• The Korean Journal of Pesticide Science
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• v.4 no.1
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• pp.32-37
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• 2000

A series of transition metal complexes of 3,6-bis(6'-methyl-2'-pyridyl)pyridazine ($L^{1}$) and 3,6-bis(2'-pyridyl)pyridazine ($L^{2}$) as artificial nuclease, $1{\sim}8$ were synthesized. After determining of X-ray crystal structure, hydrolysis rate constants of phosphates, as DNA model compound and biological activities were confirmed. $L^{2}$-Zn(II) complex, 8 was shown the best hydrolysis rate constant. The $L^{2}$-Ni(II) complex, 5 and $L^{2}$-Co(II) complex, 6 showed the highest herbicidal activity against SCP (Scriptus Juncoids) with excellent tolerance to rice, ORY (Oryzae sativa L.). And the $L^{1}$-Co(II) complex, 2, $L^{1}$-Zn(II) complex, 4 and ligand ($L^{1}$ amp; $L^{2}$) displayed above 90% fungicidal activity against MAG (Magnaporthe grisea).

• Korean Journal of Weed Science
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• v.5 no.2
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• pp.137-142
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• 1985

This experiment was conducted to know the difference in weed population in the five cropping patterns kept same for six years from 1976 such as ricebarley, potato-rice, pea-rice, rice-rye, and rice-fallow. More and many weeds were growing in single cropping field than double cropping field. Dominant weed species in pea-rice and potato-rice cropping patterns were M. vaginalis and S. hotarui, M. vaginalis and P. distinctus. Coefficient of similarity of the cropping patterns between pea-rice and potato-rice appeared higher than single cropping system. However, pea-rice and rice-fallow cropping patterns showed low coefficient of similarity.

• Weed & Turfgrass Science
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• v.5 no.1
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• pp.1-4
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• 2016

The Rural Development Administration of Korea conducted a series of surveys of paddy weeds from 1971 to 2013 in approximately 10-year cycles and the results have been used for the efficient weed management of paddy fields. In 1971, annual weeds such as Rotala indica, Eleocharis acicularis f. longiseta, and Monochoria vaginalis were dominant. In 1981, the population of Echinochloa species decreased whereas broadleaf weeds such as M. vaginalis, Sagittaria pygmaea, and S. trifolia were dominant. In 1991, perennial weeds such as Eleocharis kuroguwai, S. pygmaea, and S. trifolia were dominant over annual weeds. In 2000, M. vaginalis was the most abundant species, followed by E. kuroguwai, Echinochloa species, and S. trifolia. In 2013, herbicide-resistant Echinochloa species and M. vaginalis were most dominant, followed by E. kuroguwai, Scirpus juncoides, and S. trifolia. It has been predicted that the prevalence of Echinochloa species will continue to increase and that perennial weeds will be more abundant than annual ones in the near future. The occurrence of herbicide-resistant weeds and exotic weeds will also increase due to global warming and changes in agricultural patterns.

• The Korean Journal of Pesticide Science
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• v.3 no.1
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• pp.1-12
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• 1999

Herbicidal activities of newly synthesized experimental compound, KSC-13906 [Erythro N-{(4,6-dimethoxy pyrimidin-2-yl)aminocarbgnyl}-2-(2-fluoro-1- hydroxy-n-propyl)benzenesulfonamide, US Patent 5,461,025], were investigated in greenhouse and field for development as a paddy herbicide. KSC-13906 exihibited excellent weeding effects and selectivity to rice under submerged paddy condition in geenhouse. At the application rate of $2.5{\sim}5$ g ai/ha treated on surface of water, KSC-13906 effectively controlled three annual weeds such as Echinochloa crus-galli var. oryzicola. Scirpus juncoides, and Monochoria vaginalis as well as five perennial weeds such as Cyperus serotinus, Sagittaria pygmaea, Eleocharis kuroguwai, Potamogeton distinctus, and S. trifolia. However, there was no effect on Aneilema keisak and Lindernia procumbens. Especially, KSC-13906 effectively controlled Echinochloa crus-galli var. oryzicola at growth stages ranging from pre-emergence to 3-leaf stage. Antagonistic interaction was found between pyrazosulfuron-ethyl and mefenacet, but not between KSC-13906 ana mefenacet. KSC-13906 had high selectivity to transplanted rice, but caused phytotoxic effect on direct-seeded rice when treated before 3-leaf stage. Herbicidal activity of KSC-13906 on the Echinochloa crus-galli var. oryzicola was 7-folds greater than that of pyrazosulfuron-ethyl in terms of relative dose ratio of the herbicides. These results suggest that KSC-13906 possesses selective herbicidal potency in rice.

