• The Journal of Engineering Geology
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• v.12 no.2
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• pp.151-166
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• 2002

Groundwater development as a means of acquiring subsidiary water resource is very important for the persistent security of water resource. Nowadays, pneumatic fracturing technology which was developed in the advanced countries is applied for increasing pumping rate and eliminating contaminants. This study gives an experimental data to clarify permeability characteristics of the single discontinuity which is newly developed or increased in aperture by the pneumatic fracturing or damage propagation of the natural barrier for the nuclear waste disposal. On the basis of understanding the relationship between permeability and hydraulic aperture the result could apply as one of the basic data for researches concerned with increasing pumping rate and eliminating contaminants. Hydraulic aperture is decreased exponentially with increasing confining pressure and proportioned to permeability in the same confining pressure. Especially, with the increasing aperture permeability of coarse- and medium- grained granite shows the more rapid increasing than that of fine- grained granite.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.61-72
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• 2004

The soil samples were collected from the paddy field near the mine tailing dumps in the abandoned Duckum mine in Korea. In the laboratory, the soil solution was extracted from the soil using centrifuge, and analysed for the chemical composition. Physical and chemical soil properties were also analysed. Kaolinite is the main clay minerals in the paddy soil and the CEC value is therefore relatively low. Nearly all soil samples show enrichment in their trace elemental concentrations(Cd, Cu, Pb and Zn) compared with natural background level. Some soil samples exceed the soil remediation intervention values for Cd, Pb and Zn and target value for Cu, when compared with Dutch standard, whereas As, Ni and Cr are in normal range. Lead concentrations in some samples near the mine tailing dumps also exceed the standard for remediation act for agricultural area set by Korean soil conservation law. The trace elemental concentrations are higher in the paddy soil nearer the mine tailing dumps and lower for the samples from distance. Similar trend with distance is found for the soil solution chemistry but the decrease with distance from the mine tailing dumps are sharper than the changes in soil chemistry. Cadmium, Cu and Pb concentrations in the soil solution are very low, ranging from a tenth and hundredths to a maximum of several mg/l, whereas their concentrations in soils are highly enriched for natural background. Most of the trace elements are thought to be either removed by reduced iron sulphides or iron oxides, depending on the redox changes. Geochemical equilibrium modelling indicate the presence of solubility controlling solid phases for Cd and Pb, whereas Zn and Cu might have been controlled by adsorption/desorption processes. Although pollutants migration through solution phase are thought to be limited by adsorption onto various Fe, Mn solid phases, the pollutants exist as easily releasable fractions such as exchangeable site. In this case, the paddy soil would act as pollutant pool, which will supply to plants in situ. whenever the geochemical conditions favour.

• Analytical Science and Technology
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• v.28 no.3
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• pp.187-195
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• 2015

The heat of sublimation (HOS) is an essential parameter used to resolve environmental problems in the transfer of organic contaminants to the atmosphere and to assess the risk of toxic chemicals. The experimental measurement of the heat of sublimation is time-consuming, expensive, and complicated. In this study, quantitative structural property relationships (QSPR) were used to develop a simple and predictive model for measuring the heat of sublimation of organic compounds. The population-based forward selection method was applied to select an informative subset of descriptors of learning algorithms, such as by using multiple linear regression (MLR) and the support vector machine (SVM) method. Each individual model and consensus model was evaluated by internal validation using the bootstrap method and y-randomization. The predictions of the performance of the external test set were improved by considering their applicability to the domain. Based on the results of the MLR model, we showed that the heat of sublimation was related to dispersion, H-bond, electrostatic forces, and the dipole-dipole interaction between inter-molecules.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.92-92
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• 2017

