• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.436-436
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• 2023

산업혁명을 거치면서 높은 화석연료를 사용하는 제조업 중심의 산업구조와 많은 자원을 필요로 하는 도시의 집중 현상으로 지구 온난화에 따른 이상기후 발생이 증가하고 있다. 이러한 기후변화는 홍수, 태풍, 폭염 및 폭설 등의 자연재해 발생 빈도 및 규모를 증가시켜 피해가 커지고 있다. 특히 인구 및 시설들이 집중해 있어 도시의 집중 현상은 이러한 재해에 더욱 취약한 구조가 됨에 따라 피해의 규모를 가중 시키고 있는 실정이다. 전 세계적으로 기후변화 문제의 심각성을 인식하고 이를 해결하기 위해 선신국에 의무를 부여하는 교토의정서(1997년) 채택에 이어, 선진국과 개도국이 모두 참여하는 파리협정(2015년)을 채택하였고 2016년 협정이 발효되었다. 파리협정의 목표는 산업화 이전 대비 지구 평균온도 상승을 2℃보다 아래로 유지하고, 나아가 1.5℃로 억제하기 노력하는 것을 강제하는 것으로 2050년까지 탄소 순배출량을 '0'으로 만든다는 탄소중립사회로의 전환이 본격적으로 시작되었다. 본 연구에서는 기후변화로 인한 물부족 및 수실오염과 같은 도시의 수자원 문제 해결을 위해 IoT 기반 센서 및 네트워크 기반 수자원 플랫폼을 개발하였다. 도시 수자원 시설 데이터를 기반으로 대체 수자원 확보 및 수요 중심의 물 관리를 통해 효율적인 물 배분이 될 수 있도록 하였으며 이러한 스마트 물 관리에 따른 대체 수자원 확보 및 효율적 물 배분이 탄소 저감에 미치는 효과에 대해 분석하였다. 연구대상 지역은 세종 6-4구역으로 LID 특화지구로 조성되었으며 1,000 세대의 주민이 생활하는 공동주택이다. 물 순환(LID) 시설에서 확보된 물을 물 공급 시설과 연계하여 공동주택에서 활용함으로써 감소된 상수 사용량을 온실가스 배출량으로 환산하여 탄소 저감량을 계산하였다. 실제 주민들(1,000세대)이 사용하고 있는 상수량 데이터와 전력거래소 온실가스 배출계수를 활용하였으며 물순환(LID) 시설로 확보하여 대체할 수 있는 상수량은 10%로 가정하였다. 연구대상 지역(1,000세대)의 연간 상수공급량은 331,603m³이며, 연간 전력사용량은69,637kWh이다. 온실가스 배출량은 31.963tCO₂eq이며, 온실가스 저감량은 3.2tCO₂eq로 산정되었다. 추후 LID 시설에 대한 상수 대체량과 온실가스 저감효과 정량화가 필요하다.

• Clean Technology
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• v.24 no.1
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• pp.1-8
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• 2018

As the social demands for environmental pollution increase and regulations on the dyeing process wastewater are strengthened, supercritical dyeing process has been attracting attention as an alternative technology to reduce wastewater and energy consumption. In the supercritical dyeing process where carbon dioxide is used as a solvent instead of water as a solvent, there is no wastewater generated. The unfixed dyes can be reused later which makes the process environment-friendly. Also, after dyeing process, dried textiles can be obtained without additional drying process, which makes the process energy efficient. In this article, we have summarized the development of the supercritical dyeing process along with the research in Korea today and compared the principle of supercritical dyeing process with conventional dyeing process. To further explain the principle, studies of the distribution factor and mass transfer of dyes in supercritical carbon dioxide and fibers, as well as solubility between supercritical $CO_2$ and dyes are discussed. The dynamic behavior of dyes in supercritical dyeing apparatus and summary of the supercritical dyeing facilities developed around the world are also discussed. Finally, we suggest the direction of research and development for optimization of supercritical dyeing process and application to synthetic fibers and natural fibers except for polyester.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.1
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• pp.37-43
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• 1998

Batch experiments were conducted to study the dissolution behavior of gasoline components. First, the dissolution kinetics of gasoline components and the applicability of Raoult's law in predicting their solubilities were investigated. In addition, the effects of compositional change of gasoline due to evaporization on the solubilities of individual components and TPH were determined. The kinetics of gasoline-water man transfer was found to be very similar for most components except for MTBE, which is a major additive for commercial gasoline. At equilibrium, the gasoline-water partitioning coefficients of individual components showed a log-linear relationship with their pure solubilities, though the slope was a little less than that predicted by Raoult's law. The concentrations of the individual components in the gasolines concentrated by volatilization could be characterized by the initial increase followed by substantial decrease. Almost the same behavior was observed for their solubilities. The total solubility (TPH) of gasoline decreased rapidly with the initial volume reduction and gradually decreased afterwards. The solubilities of BTEX, the major regulatory compounds, decreased even faster than the TPH solubilities. It was concluded that the compositional change of gasoline by volatilization may greatly affect their leaching potential and the toxicity of the contacting groundwater. The toxicity reduction efficiency by evaporating gasoline could be much more than the mass removal efficiency.

• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.4
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• pp.201-210
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• 2007

Pollution by chemical substances such as POPs, EDCs and PBTs in the ecosystem has become more complex and varied, increasing the possibility of irreversible damage to human health or the ecosystem. It is necessary to have a exposure assessment in a multi-media environment for various chemical substances is required for efficient management. This study applied MUSEM(Multi-media Simplebox-systems Environmental Model), a multimedia environmental model that can simultaneously evaluate the possibility of exposure of hundreds of chemical substances in order to efficiently manage chemical substances that can have negative impact on human health or ecological environment through environmental contamination. MUSEM executed the modeling for Japan by setting all 47 prefectures of japan as the regional area for 62 chemical substances and the rest of the territory of japan, excluding regional area, as the continental area and made the estimation of concentration among environment media in each administrative area and made the sensitivity analysis on Tokyo area. The results of simulation for chemical distribution showed that most of the target chemicals located in water region. The result of sensitivity analysis for octanol-water partition rate showed that the concentration change of soil in urban/industrial area and sediment in freshwater was high. In the case of sensitivity analysis for degradation rate showed that the concentration change of freshwater, soil in urban/industrial area, and sediment in freshwater was high.

• Analytical Science and Technology
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• v.6 no.1
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• pp.1-8
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• 1993

The purpose of this study is to investigate the elution behavior of monosubstituted phenols and benzenes in micellar liquid chromatographic system, $C_{18}$ column-anionic surfactant, sodium dodecyl sulfate(SDS). The partition coefficients between the micellar pseudophase-water and modified stationary phase-water are calculated by the relationship between solute retention and micellar mobile phase(SDS) composition. The free energy of transfer of solute from water to micelle is also calculated from these values. There is a direct correlation between the hydrophobicity parameters in MLC and corresponding partition data for 1-octanol-water, which indicates that the hydrophobicity of molecules plays an important role in the partition for both systems and that quantitative structure activity relationships(QSAR) are available from studies on micellar partition. The other purpose of this study is to investigate methylene selectivity of alkyl homologous series through correlation between retention and the number of carbons. The correlation between hydrophobicity parameters in MLC and 1-octanol-water partition data was also observed when n-propanol was as a modifier in the mobile phase.

• Journal of Radiation Protection and Research
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• v.40 no.4
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• pp.252-260
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• 2015

This paper describes the technical background for the Korean wildlife radiation dose assessment code, K-BIOTA, and the summary of its application. The K-BIOTA applies the graded approaches of 3 levels including the screening assessment (Level 1 & 2), and the detailed assessment based on the site specific data (Level 3). The screening level assessment is a preliminary step to determine whether the detailed assessment is needed, and calculates the dose rate for the grouped organisms, rather than an individual biota. In the Level 1 assessment, the risk quotient (RQ) is calculated by comparing the actual media concentration with the environmental media concentration limit (EMCL) derived from a bench-mark screening reference dose rate. If RQ for the Level 1 assessment is less than 1, it can be determined that the ecosystem would maintain its integrity, and the assessment is terminated. If the RQ is greater than 1, the Level 2 assessment, which calculates RQ using the average value of the concentration ratio (CR) and equilibrium distribution coefficient (Kd) for the grouped organisms, is carried out for the more realistic assessment. Thus, the Level 2 assessment is less conservative than the Level 1 assessment. If RQ for the Level 2 assessment is less than 1, it can be determined that the ecosystem would maintain its integrity, and the assessment is terminated. If the RQ is greater than 1, the Level 3 assessment is performed for the detailed assessment. In the Level 3 assessment, the radiation dose for the representative organism of a site is calculated by using the site specific data of occupancy factor, CR and Kd. In addition, the K-BIOTA allows the uncertainty analysis of the dose rate on CR, Kd and environmental medium concentration among input parameters optionally in the Level 3 assessment. The four probability density functions of normal, lognormal, uniform and exponential distribution can be applied.The applicability of the code was tested through the participation of IAEA EMRAS II (Environmental Modeling for Radiation Safety) for the comparison study of environmental models comparison, and as the result, it was proved that the K-BIOTA would be very useful to assess the radiation risk of the wildlife living in the various contaminated environment.

