• Title/Summary/Keyword: 오염물 이동

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Analyses on Solute Transport with the Movement of an LNAPL on the Water Table (지하수면 위의 LNAPL 이동을 고려한 용질이동에 대한 분석)

  • 김지훈;최종근
    • Journal of Soil and Groundwater Environment
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    • v.8 no.3
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    • pp.1-7
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    • 2003
  • A modified model was developed for solute transport in porous media that can consider the movement of an LNAPL above the water table. From the results of sensitivity analyses with and without considering LNAPL movement, there are some differences according to the hydraulic gradient, the quantity of oil leakage and dispersivity. The mean deviation between the model in this study and a conventional model without LNAPL movement increases as the hydraulic gradient decreases and the quantity of oil leakage increases. Variation of dispersivity has no influence on the magnitude of the mean deviation. However, the spatial distribution of the deviation between the two models is wider as dispersivity increases. Furthermore, groundwater is at high risk of contamination in the vertical direction in the case that transverse dispersion value is large. A conventional model underestimates the concentration of solute in an aquifer where the movement of an LNAPL cannot be negligible: Based on the study results, it is important to understand how fast the LNAPL moves on the water table for realistic prediction of solute transport in an aquifer with the movable LNAPL on the water table.

Study on the Sediment Quality in Bottom Water (I) (수 저층의 저질 조사 (I) - 저질 조사의 중요성과 분석에 관하여 -)

  • Kim, Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.1 s.28
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    • pp.93-102
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    • 2007
  • Particle materials sink in bottom and dissolved inorganic substances release from sediment and many kinds of materials continuously exchange in sediment and water column as well as transfer and transformation in sediment. The study of sediment quality means the state of sediment pollution relation of the water quality, sediment biota, materials fluxes between sediment and water column, transformation of materials in sediment is being important in recent. The state of sediment quality imply that the history of water pollution for long time, because the sediment quality does not change temporally. The sediment quality of bottom water can be used as a good indicator of pollution at present and in future. The major index of sediment qualities are the content of nutrients and hazard materials such as metals, Ignition Loss (IL), Total Sulfur (TS), Oxidation Reduction Potential (ORP), sediment COD, color, odor and the release of nutrients from sediment. However, there are some arguments between researchers about compare to estimation of sediment quality and sampling and analysis of sediment. In this study, I will introduce the method of sediment sampling, analyzing and estimating of the sediment pollution.

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Advection and Diffusion of Pollutant Inflow of Freshwater in Masan Bay (마산만에서의 담수 유입시 오염물의 이송 및 확산)

  • Yoo, Mim-Wook;Kim, Young-Do;Lyu, Si-Wan;Seo, Il-Won
    • 한국방재학회:학술대회논문집
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    • 2008.02a
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    • pp.795-798
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    • 2008
  • An estuary is very important that the seawater and the freshwater meet and they formed wide foreshore and estuarine which is used as the habitat of various living thing and spawning bed of fish. Masan bay is typical closing bay in Korea. It is located 9 km from the open sea and most inside of Jinhae bay. The width of bay entrance is less than 1 km, where the flow velocity is very low. The large scale industrial complex of Masan bay is located in near Masan and Changwon city whose population is about 100 million. Because of low tidal velocity, the pollutants from the land are accumulated, which makes the water quality worse in Masan bay. The purpose of this study is to analyze the various hydraulic characteristics using RMA-2 model. The advection and diffusion of pollutant is also simulated using RMA-4 model according to the inflow of Changwon-stream and Nam-stream. The hydraulic simulations include the effect of tide which can be characterized by the tide data of Masan bay tide observatory.

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Influence of Wax Molecular Weights on Wax Migration and Evaporation of Rubber Vulcanizates at Room Temperature (상온 노화 후 고무가황물에서 왁스의 이동과 증발에 미치는 왁스의 분자량 분포)

  • Im, Song-Hee;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.397-400
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    • 2009
  • Ozone caused the crack on the surface of a rubber article by oxidation of double bond at room temperature. Wax migrates to the surface of a rubber article and makes a physical barrier to prevent process of ozonation. We investigated change of molecular weight distribution of waxes in unfilled NR, SBR, and BR vulcanizates before and after aging at room temperature for 6 months. Migration and evaporation behaviors of wax in a rubber article at ambient conditions help understand a role of wax as an antidegradant and appearance contamination of a rubber article. The relative intensity distribution of n-alkanes of the NR specimen after the aging was shifted to higher molecular weight compared with the relative intensity distribution before the aging, while those of the SBR specimen before and after the aging did not show a big difference.