본 연구에서는 수치모델을 이용하여 대하천서 발생되는 조류의 공간적 농도 분포를 예측하였고, 현장실험을 통해 모델을 검증하였다. 국내하천은 다수의 지류가 본류로 유입됨에 따라 오염물질의 생산과 공급이 지속적으로 발생하고, 하천의 유로연장과 하폭에 비해 수심이 낮은 지형학적 특성을 지닌다. 따라서 지류 유입 이후 발생되는 조류의 거동 특성을 분석하기 위해 수심 적분된 2차원 이송-확산 모델을 사용하였다. 광합성 성장을 이루는 조류의 성장속도 계산을 위해 영양염류, 수온, 일사량과 수심 등을 변수로 하는 성장속도 함수들을 위의 모델과 결합하였다. 본 연구의 대상구간은 낙동강과 금호강 합류부를 포함한 강정고령보 하류 약 9.2 km 구간으로 모델 검증을 위한 현장실험을 수행하였다. 2차원 이송-확산 모델의 입력 값인 유속 및 수심을 계산하는 수리동역학 모델 검증을 위해 미국 Sontek사의 M9을 이용하여 낙동강과 금호강 각각 32개, 12개 측선에 대하여 수리량을 측정하였다. 수리량 측정결과, 금호강과 낙동강의 평균 유량은 각각 $240m^3/s$, $60m^3/s$로 측정되었고 측정된 유량을 모델의 상류단 경계조건으로 사용하여 측정 유속 및 수심과 유사한 결과를 모델로부터 취득할 수 있었다. 조류 농도 측정을 위해 독일 bbe사의 AlgaeTorch 10을 사용하였으며, 수리량 측정과 동일한 측선서 총 조류 세포수(cells/ml)를 측정하였다. 농도 측정결과, 하류로 내려감에 따라 조류의 농도가 증가하는 경향이 나타났고 금호강 합류 후 최대농도는 측정구간 최하류 우안서 4,460 cells/ml로 나타났다. 주 흐름이 발생하는 하천 중앙부에 비해 유속이 느린 하안서 상대적으로 높은 농도가 측정되었으며, 이와 같은 경향은 하류로 내려감에 따라 강하게 나타났다. 측정된 조류 농도를 이용한 2차원 이송-확산 모델 검증결과, 합류부 최상류 측선서 MAPE = 10.5 %의 최대오차가 발생하였고 최하류 측선서 MAPE = 6.7 %의 최소오차가 발생하였다. 인과 질소와 같은 영양염류의 농도가 높고 횡 방향 수온 분포가 균일한 대상구간의 특성상 영양염류 함수와 수온 함수로부터 계산된 성장속도 가중치 범위는 각각 0.8~1.0, 0.91~1.09로 공간적 변동성이 크게 나타나지 않은 반면, 수심을 변수로 하는 일사량 함수의 성장속도 가중치 범위는 0.05~1.00으로 상대적으로 매우 높은 공간적 변동성이 나타났다. 수심이 4 m 이하인 하천 양안서 0.8 이상의 가중치가 나타났으며, 수심이 7 m 이상인 하천 중앙서 0.4 이하의 가중치가 나타났다. 본 연구의 수치모의 결과, 수리동역학 모델로부터 계산된 수심이 모델 결과 값에 큰 영향을 미치는 것으로 판단된다.

• Clean Technology
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• v.27 no.1
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• pp.93-103
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• 2021

As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.18-27
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• 2006

Air Sparging (IAS, AS) is a ground-water remediation technique, in which organic contaminants are volatilized into air as they rise from saturated to vadose soil zone. This study was conducted to investigate the variation characteristics of TPH, VOCs and $CO_2$ for air sparging of diesel contaminated saturated soil. Initial TPH concentration was 10,000 mg/kg for saturated soil phase and 1,001 mg/L for soil aquifer phase. After 36 days of air sparging, the equilibrium temperature of 2-Dimension experiment system was $24.9{\pm}1.5^{\circ}C$. The saturated soil TPH concentration (in the C10 port close to air diffuser) was reduced to 66.0% of the initial value. The mass amount of $CO_2$ was 3,800 mg and 3,200 mg in air space (C70 port) and in unsaturated soil zone (C50 port), respectively. The VOCs production kinetic parameter was 0.164/day in the air space (C70 port) and 0.182/day in the unsaturated soils (C50 port).

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.148-148
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• 2023