• Korean Journal of Weed Science
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• v.13 no.2
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• pp.159-163
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• 1993

This research was conducted at the Crop Experiment Station to determine the changes of weed flora under direct seeded rice cultivation in dry paddy field from 1989 to 1992 and to establish an effective weed control strategy in direct seeded rice cultivation. With the continuous rice growing under direct seeded rice cultivation in dry paddy field, there were more occurrence in grasses and annual weeds while broadleaf and perennial weeds were diminished. The predominant weeds were aquatic weeds such as Eleocharis kuroguwai, Echinochloa crusgalli, and Monochoria vaginalis in machine transplanted rice paddy field while there were predominant of semi aquatic weed species such as E. crusgalli, Digitaria sanguinalis, Bidens tripartita, Aeschynomene indica, and Arthraxon hispidus in continuous direct seeded rice cultivation in dry paddy condition. Based on the vegetative analysis of weeds in terms of simpson index and community dominance, there was more distribution of weed species in direct seeded rice cultivation on dry paddy condition while only distributed with 1-2 weed species in machine transplanted rice paddy field. In similarity coefficient, there was a gradual increase up to 67% of weeds with the continuous direct seeded rice cultivation in dry paddy condition for 4 years starting from 41% of similarity coefficient.

• Weed & Turfgrass Science
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• v.2 no.3
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• pp.318-321
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• 2013

National Academy of Agricultural Science and eight province Agricultural Research & Extension Services investigated the occurring area of herbicide resistant weeds in paddy field of Korea. In order to estimate the occurring areas of herbicide resistant weeds, we collected paddy soils randomly from 3,200 sites in 2011 and 2012, and treated 30 kg $ha^{-1}$ of pyrazosulfuron-ethyl+pyriminobac-methyl GR to the paddy soil. 176,870 ha, approximately 22.1% of cultivated area excluding organic and eco-friendly cultivated area, was estimated to be infested by SUherbicide resistant paddy field weeds. Several species of resistant weeds were occurred at Jeonranam-do with 44.3%, followed by 30.5% at Chungchungnam-do, 27.8% at Chungchungbuk-do, and 24.5% at Jeonrabuk-do, respectively. Monochoria vaginalis showed the highest distribution with 57,018 ha, 32.2% followed by Scirpus juncoides, and Lindernia procumbens, respectively.

• Korean Journal of Weed Science
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• v.18 no.1
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• pp.12-19
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• 1998

The pattern of rice cultivation in Korea is changing from hand transplanting and machine transplanting into direct-seeding for low input and cost-down practices. However, there are still some obstacles to establish the direct-seeding cultural practices because of poor seedling stand, lodging, and weed infestation. In particular, there were much more and wide weed occurrence in direct-seeding rice as compared with the transplanted rice. Weed occurrence in terms of dry weight of weeds was highest in dry direct-seeded rice followed by sowing an puddled soil, sowing on submerged soil in order as compared with transplanting with infant rice seedling. Echinochloa crux-galli was a common dominant weed with 35~44% distribution in any direct-seeding methods. The dominant weed species were E. crux-galli, Cyperus difformis, C. serotinus, and Ludwigia prostrata in dry-seeded rice. The dominant weed species in water-seeded rice were E. crus-galli, Eleocharis kuroguwai, Scirpus juncoides, and Monochoria vaginalis. Yield loss of rice due to weeds at weedy condition was 96% in dry direct-seeded rice. In water-seeded rice, yield loss was 61%, whereas yield loss was 40% in machine transplanting with infant rice seedling.

