• Title/Summary/Keyword: 완전혼합반응기

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Degradation of Phenolic Compounds in a Slurry Reactor (슬러리 반응기를 이용한 페놀류 화합물의 분해거동)

  • Lee, Jamyoung;Jung, Yonkyu;Lee, Taejin
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.949-957
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    • 2000
  • This study investigates the remediation of the phenol or PNP(p-Nitrophenol) contaminated soils in a slurry reactor by a pure culture, P-99. The application of a pure culture for the phenol decontamination make the degradation rate three times faster than that of the mixed activated sludge. The destruction of 300 mg/L phenol was completed in 26 hours. As 1 mg of phenol was added, 0.1457 mg of microorganism was grown in the medium. The pure culture could not utilizes PNP, one of the xenobiotics, as a growth substrate. When the bacteria was induced by phenol enrichment medium. PNP could be effectively transformed with cometabolic process. The induction of the bacteria requires 1 mg of phenol for the destruction of 0.027 mg PNP. When PNP concentration in the medium contained phenol and PNP increased. the degradation rate of phenol was decreased. The degradation rate of phenol and PNP in the slurry reactor was about two times faster than in the reactor without slurry because of higher dissolved oxygen supply in the aqueous phase and adsorption on the surface of the soil.

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A Study of the Simultaneous Nitrification and Denitrification in a Single Bioreactor (단일 반응기를 이용한 동시 질산.탈질에 관한 연구)

  • Park, Jong-Il;Lee, Tae-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.220-228
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    • 2007
  • In this study, effective simultaneous nitrification and denitrification reaction was accomplished in a completely mixed single bioreactor. As the important factors on the reaction, optimal DO concentration and effective range of influent C/N ratio was investigated with the synthetic wastewater. Experimental results show that stable nitrogen removals were accomplished with 0.5 mg/L DO concentration and over 7 C/N ratio. Nitrogen removal efficiency of the real municipal wastewater was low with 0.5 mg/L DO concentration because of its low C/N ratio. The increment of the C/N ratio at the inflow of the municipal wastewater with addition of external carbon source (glucose) over 7(up to 14) shows over 70% nitrogen removal in the single bioreactor.

RTD Analysis using Radioisotope Tracer on the Water Flow Characteristics in a Flocculator of Wastewater Treatment Facility (방사성동위원소 추적자를 이용한 폐수처리시설의 응집조에서 유입수의 체류시간분포 분석)

  • Kim, Jin-Seop;Jung, Sung-Hee;Kim, Jong-Bum
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.1
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    • pp.1-6
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    • 2006
  • Using In-113m emitting gamma ray of 0.392MeV at radioisotope tracer the RTD (residence time distribution) of water in the flocculator of wastewater treatment facility was measured. The result was analyzed mathematically using K-RTD program constructed on the basis of CFSTR (constant flow stirred tank reactor) model. The mean residence time and the tank number are the main parameters which describe the flow behavior of the system. Those parameters were obtained in the fitting profess of the simulated curves to the experimental results. It was suggested to construct a modified numerical model to describe the bypass flow which was observed in the experiment.

Development of Gas Turbine Engine Simulation Program Based on CFD (CFD 기반 가스터빈 엔진 모사 코드 개발)

  • Jin, Sang-Wook;Kim, Kui-Soon;Choi, Jeong-Yeol;Ahn, Iee-Ki;Yang, Soo-Seok;Kim, Jae-Hwan
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.2
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    • pp.42-53
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    • 2009
  • Gas turbine engine simulation program has been developed. In compressor and turbine, 2-D NS implicit code is used with k-$\omega$ SST turbulent model. In combustor, 0-D lumped method chemical equilibrium code is adopted under the limitations, the products are only 10 species of molecular and air-fuel is perfectly mixed state with 100% combustion efficiency at constant pressure. Fluid properties are shared on interfaces between engine components. The outlet conditions of compressor have been used as the inlet condition of combustor. The inlet condition of turbine comes from the compressor The back pressure in compressor outlet is transferred by the inlet pressure of turbine. Unsteady phenomena at rotor-stator in compressor and turbine is covered by mixing-plane method. The state of engine can be determined only by given inlet condition of compressor, outlet condition of turbine, equivalence ratio and rotating speed.