산업 고도화로 인하여 복잡하고 다양한 유기물의 사용량이 증가하였으며, 공공수역 내 새로운 오염물질이 유입됨에 따라 생화학적 산소요구량(BOD) 중심의 수질평가에 한계를 나타내었다. 이후 난분해성 물질을 고려한 유기물관리 정책과 총량관리의 필요성이 제기되었고 국내 하천과 호소에서는 총 유기탄소(TOC)를 유기물 관리지표로 설정하였다. 그러나 부영양 하천과 호소에서 TOC는 외부 부하뿐만아니라 식물플랑크톤의 과잉성장에 의해 증가할 수 있는 항목이므로 TOC 관리정책 추진을 위해서는 유기물의 기원에 대한 파악이 필요하다. 한편, 우리나라와 같이 몬순 기후대에 속한 댐 저수지의 경우 강우시 유입하는 탁수에 의해 다량의 유기물과 인이 유입되기도 하지만 식물플랑크톤의 제한요인 중 광량에 많은 영향을 미친다. 식물플랑크톤의 광합성은 수체 내 유기탄소 내부생성에 매우 중요한 요소이나 점 단위의 실험적 방법을 활용한 유기탄소 순환 해석은 저수지의 시·공간적인 변동성을 고려하기에 한계가 있다. 본 연구의 목적은 금강 수계 최대 상수원인 대청호를 대상으로 3차원 수리-수질 모델을 적용하여 유기탄소 성분 별 유입과 유출, 내부생성 및 소멸량을 평가하고 탁수가 저수지에서의 유기탄소 순환에 미치는 영향을 분석하는데 있다. 유기탄소 물질수지 해석을 위해 AEM3D 모델을 사용하였으며 2018년을 대상으로 입력자료를 구축한 후 보정 및 검정을 수행하였다. 모델은 유기탄소를 입자성, 용존성, 그리고 난분해성과 생분해성으로 구분하여 모의하며 유기물질 성상별 실험결과를 이용하여 입력자료를 구축하였으며 유기탄소순환 해석을 위해 4가지의 탄소성분과 조류 세포 내 탄소의 질량 변화율을 계산하였다. 이를 위해 외부 유입·유출부하율, 수체 내 생성(일차생산, 재부상, 퇴적물과 수체 간 확산) 및 소멸률(POC 및 조류 침강, DOC 무기화, 탈질)을 고려하였으며 탁수의 영향을 분석하기 위해 탁수 포함여부 시나리오를 구성하고 유기탄소 생성 및 소멸기작별 변동성을 비교 분석하였다. 모델은 2018년의 물수지를 적절히 재현하였으며 저수지의 수온 및 탁도 성층구조를 잘 재현해내면서 전반적인 수질을 적절하게 모의하였다. 탁수를 고려하였을 시 연간 TOC 부하량 중 내부기원 부하량은 56% 수준이였으나 탁수를 배제한 경우 내부기원 부하량은 82%로 나타났다. 특히, 연평균 Chl-a 농도가 44~48% 차이가 발생하면서 1차생산량이 약 4배가량 증가하였다. 몬순지역에서의 탁수는 체류시간이 긴 성층 저수지에서 식물플랑크톤 성장제어에 큰 영향을 미쳤으며 전반적인 유기탄소 순환을 해석하는데 있어 매우 중요한 인자로 작용하였다.

• Journal of the Korean GEO-environmental Society
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• v.13 no.5
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• pp.35-40
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• 2012

In this study, adsorption characteristics of expanded graphite (EG) were investigated by a series of batch adsorption tests using p-Xylene as a model volatile organic compounds (VOCs). After acid treatment, graphite were expanded at various temperature from $600^{\circ}C$ to $1000^{\circ}C$ for one minute. The optimal temperature was $800^{\circ}C$, where the expansion ratio reached 195 times of original volume. The BET specific surface area of EG was $92.4m^2/g$, which was only 1/10 of granular activated carbon (GAC), however the adsorption of p-Xylene by EG was almost completed within 5 minutes while that of GAC continued for 7 days because the majority of pores of EG was consisted with meso- and macro-pores. According to the Langmuir isotherm analysis, the maximum specific adsorption of p-Xylene onto EG was 24.0 mg/L with the adsorption constant of 7.94. In conclusion, the adsorption capacity of EG was much less than that of GAC due to the significantly lower specific surface area, but the first order kinetic constant was more than 500 times larger than GAC. Overall, EG might be effective where the fast adsorption is required.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.1
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• pp.52-58
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• 2005

To establish low-cost and high efficiency water treatment process, feasibility of applying ultrasonic spray nozzle for chemical injection was evaluated. Ultrasonic spray nozzle was manufactured using piezoelectric ceramics. Treatment efficiencies of contaminants by ultrasonic spray nozzle were compared with conventional chemical mixing such as back-mixing. It was found out that the rate of chemical diffusion rate by ultrasonic spray nozzle was faster than by back-mixing method. Removal efficiencies of various contaminants, such as turbidity, organics and microorganism by ultrasonic spray nozzle were also higher than by back-mixing method. By adapting ultrasonic spray nozzle in coagulant injection process, it can be prevented that the decline of treatment efficiency by coagulant overdose. The amount of coagulant can be reduced by applying ultrasonic spray nozzle in water treatment. Along with these advantages chemical mixing chamber is not required if ultrasonic spray nozzle is adapted. From these results, it can be concluded that chemical injection by ultrasonic spray nozzle is an economical and highly efficient device for coagulant mixing.

• Journal of Korean Society on Water Environment
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• v.31 no.1
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• pp.12-18
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• 2015

In this research, the hydrologic effects between a pre-existing urban landuse and low impact development (LID) applied conditions were compared and evaluated. The infiltration trench and tree box filter that were utilized in LID represent only 1% of the catchment area that they drain. Storm event monitoring were conducted from July 2010 to July 2014 on a total of 22 storm events in both LID sites. After LID, hydrological improvement was observed as the sites exhibited a delay (lag time) or reduction in the magnitude, frequency and duration of runoff and flow peaks as the rainfall progress. In addition, the maximum irreducible peak flow reduction for infiltration trench was found to be 61% and 33% for the tree box filter when rainfall was 40 mm and 30 mm, respectively. In designing LID, it is recommended to consider the storage capacity and catchment area, as well as the amount of rainfall and runoff on the site.