Study of the Separation and Elution Behavior of Phenols as Priority Pollutants in Reversed Phase Liquid Chromatography (역상 액체 크로마토그래피에서 유기오염물질로서의 페놀류들의 분리 및 용리거동에 관한 연구)

  • Dai Woon Lee;Sun Kyung Lee;Keun Sung Yook;Won Lee
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.287-294
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    • 1989
  • The optimum condition for the separation of priority pollutant phenols using isocratic elution has been determined. The elution behavior of eleven phenols has been also studied to interpret the retention. The reversed phase liquid chromatographic methods were performed on a ${\mu}$-Bondapak $C_{18}$ column with methanol-water, acetonitrile-water, and THF water mixtures as mobile phases. The COF method, where Snyder's solvent triangle concept was combined with a mixture-design statistical technique, was used to optimize the strength and selectivity of solvents for the separation of phenols. The optimum solvent composition, which gives a complete separation of eleven phenols, was found to be $MeOH:ACN:H_2O$ = 7:40:53. The plots of ln k' vs. -${\Delta}H^{\circ}$ and ${\Sigma}{\pi}$ of phenols showed relatively good linearities. Effect of van der Waals volume, pi-energy and hydrogen bonding on the retention of phenols were investigated. The following equation with the correlation coefficient of 0.9927 for ACN-water solvent system was obtained; $log^{k'}=2.515{\times}10^{-2}VWV-1.301{\times}10^{-1}E-3.674{\times}10^{-1}$

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Estimation of Trapping Efficiency Using VFSMOD: Application to Cheongmi Basin (VFSMOD를 이용한 토사저감효율 산정: 청미천 유역에서의 적용)

  • Son, Minwoo;Byun, Jisun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.338-338
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    • 2015
  • 하천으로 유입되어 수질 오염을 야기하는 오염원은 오염 배출원이 명확하여 하나의 점으로 나타낼 수 있는 점오염원(Point Source)과 오염원이 명확치 않은 비점오염원(Non-point)으로 구분된다. 생활하수, 축산폐수와 같이 오염원이 명확한 점오염원은 하천 유입 이전에 처리장을 거쳐 정화작업이 가능한 반면, 비점오염원은 오염원이 명확치 않아 처리에 어려움이 따른다. 또, 오염물의 양과 이동 경로가 예측이 불가능하고 강우시에는 특별한 처리 없이 하천으로 바로 유입된다. 비점 오염원의 종류는 토사, 영양물질, 유기물질, 농약, 바이러스 등 다양하다. 이 중에서 토양에 흡착되어 이동하는 질소와 인은 하천으로 유입되어 부영양화를 야기하는 특성이 있어 더욱 처리가 필수적이다. 이러한 비점오염원으로 인한 수질 오염을 줄이기 위해 여러 최적관리기법(Best Management Practices, BMPs)이 제시되어 있으며 오염 물질의 하천 유입을 차단하는 것에 중점을 둔다. 가장 널리 이용되는 방법으로는 비점오염원 저감시설 중 하천변에 식물체를 설치하여 토양의 유실을 막는 식생대(Vegetative Filter Strip, VFS)가 있다. 식생 밀집 지역의 설치를 통해 표면 유출을 차단하고 토양 유실 감소와 수체로의 오염물질 확산을 막을 수 있다. 이에 VFSMOD-w를 이용하여 강우시 식생대를 통한 토양 유실 감소 효율에 대한 연구를 수행하였다. 연구 대상 지역으로 비교적 수문 및 토양 자료가 풍부한 청미천 유역을 선정하였다. 그 결과, 식생대의 길이와 식생대 내 식물체의 파종간격이 가장 지배적인 영향을 미치는 것이 확인된다. 이때, 식물체의 종류는 식물체 파종으로 인해 변화되는 토양의 수정된 Manning의 조도계수로 구분한다. 모든 강우 및 식물체 조건이 동일할 때, 식생대 내 식물의 파종 간격이 좁고 식생대의 길이가 길수록 토사 저감 효율이 증가하는 결과가 도출되었다. 식물체의 높이, 식물체의 종류 및 식물의 파종간격이 입력 자료로 요구되나 이 중 식물체의 높이는 토사 저감 효율에 영향을 미치지 않는 것으로 나타났다. 또, 동일한 강우 조건에서 식생대의 길이가 0.5 m에서 1.0 m로 2배 증가하였을 때 토사 저감 효율이 두 경우 모두 95% 이상의 효율을 보이는 것이 나타났다. 이는 식생대의 길이가 증가할수록 토사 저감 효율이 증가하나 일정 길이 이상이 되면 대부분의 토사가 저감되는 것을 의미한다. 결론적으로 식생의 파종 간격이 좁을수록 토사 저감 효율이 증가하더라도 식물체의 성장을 고려한 적절한 파종 간격을 선정하여야 한다. 즉, 식생대의 설치는 적절한 파종 간격 및 식생대 길이를 식생대 설치지역의 강우 특성에 따라 결정지어야 한다고 판단된다.

