 부피의 감소와 탈수현상이 나타났다. 초기 탈수속도는 저분자 용액에 침지시 더 빨랐으나 최종 탈수량은 고분자 용액에 침지시 더 컸다 고장성 용액에 감자절편을 침지시켜 탈수되는 기작이 두가지 압력(삼투압 분자압착력)에 의해 진행된다고 가정하고 모델을 제안하여 감정한 결과 제안된 모델은 고분자 용액에 침지시의 탈수현항을 설명하는데 적합하였다. 모델에서 구해진 압력인자(ΔP)와 농도인자(a)는 온도(T)와 농도(C) 의 함수로 표현되며 계수의 탄력성 검정결과 농도에 대한 의존성이 더 큰 것으로 나타났다.

• Journal of Advanced Marine Engineering and Technology
• /
• v.16 no.3
• /
• pp.42-50
• /
• 1992

다공성 물질이 충전된 밀폐용기 내에서 수용성 이원혼합용액($H_2O{+}NaCl$)이 수평한 상부전열면으로 부터 동결될 때 혼합용액의 초기농도, 액체의 과열 및 다공성물질의 입자직경 크기가 온도와 농도분포에 미치는 영향을 실험하였으며, 동결이 진행됨에 따라 이동하는 고액상 혼합영역의 계명위치를 측정하였다. 다공성물질은 평균직경이 2.85mm, 6mm인 구형의 유리구슬을 이용하였다. 수용성 혼합용액의 초기농도는 공융농도도 이하로 하였으며 상부 전열면은 공융온도 이하로, 하부전열면은 액상선온도 이상으로 유지하여 동결 실험한 결과 상부 전열면으로 부터 고체 영역, 고액상혼합영역, 액체영역으로 구분되었다. 액체의 초기농도가 5%인 경우 과냉현상이 관찰되었으나 10%, 15%인 경우 액체온도는 액상선 온도보다 더 높았다. 용액의 초기농도를 감소시킬수록 고체와 고액상혼합영역의 범위는 증대되었으며 고액상혼합영역과 고체영역의 계면은 더욱 강해진 자연대류에 의하여 2차원성이 증가된 형상을 보였다. 용액의 자연대류는 다공성물질의 직경이 클수록 증가되었으며 계면에서의 제융해현상은 관찰되지 않았다.

• Journal of Bio-Environment Control
• /
• v.14 no.3
• /
• pp.196-202
• /
• 2005

This research was conducted to determine the amount of water absorbed by a polyacrylamide hydrogel such as Stocksorb C (STSB), effect of salts on inhibition in hydration of STSB, and the hydrogel effects on changes of nutrient concentration in external solution. Absorption of deionized water by STSB reached a maximum of 180 $mL{\cdot}g^{-1}$. Monovalent soluble salts such as $KH_2PO_4,\;KNO_3$, and $(NH_4)_2SO_4$ reduced absorption of the hydrogel, but the degrees of inhibition in absorption were similar in three kinds of salts. Twenty milliequivalents per liter of $Ca_{2+}\;or\;Mg_{2+}$ reduced water absorption of STSB to $14\%$ compared to those of deionized water. Solution absorption was consistently lower in the presence of divalent cations than in the presence of the monovalent cations. But the absorption was unaffected by the uncharged salt such as urea in all concentrations tested. The final $K^+\;and\;NH_4^+-N$ concentrations of the solution remaining after absorption by STSB was higher than those of the initial solution. The soaking of STSB to full strength of Hoagland solution resulted in increase of $NO_3^--N,\;H_2PO_4^-\;and\;SO_4^{2-}$ concentrations in external solution compared to initial solution, reaching 5,300, 250 and 1,500 $mL{\cdot}g^{-1}$, respectively, at 24 hrs after soaking.

• Proceedings of the KAIS Fall Conference
• /
• 2006.05a
• /
• pp.599-601
• /
• 2006

본 논문에서는 용액의 농도가 이온교환 특성에 미치는 영향을 조사하기 위하여 농도는 $Na^+\;50$, 125, 250ppm, $Cl^-\;165$, 315, 610ppm, 입자성 물질의 유입 농도 0ppm, 유속 500ml/min, 이온교환 수지는 ROHM&HAAS IR 120 양이온 수지와 ROHM&HAAS IRA 402 음이온 수지를 사용하였다. 수지탑 배열은 혼상-혼상-음이온 수지탑 순으로, 이온교환 수지탑의 양 음이온교환 수지의 조성 비율은 1:2 로 실험한 결과 이온교환 수지탑 성능은 유입 용액 성분 및 농도에 영향을 받는 것으로 나타났다. 이온교환 수지탑 배열 순서에 따라 파과시점이 연장되며, 파과순서는 음이온의 경우 $Cl^-\;<\;NO_3\;^-\;<\;F^-$, 양이온의 경우 $Na^+\;<\;K^+\;<\;Ca^{2+}$ 순 이였으며, 용액의 농도가 증가할수록 파과시간이 단축되었다.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.6 no.4
• /
• pp.584-594
• /
• 1996