Numerical Simulation of the Experimental Investigation of the Two Dimensional Ram Accelerator Combustion Flow Field (이차원 램 가속기 연소 유동장의 실험적 연구의 수치 모사)

  • 최정열;정인석;윤영빈
    • Journal of the Korean Society of Propulsion Engineers
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    • v.1 no.1
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    • pp.8-23
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    • 1997
  • Steady and unsteady numerical simulations are conducted for the comparison with the experiments performed to investigate the ram accelerator flow field by using an expansion tube facility in Stanford University. Wavier-Stokes equations for chemically reacting flows are analyzed by fully implicit and time accurate numerical methods with Jachimowski's detailed chemistry model for hydrogen-air combustion involving 9 species and 19 reaction steps. Although the steady state numerical simulation shows a good agreement with the experimental schlieren and OH PLIF images for the case of $2H_2$$O_2$$17N_2$ fails in reproducing the combustion region behind the shock intersection point shown in the case of $2H_2$$O_2$$12N_2$ mixture. Therefore, an unsteady numerical simulation is conducted for this case and the result shows all the detailed flow stabilization process. From the result of unsteady numerical simulation, the experimental result seems to be an instantaneous state during the flow stabilization process. The combustion behind the shock intersection point is the result of a normal detonation formed by the intersection of strong oblique shocks that exist at early stage of the stabilization process. At final stage, the combustion region behind the shock intersection point disappears and the steady state result is retained. The time required for stabilization of the reacting flow in the model ram accelerator is found to be very long in comparison with the experimental test time.

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The synthesis of silver powders with narrow particle distribution and spherical shape prepared by spray pyrolysis (분무열분해법에 의한 입자분포가 좁은 구형의 은 분말 제조)

  • 이교광;강윤찬;김중현;박희동
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.112-112
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    • 2003
  • 은분말은 전자 산업에 있어 후막 도체 페이스트의 제조를 위해 사용되어지고 있다. 후막 페이스트는, 기재상에 스크린 프린트되고, 전도성의 회로 패턴을 형성한다. 이러한 회로는, 다음에 건조, 소성되고 액체 유기 비이클을 휘발 시키고, 그리고 은 입자를 소결시킨다. 프린트 회로 기술은 점점 고밀도이면서 더욱 정밀한 전자 회로를 요구하고 있다. 이러한 요건에 적합하기 위하여 도선은 폭이 점점 좁아지고, 선의 사이의 거리가 점점 작아지고 있다. 고밀도가 조밀하게 꽉 찬 좁은 선을 위하여 은 분말은 가능한 크기가 단일하고 구형의 형태를 가져야 한다. 현재 금속 분말을 제조하는 방법으로는 화학적 환원법, 무화 또는 분쇄, 열분해법등의 물리적 과정 및 전기 화학적 과정 등이있다. 본 연구에서는 입도 분포가 좁은 구형의 은 분말을 제조하기 위하여 기상법의 하나인 분무열분해법을 도입하였다. 또한 싸이클론을 사용하므로 큰 액적들을 걸러 입도 분포를 줄였다. 은 분말의 프리커서로써는 AgNO$_3$를 사용하였고 반응기의 온도는 $700^{\circ}C$에서 100$0^{\circ}C$까지 변화시켰으며 운반기체로써는 5%H$_2$ 혼합가스로 20L/min에서 80L/min 변화시켜 은 분말을 제조하였다. 또한 용액의 농도는 0.2M에서 1.0M까지 변화시켰다. 용액의 농도가 0.2M이고 운반기체의 유랑이 40L/min일 경우 완전한 은 상이 관찰되었고, 입자의 크기는 약 600nm였다.