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Feasibility Study for Derivation of Tropospheric Ozone Motion Vector Using Geostationary Environmental Satellite Measurements (정지궤도 위성 대류권 오존 관측 자료를 이용한 대류권 이동벡터 산출 가능성 연구)

  • Shin, Daegeun;Kim, Somyoung;Bak, Juseon;Baek, Kanghyun;Hong, Sungjae;Kim, Jaehwan
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1069-1080
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    • 2022
  • The tropospheric ozone is a pollutant that causes a great deal of damage to humans and ecosystems worldwide. In the event that ozone moves downwind from its source, a localized problem becomes a regional and global problem. To enhance ozone monitoring efficiency, geostationary satellites with continuous diurnal observations have been developed. The objective of this study is to derive the Tropospheric Ozone Movement Vector (TOMV) by employing continuous observations of tropospheric ozone from geostationary satellites for the first time in the world. In the absence of Geostationary Environmental Monitoring Satellite (GEMS) tropospheric ozone observation data, the GEOS-Chem model calculated values were used as synthetic data. Comparing TOMV with GEOS-Chem, the TOMV algorithm overestimated wind speed, but it correctly calculated wind direction represented by pollution movement. The ozone influx can also be calculated using the calculated ozone movement speed and direction multiplied by the observed ozone concentration. As an alternative to a backward trajectory method, this approach will provide better forecasting and analysis by monitoring tropospheric ozone inflow characteristics on a continuous basis. However, if the boundary of the ozone distribution is unclear, motion detection may not be accurate. In spite of this, the TOMV method may prove useful for monitoring and forecasting pollution based on geostationary environmental satellites in the future.

Bacterial Behavior in Soil under Electric Field and its Effect on Electrokientic Bioremediation (전기장하 토양내에서 미생물 이동특성과 동전기 생물학적복원의 효과)

  • Kim, Sang-Joon;Park, Ji-Yeon;Lee, You-Jin;Yang, Ji-Won
    • KSBB Journal
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    • v.21 no.3
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    • pp.175-180
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    • 2006
  • In this study, it could be found that the microbial movement in soil under electric field mainly occurred by electrophoresis and electroosmosis. The contribution of electrophoresis on the microbial mobility and flux was generally higher than that of electroosmosis. In the electrokinetic(EK) bioremediation of a pentadecane-contaminated soil, the microbial population increased simultaneously at anode and cathode regions of the soil specimen because both electrophoresis and electroosmosis affected on the microbial movement. After initial operation, the microbial population was high in order of anode, middle, and cathode regions due to their negatively-charged surface and oxygen generation at anode. However, the uniform contaminant removal was achieved by the microbial movement with two-directionality.

소각재의 무해화 및 재활용에 관한 연구

  • 이동호;김성중;박현서
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.06a
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    • pp.37-41
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    • 2000
  • 폐기물 소각시 발생되는 각종 유해가스 및 비산회재(fly ash)는 후처리 설비에 의해 배출허용기준치 이하로 처리된 후 대기 중으로 방출되도록 환경 규제되고 있다. 그러나 포집된 비산회재(fly ash) 및 노하부 배출재(bottom ash) 내에는 미 연소된 상태로 배출된 유해성 유기물질(다이옥신, 퓨란류 등)과 중금속 성분이 함유되어 있어 이들 소각잔류물(incineration residues)을 안정화나 무해화 처리 없이 단순 매립할 경우 강우에 의해 소각잔류물 내의 유해성분이 침출됨에 따라 토양이나 지하수 등에 2차 환경오염을 일으키게 된다. (중략)

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마산만의 해저퇴적물 입자 분포의 통계학적 특성

  • 염말구;권영택;정태성
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2002.10a
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    • pp.164-165
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    • 2002
  • 내만의 해저퇴적물은 하천이나 외해로부터 유입되어 침강, 응집, 확산, 이동, 재용출 등의 과정에서 수질변화와 저서생물의 서식에 많은 영향을 주는 것으로 알려져 있다(조 등,1982; ASCE, 1992; Kwon and Lee, 1998). 그러므로 해저퇴적물의 변화과정을 이해하기 위해서는 먼저 그 입자 분포의 특성을 파악할 필요가 있다고 생각한다. 이 논문은 오염이 비교적 심한 것으로 알려져 있는 마산만의 여러 정점에서 채취한 해저퇴적물의 입자크기를 측정하고 그 분포의 통계학적 특성을 조사한 것이다. (중략)

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