• Journal of Soil and Groundwater Environment
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• v.10 no.5
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• pp.61-69
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• 2005

Changes in pyrene binding by dissolved and kaolinite-associated humic substances (HS) due to HS adsorptive fractionation processes were examined using purified Aldrich humic acid (PAHA) at different pH (4, 7 and 9). Irrespective of solution pH, molecular weight (MW) fractionation occurred upon adsorption of PAHA onto kaolinite, resulting in the deviation of residual PAHA MW from the original MW prior to sorption. Variation in $K_{OC}$ by bulk PAHA was observed at different pH due to relative contributions of partitioning and size exclusion effects (i.e., specific interactions). For all pH conditions investigated, carbon-normalized pyrene binding coefficients for nonadsorbed, residual fractions $(K_{OC}(res))$ were different from the original dissolved PAHA $K_{OC}$ value $(K_{OC}(orig))$ prior to contact with the kaolinite suspensions. Positive correlations between pyrene $(K_{OC}(res))$ and weight-average molecular weight $(MW_W)$ for residual PAHA fractions were observed for pH 7 and 9. However, such a positive correlation was not found at pH 4 due to the absence of the dramatic fractionation observed for high pH conditions (i.e., exclusive fractionation with respect to higher MW), suggesting that actual MW distribution pattern is more important for sorption-fractionated HS than the composite MW value. For adsorbed PAHA, conformational changes of PAHA upon adsorption seem to be important for the extent of pyrene binding. At relatively high pH (7 and 9), lower extent of pyrene binding was observed for adsorbed PAHA versus nonadsorbed PAHA. The conformation effects were more pronounced at higher pH.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.283-296
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• 2014

The distribution of heavy metals in the stormwater runoffs from industrial sites around Shihwa Lake that implements the total pollutant load management system (TPLMS) was studied to characterize the temporal changes of metal concentrations and to assess the ecological risk in dissolved and particulate phases of the selected metals. The dissolved Co and Ni concentration demonstrated first flush and tended to decrease with increasing of the duration of rainfall. The intensity of precipitation was found to be the main controlling factor of particulate metals in the stromwater runoffs. The particulate concentration of Pb accounted for 97.2% so the particulate phase was its main form. Other metals followed the sequence: Pb>Cu>Cd>Co>Zn>Ni. The particulate-dissolved partitioning coefficient ($K_d$) indicated that the $K_d$ of Pb were bigger than that of other metals because the metal Pb in the stormwater runoffs is quickly removed into the particulate phase. In a single day rainfall event, total runoff fluxes for total metals as the sum of dissolved and particulate forms through only two sewer outlets were 2.21 kg for Co, 30.5 kg for Ni, 278.3 kg for Cu, 398.3 kg for Zn, 0.39 kg for Cd and 40.0 kg for Pb, respectively. Given the annual rainfall, the number of rain days and the basin area for total pollutant load management system (TPLMS) of Shihwa area, enormous amount of non-point metal pollutants were entered into Lake with any treatment. The dissolved metals (e.g., Ni, Cu and Zn) in the stormwater runoffs exceeded the acute water quality criteria. Additionally, all metals were significantly enriched in the particulate phase and exceeded the PEL criteria of sediment quality guidelines (SQGs). These results indicated that the heavy metals in the stormwater runoffs may pose a very high ecological risk to the coastal environments and ecosystem.

• Journal of the Mineralogical Society of Korea
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• v.26 no.3
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• pp.209-218
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• 2013

This study was to characterize the minerals in fractured and bedrock zone, and determine quantitatively sorption for radioactive cesium ($^{137}Cs$) at the Korean nuclear facility site. The rock samples were granite group that mainly consists of quartz and feldspar with 10~20% mica minerals. Chlorite was observed as secondary mineral for the rock samples collected from fractured zone, but not for bedrock samples. The $^{137}Cs$ sorption distribution coefficients increased to $K_d$ = 880~960 mL/g in the fractured zone because of the presence of secondary minerals formed by weathering processes, compared to the bedrock zone ($K_d$ = 820~840 mL/g). These results suggest that the released $^{137}Cs$ to groundwater environment could be significantly retarded in the fractured zone in the case of severe nuclear accident at the study site.