• Weed & Turfgrass Science
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• v.4 no.4
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• pp.295-307
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• 2015

Surveys of weed species in paddy fields were conducted to identify weed occurrence on July 2013. Total 237 sites of paddy fields in 9 City/Gun, Jeonnam Provinces in Korea were investigated. From the survey, 45 weed species in 18 families were identified and classified to 33 annuals and 15 perennials. Based on the occurrence ratio, the most weed species belonged to Poaceae (9 species) and 8 and 4 weed species belonged to Cyperaceae and Scrophulariaceae, respectively. These 21 weed species in the most four families accounted for 46% of total weed occurrence. The most dominant weed species in Korean paddy fields were Echinochloa spp. (18.5%), followed by Monochoria vaginalis (12.3%), Lemna perpusilla (8.2), Eleocharis kuroguwai (5.2%) and Scirpus juncoides (5.2%). The most dominant weed species in machine transplanting paddy fields were Echinochloa spp. (14%), followed by Monochoria vaginalis (12%) and in water seeded rice paddy fields were Echinochloa spp. (25%), followed by Monochoria vaginalis (11%). This information could be useful for estimation of future weed occurrence, weed population dynamics and establishment of weed control methods in paddy fields.

• Applied Biological Chemistry
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• v.39 no.3
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• pp.235-240
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• 1996

The most stable stereo conformer in non substituted benzenesulfonyl urea, 1 was the II-keto form, which the molecule was intramolecular associated(H-bond) coformer between imide group and N atom on the Pyrimidine ring. The hydrolytic degradation of 2 derivatives were proceeds by nucleophilic addition reaction(p<0) with orbital controlled intermolecular interaction between LUMO with electron donating$(\sigma<0)$ groups of 2 and HOMO of water molecule. N-(4,6-disub. pyrimid ine-2-yl)aminocarbonyl-2-(1,1-dimethoxy-2-fluoro)ethylbenze nesulfonamides,3 and N-(4,6-disub. triazine-2-yl)aminocarbonyl-2-(1,1-d imethoxy-2-fluoro)ethylbenzenesulfonamides,4 we re synthesized and their herbicidal activities in vivo against bulrush (Scirpus juncoides.) were measured by the pot test under the paddy conditions And the structure activity relationships(SAR) were analyzed by the multiple regression technique. The results of the SAR suggested that the 3 and 4 derivatives indicated dependent on the hydrophobicity of the 4,6-disubstituents and the heterocyclo group, where the optimal value $((log\;P)_{opt.}=0.89)$ of hydrophobicity was 0.89. The pyrimidine substituents, 3 showed higher herbicidal activity than the triazine substituents, 4. Among them, 4,6-dimethoxypyrimidine substituent, 3a showed the best herbicidal activity.

• Weed & Turfgrass Science
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• v.1 no.4
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• pp.6-12
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• 2012

A fact-finding survey was conducted to obtain the basic information on nation-wide weed distribution and farmer's opinions to weed control strategy in paddy field. Most respondents considered Echinochloa spp., Monochloa vaginalis, Sagittaria trifolia, and Scirpus juncoides etc. as dominate weeds in paddy fields. And herbicide resistant weed species were M. vaginalis, S. juncoides, E. oryzicola and S. pygmaea etc. Purchase guidances for herbicide selection, experience of farmers was 34.0% and dealers recommendation was 33.9% at farmer's level. And paddy field herbicides application frequence were one time 15.6% but twice 75.6%. Preferred herbicides were ranked in the following order: oxadizone 12% EC, butachlor 5% GR, butachlor 33% CS, mefenacet pyrazodulfuron-ethyl 21.42% SC, and oxadiargyl 1.7% EC etc. in paddy fields. And in most preferred foliar herbicide were bentazone MCPA 38.6% SL and bentazone cyhalop-butyl 18.5% ME, 48.5% and 22.3%, respectively.