• Analytical Science and Technology
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• v.24 no.1
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• pp.15-23
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• 2011

An accurate mass and isotope ratio were determined using a gas chromatography/time of flight mass spectrometer in CI positive mode for the identification of unknown metabolites. High mass tune was used to improve the ion intensity of $[M+H]^+$. Chromatographic resolution and dynamic range enhancement were performed to obtain more reliable accurate masses and correct isotope abundance ratios. Average absolute errors of mass and isotope ratios for 24 reference metabolite -TMS (trimethylsilyl) derivatives were 6.8 ppm, 1.5% of (M+1/M ratio) and 1.7% of (M+2/M ratio), respectively. The correct formulas of twenty one compound were retrieved within top-2 hit from the heuristic algorithm for elemental composition using each accurate mass and isotope abundance ratio.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.540-540
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• 2012

강우 발생시 유역에 집수된 물이 하천에 이르는 경로에 따른 유출은 지표유출, 지표하유출, 지하수유출로 구분된다. 정확한 수문순환 과정의 해석을 위해서는 지표 흐름뿐만 아니라 지표하 및 지하수 흐름의 해석이 중요한 실정이나 일반적으로 실무에서 사용되는 강우-유출해석 모형은 지표유출을 해석하기 위한 모형이 대부분이며, 지표하 유출과 침투량을 산정하는데 어려움이 있다. 일반적인 강우-유출해석 모형은 Horton 방법, NRCS 방법, Green-Ampt 방법에 의해 유효우량을 분리하며, 이 과정은 침투량을 직접적으로 모형화 할 수 없으므로 지표 및 지표하, 지하수 흐름을 복합적으로 해석할 수 있는 모형이 질적이나 양적으로 부족한 실정이다. 이러한 지표하 흐름과 침투량을 산정하기 위하여 FE-FLOW, PM, MS-VMS, GMS, GW-VISTAS, ARGUS 및 MODFLOW와 같은 지하수 모형을 사용하고 있다. 본 연구에서는 지표하유출 산정을 위한 침투량의 비교분석을 위해 현재 가장 범용되는 지하수 유동 모델링 프로그램인 Visual Modlfow 모형과 GMS 모형을 이용하여 침투량 산정을 위한 수치 모의를 진행하였다. 각 모형의 입력자료는 2009년 국립방재연구원에서 수행한 침투실험시설 자료를 이용하여 동일한 조건을 부여하고, 두 모형의 비교를 위해 Visual Modflow에서는 MODFLOW의 기본 해석방법인 유한차분법(FDM)을 이용하고, GMS 모형에서는 3차원 유한요소해석이 가능한 GMS-FEMWATER를 이용하였다. 두 모형의 수치모의 조건으로 2009년 국립방재연구원에서 수행한 침투실험방법과 동일하게 공극률에 따른 투수성 보도블럭의 구분과 50mm/hr, 100mm/hr, 150mm/hr, 200mm/hr의 강우강도별 선행함수조건에 따른 수치모의를 진행하였으며, 수치모의된 침투량의 적정성을 판단하기 위하여 국립방재연구원의 침투실험 결과자료와 비교분석하였다. 침투실험 자료와 각각 수치모의된 침투량을 비교분석한 결과 서로 유사한 경향을 보이고 있으나 초기 침투시 상대오차가 비교적 크게 발생하였다. 이는 수치모형의 경우 수리실험과는 다르게 모의시작과 동시에 해당 강우강도의 침투가 시작되므로 초기 유입 유출량 발생시간의 차이가 종료시간까지 누적 침투량에 미치는 것으로 판단되며, 매개변수에 많은 영향을 받는 것으로 판단된다.