For the separation and purification of aluminium chloride hexahydrate crystals from kaolin leaching solution the effects of crystallization conditions, such as crystallization temperature, concentration of aluminium chloride concentration in the leaching solutin and gas flow rate of HCl into the leaching solution, on purity of the aluminium chloride hexahydrate crystals were investigated. The supersaturation level of aluminium chloride in the leaching solution gave great influence on the purity of the crystals. When supersaturated concentration of the aluminium chloride in the leaching solution was generated in low level, the aluminium chloride hexahydrate crystals were produced with high purity ; that is, the crystals hving a low Fe-ion concentration. The supersaturation level of aluminium chloride in the leaching solution was mainly determined by crystallization temperature, concentrations of aluminium chloride and hydrochloric acid in the solution. However, in spite of changes of the above crystallization coditions, a needle shape morphology of aluminium chloride hexahydrate crystals did not modified. To measure hydrochloric acid concentration in the kaolin leaching solution, we applied the oxalate titration method, which was suggested by shank [9] and it was prove that this method could titrate hydrochloroic acid concentration in multi-component ionic solution such as kaolin leaching solution.

• Applied Biological Chemistry
• /
• v.35 no.5
• /
• pp.399-403
• /
• 1992

The amounts of salt diffused into radish after immersing in various concentrations of salt solution at different temperatures were measured and the changes of radish texture by the salt diffusion were estimatedwith the viscoelastic constants of a 3 element solid model determined by a stress relaxation test. While the amount of salt diffused throught radish was increased with increasing the salt concentration and soaking temperature, the istantaneous stress, equilibrium elastic solid and viscoelastic constants of radish were decreased. Also the degree of stress relaxation and equilibrium elastic solid approached the same or zero values, as salt concentration was further increased. Viscoelstic constants as well as salt diffusion were more influenced by lower salt concentration with increased temperatures.

• Korean Journal of Optics and Photonics
• /
• v.13 no.1
• /
• pp.9-14
• /
• 2002

A surface plasmon sensor has been fabricated for detection of concentration and refractive-index of a mixed solution. Based on the Kretschmann-Raether attenuated-total-reflection configuration, the sensor consists of 54 nm-thick Ag metal layer under a prism and a cell containing the mixed solution. We have observed a nonlinear refractive-index change as the ethanol-water concentration increased. The experimental results show us that the detection limit of the SPR sensor is 3$\times$10$^{-2}$ % in ethanol mass ratio. The concentration-to-index curve shows a linear increase in the range of ethanol concentration from 0% to 50%, but a nonlinearity is observed beyond 50%. We have modeled the nonlinearity and compared it with the experimental results.

• Korean Journal of Fisheries and Aquatic Sciences
• /
• v.28 no.4
• /
• pp.397-400
• /
• 1995

Effects of rheological parameters, such as shear rate, temperature, concerntration, salts on the apparent viscosity of chitosan(deacetylation degree: $84\%$, Mw: 267,000) dissolved in acetate buffer(pH 4.5) were investigated. Rheologiral properties of chitosan solution from cuticle of red snow crab (Chinonecetes japonicus) are as follows. $0.5\%$ chitosan in 0.1M acetate buffer (pH 4.5) solution showed Bingham flow having hysteresis loop. It's flow equation was $\sigma=0.757+19.6_\gamma(r^2=0.99)$. The viscosity of chitosan solution is exponentially increased with its concentration, and showed Arrhenius dependence with respect to the temperature $(10^{\circ}C-40^{\circ}C).$ When various salts were added to chitosan solution, the viscosity decreased as the concentration of counterion increased. But the type ot counterions itself does not have any significant effects on the viscosity.

• Membrane Journal
• /
• v.2 no.1
• /
• pp.59-66
• /
• 1992

The experimental studies were carried out on ultrafiltration of PEG #6000 and dextran 70T macromole¬cules. using an asymmetric cellulose acetate membrane in a cross flow plane type cell. Effects of pressure difference. feed concentration were studied on permeate flux and observed rejection for both the macromole¬cules. and the concentration polarization layer resistance $R_{b1}$ on permeate flux was analysed. The concentration polarization layer resistance $R_{b1}$ was correlated with the average macromolecule concen¬tration $C_{b1}$ in polarization layer. The resulting dimensionless correlation was expressed as : $\frac{R_{b1}}{{R_m}}=\alpha[\frac{\rho_{b1}}{C_{b1}}]^\beta$

• Resources Recycling
• /
• v.12 no.4
• /
• pp.30-37
• /
• 2003

A kinetics study on the dissolution reaction of zinc-ferrite has been made with aqueous sulfuric acid in various temperature and concentration. Fraction reacted(R) and apparent rate constant(K) increased with increasing temperature and concentration of sulfuric acid solution. The rate of dissolution is shown by $1-(1-K)^{1/3}=Kt$ for the initial stage of the reaction in aqueous sulfuric acid, where K is apparent rate constant, R is fraction reacted and t is reaction time, respectively. Activation energy associated with reaction was determined to be 16.3 kcal/mole. The dissolution of zinc-ferrite in sulfuric acid solution is dissolved by sto-ichiometric composition, but Fe and Zn did not dissolved, respectively.