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Performance Evaluation of 1 N Class HAN/Methanol Propellant Thruster (HAN/메탄올 추진제를 사용하는 1 N급 추력기 성능 평가)

  • Lee, Jeongsub;Huh, Jeongmoo;Cho, Sungjune;Kim, Suhyun;Park, Sungjun;Kim, Sukyum;Kwon, Sejin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.4
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    • pp.299-304
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    • 2013
  • The HAN which is an ionic liquid is a non-toxic monopropellant with high storability, and its specific impulse can be increased by blending methanol, thereby it can substitute the hydrazine. The HAN was synthesized by acid-base reaction of hydroxylamine and nitric acid, and the blending ratio of HAN and methanol is 8.2:1. The iridium catalyst was used to decompose the HAN, and 1 N class thruster with shower head type injector having one orifice was used to evaluate the HAN/Methanol propellant. The thermal stability of distributor was increased by using ceramic material to endure the high temperature of product gas. The preheating temperature of catalyst should be $400^{\circ}C$ at least for the complete decomposition. The feeding pressure should be increased to increase the $C^*$ efficiency, thereby the decomposition performance was decreased upstream catalyst, and the performance of thruster was decreased. The fine metal mesh was inserted after the injector to improve the atomization of propellant, thereby it can settle the performance decrease problem. The phenomenon of performance decrease was remarkably improved owing to the insertion of fine metal mesh.

Chlorodifluoromethane (CHClF2) Thermal Decomposition by DC Nitrogen Plasma (질소 플라즈마 공정을 이용한 염화이불화메탄(CHClF2) 열분해)

  • Ko, Eun Ha;Yoo, Hyeonseok;Jung, Yong-An;Park, Dong-Wha;Kim, Dong-Wook;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.171-176
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    • 2017
  • The nitrogen plasma thermal decomposition and recovery processes for $CHClF_2$ (Chlorodifluoromethane) refringent were investigated. The steam generator was employed to provide superheated steam reactor, supporting the decomposition reaction of refringent. Even though over 94% of R-22 was decomposed on the condition of 60 A and 9.0 kW, a higher power and specific energy density were required to achieve the complete combustion of carbon materials. In the operating condition of 60 A and 12.6 kW, $O_2$/R-22 ratio in reactants gases are a key factor to obtain much higher decomposition ratio during process. It should be noticed that injecting the mixture of $O_2$ and air was much more effective than injecting the air consisting equivalent $O_2$ amount.

Start-up and operation of Gasoline Fuel Processor for Isolated Fuel Cell System (독립형 연료전지 시스템을 위한 가솔린 연료프로세스의 시동 및 운전)

  • Ji, Hyunjin;Bae, Joongmyeon
    • Journal of Energy Engineering
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    • v.25 no.1
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    • pp.76-85
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    • 2016
  • This study introduces the system layout and control strategy necessary to start and operate a fuel processor in a wide range of temperatures where a gasoline was selected as the fuel of fuel processor considering logistic support of Korea Army. The autothermal reformig(ATR) catalyst is heated to light-off temperature by combustion method in the initial stage. In order to ignite the gasoline and air mixture stably, the glow plug is installed after ATR catalyst. When the catalyst is increased to light-off temperature, the reformer is operated from initiation to steady state conditions as follows: Partial oxidation(POX) mode, partial ATR mode, full ATR mode. Finally the start-up and control strategy is validated by the operational test of gasoline fuel processor at low and room temperature. As a result the gasoline fuel processor is able to start-up within 40 min and to produce the reformate gas which has 37 ~ 42 vol.%(dry basis) of $H_2$ and 0.3 vol.% of CO.

An Experimental Study on the Combustion Characteristics of a Catalytic Combustor for an MCFC Power Generation System (MCFC 발전시스템용 촉매연소기의 연소 특성에 관한 실험적 연구)

  • Hong, Dong-Jin;Ahn, Kook-Young;Kim, Man-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.4
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    • pp.405-412
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    • 2012
  • In the MCFC power generation system, the combustor supplies a high temperature mixture of gases to the cathode and heat to the reformer by using the off-gas from the anode; the off-gas includes high concentrations of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and avoid local heating, a catalytic combustor is usually adopted. Catalytic combustion is also generally accepted as one of the environmentally preferred alternatives for generation of heat and power from fossil fuels because of its complete combustion and low emissions of pollutants such as CO, UHC, and $NO_x$. In this study, experiments were conducted on catalytic combustion behavior in the presence of Pd-based catalysts for the BOP (Balance Of Plant) of 5 kW MCFC (Molten Carbonate Fuel Cell) power generation systems. Extensive investigations were carried out on the catalyst performance with the gaseous $CH_4$ fuel by changing such various parameters as $H_2$ addition, inlet temperature, excess air ratio, space velocity, catalyst type, and start-up schedule of the pilot system adopted in the BOP.