• The Journal of the Acoustical Society of Korea
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• v.40 no.3
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• pp.192-200
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• 2021

Korean bell is a macroscopically axi-symmetrical structure, but has a slight asymmetry due to complex patterns and casting irregularity. Small asymmetry separates one vibration mode into a mode pair with slight frequency difference. The mode pair interferes and creates a beat. The vivid beat with an appropriate period makes the bell sound magnificent and lively feeling. In this study, we propose a method to make the vivid beat using artificial dumshoi. This method creates the vivid beat by designing artificial dumshoi that overwhelms the bell asymmetry. To this end, the asymmetry of Korean bell is quantified by analyzing the beat period data of a number of Korean bells cast in modern times. Based on the measured beat period data, the magnitude of asymmetry is quantified using an equivalent bell model and artificial dumshoi is applied. The movement of mode pair by dumshoi is predicted through finite element analysis. Finally, a design example of the artificial dumshoi for clear beat is introduced.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.37 no.1
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• pp.41-47
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• 2024

This paper utilizes computational asymptotic analysis to compute the boundary layer solution for composite beams and validates the findings through a comparison with ANSYS results. The boundary layer solution, presented as a sum of the interior solution and pure boundary layer effects, necessitates a mathematically rigorous formalization for both interior and boundary layer aspects. Computational asymptotic analysis emerges as a robust technique for addressing such problems. However, the challenge lies in connecting the boundary layer and interior solutions. In this study, we systematically separate the principles of virtual work and the principles of Saint-Venant to tackle internal and boundary layer issues. The boundary layer solution is articulated by calculating the Papkovich-Fadle eigenfunctions, representing them as linear combinations of real and imaginary vectors. To address warping functions in the interior solutions, we employed a least squares method. The computed solutions exhibit excellent agreement with 2D finite element analysis results, both quantitatively and qualitatively. This validates the effectiveness and accuracy of the proposed approach in capturing the behavior of composite beams.

• The Journal of the Petrological Society of Korea
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• v.10 no.2
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• pp.95-105
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• 2001

U-Pb age determination was performed on the zircon fractions separated from the metamorphic rocks of three locations of the Gyeonggi Massif. The ages obtained from the upper and lower intersections between concordia curve and discordia lines made of the zircon fractions separated from the rocks of each locality we: $2168\pm$24 Ma and $1227\pm$40 Ma for the Yongduri Gneiss Complex, $1955\pm$22 Ma and $493\pm$32 Ma for the Euiam Group, and $3712\pm$244 Ma and $1613\pm$51 Ma for the Yongmunsan Group (2$\sigma$ errors). The upper intercept ages from the Yongduri Gneiss Complex and the Euiam Group of Gyeonggi massif are very similar to those obtained from the granitic gneisses and the porphyroblastic gneisses of Yeongnam massif respectively. Such similarities suggest that Gyeonggi and Yeongnam massifs might situate under the similar tectonic and geographic environment during ca. 2.2-1.9 Ga. The upper intercept age of Youngmunsan Formation (3.7 Ga) shows large error, because most of the zircon fractions are plotted very close to the lower intersection. It is necessary to investigate further to confirm this age. However, It may suggest the possibility of occurrence of the oldest crust of the northeast Asia similar to the one reported recently from the northeast China. The lower intercept age of the Yongmunsan Group is interpreted to indicate strong metamorphism. Such age postdates the 1.85-1.7 Ga metamorphism and igneous activities occurred in the Yeongnam massif, which might record the late Paleoproterozoic tectonic activities simultaneously occurred in both massifs.

• Korean Journal of Optics and Photonics
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• v.18 no.1
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• pp.1-7
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• 2007

Filter colorimeters have a set of spectral bands for which spectral responsivity is the same as the color matching function defined by CIE (Commission Internationale de I'Eclairage). We have designed a set of color matching function filters denoted by $\bar{x}-filter,\;\bar{y}-filter,\;and\;\bar{z}-filter$. Because the $\bar{x}-function$ has two transmission bands, two $\bar{x}-filters$ are designed to cover the $\bar{x}-function$. To design the filters, we developed a nonlinear least square fit program which determines the thickness of the color glasses by minimizing its spectral mismatch value ($f{_1}'$) to below 3 %. The design has been validated by fabrication of the $\bar{y}-bar$ filter, of which $f{_1}'$ was measured to be 2.8 %. Considering a LCD flat panel display as a device under test, we have calculated the systematic error of the colorimetric measurement using the designed filters.

• Korean Journal of Environmental Agriculture
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• v.37 no.4
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• pp.291-301
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• 2018

BACKGROUND: Rice is one of the main sources for inorganic arsenic among the consumed crops in the world population's diet. Arsenic is classified into Group 1 as it is carcinogenic for humans, according to the IARC. This study was carried out to assess dietary exposure risk of inorganic arsenic in husked rice and polished rice to the Korean population health. METHODS AND RESULTS: Total arsenic was determined using microwave device and ICP-MS. Inorganic arsenic was determined by ICP-MS coupled with HPLC system. The HPLC-ICP-MS analysis was optimized based on the limit of detection, limit of quantitation, and recovery ratio to be $0.73-1.24{\mu}g/kg$, $2.41-4.09{\mu}g/kg$, and 96.5-98.9%, respectively. The inorganic arsenic concentrations of daily exposure (included in body weight) were $4.97{\times}10^{-3}$ (${\geq}20$ years old) $-1.36{\times}10^{-2}$ (${\leq}2$ years old) ${\mu}g/kg\;b.w./day$ (PTWI 0.23-0.63%) by the husked rice, and $1.39{\times}10^{-1}$ (${\geq}20$ years old) $-3.21{\times}10^{-1}$ (${\leq}2$ years old) ${\mu}g/kg\;b.w./day$ (PTWI 6.47-15.00%) by the polished rice. CONCLUSION: The levels of overall exposure to total and inorganic arsenic by the husked and polished rice were far lower than the recommended levels of The Joint FAO/WHO Expert Committee on Food Additives (JECFA), indicating of little possibility of risk.

• Analytical Science and Technology
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• v.7 no.3
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• pp.329-338
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• 1994

The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.

• Economic and Environmental Geology
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• v.49 no.2
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• pp.89-95
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• 2016

Mo isotope, one of highly redox-sensitive isotopes, has been shown to be useful tracers of geochemical processes. Many studies for Mo isotope have documented with the help of recently developed analysis tools, but it has not yet been documented in the Korea. In this study, we introduce two-stage column separation method of Mo using column tube (BioRad PolyPrep(R) column, 10 ml) and anion exchange resin (BioRad Resin AG(R) 1-X8, 200-400 mesh). Mo isotope ratios in the solid SRMs (BHVO-2, SDO-1, PACS-2) and liquid SRM (IAPSO) were measured on MC-ICP-MS (Multi-collector Inductively Coupled Plasma Mass Spectrometer) and then compared with reference Mo isotope ratios. Mo isotope ratios in our study overlap with reference Mo isotope ratios within analytical error.

• Analytical Science and Technology
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• v.25 no.1
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• pp.83-90
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• 2012

The objective of the study was to estimate the measurement uncertainty associated with determination of creatinine (Cr) in urine samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Centrifuged urine samples (10 ${\mu}L$) were diluted with 390 ${\mu}L$ of distilled water. To 20 ${\mu}L$ aliquots of diluted urine samples, 30 ${\mu}L$ of internal standard solution (Cr-$d_3$, 5 ${\mu}g/mL$) and 10 ${\mu}L$ of acetonitrile were added and filtered. The samples (1 ${\mu}L$) were introduced into LC-MS/MS with no further pretreatment. Cr was separated on a multi-mode ODS column (Scherzo SM-C18, 75 ${\times}$ 2.0 mm I.D., 3 ${\mu}m$) and quantified by LC-MS/MS operating in MRM mode (Cr, m/z 114.0${\rightarrow}$ 86.0; Cr-$d_3$, m/z 117.0${\rightarrow}$ 89.1). The four factors that contribute uncertainty to the final result were extracted and evaluated. The principal factors of contribution to combined standard uncertainty were sample dilution, calibration curve and repeatability, while the preparation of standard solution was only a minor factor. Relative extended uncertainty of the measured concentration was 14.2% in a real urine sample.