• Title/Summary/Keyword: 염화아연

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Zn 전기도금재 표면품질에 미치는 염화암모늄 및 첨가제 영향

  • Kim, Hyeon-Tae;Song, Yeon-Gyun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.132-132
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    • 2008
  • 실험실적 도금 simulator 에서 도금실험을 행하여 전기아연도금재 표면품질이 염화암모늄 및 유기첨가제 농도와 상관성을 관찰하였다. 이들은 각각 도금층의 우선배향면인 basal plane 와 연관성이 있었으며 basal plane 이 적을수록 표면 백색 및 광택이 감소하였다.

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펄스형 Nd:YAG 레이저를 이용한 아연도금 강판의 용접

  • 김인호;최병규;김정묵;장인성
    • Laser Solutions
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    • v.7 no.1
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    • pp.7-16
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    • 2004
  • 표면처리 강판은 주로 북미 등에서 제설용 염화칼슘에 대한 방청목적으로 개발되었으나, 최근에는 산성비등 대기환경에 대한 대책으로 표면처리의 역할이 이루어지고 있으며, 그 수요도 날로 다양화되면서 증가하고 있다. 특히 아연도금강판은 우수한 내구성과 값이 싸며 내부식성이 강하므로 자동차 산업, 강판제조업 뿐만 아니라 가전제품에도 많이 사용되는 재료이다. 자동차 차체에 적용되는 아연도금강판의 용접은 대부분은 점용접으로 행하여지고 있으며, 그 우수한 용접특성으로 인해 특수 부위를 제외하고 거의 대부분에 적용되고 있다. (중략)

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A Study on the Separation and Recovery of Useful Metallic Elements(Zn, Pb) from the 2nd Dust in Refining of Crude-Zinc Oxide (조산화아연의 정제과정에서 발생된 2차분진으로부터 유용금속원소(Zn, Pb)의 분리회수에 관한 연구)

  • Yoon, Jae-hong;Yoon, Chi-hyun
    • Resources Recycling
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    • v.30 no.1
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    • pp.66-76
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    • 2021
  • Electric arc furnace dust (EAFD) contains compounds, such as oxides and chlorides, including large quantities of Zn, Pb and Fe. An efficient and stable method for the extraction of metal elements from EAFD is the Rotary Kiln Process. This method is used to recover Zn in the form of crude ZnO (approximately 60%) via the addition of a reducing agent (coke, anthracite) and limestone (for basicity control) to EAFD. This process is commonly used in industry as well as in research and development. Currently, this method is used in many Korean commercial plants, producing approximately 150,000 tons of Crude ZnO per year. The majority of Zn is found in crude ZnO (approximately 76%). In addition components such as Pb, Cd, Sn, In, Fe, Cl, and F are present as oxides, chlorides, and alkaline compounds. This elements have an adverse effect on the zinc smelting process. Therefore, a refining process that eliminates these impurities is essential. In this study, we developed a process technology that efficiently separates Zn and Pb from byproducts (mainly chlorides). A bag filter was used to collect Zn and Pb generated during the dry purification process of crude ZnO. Pure components were recovered as metals or metal carbonate.

Preparation of Activated Carbon from Wasted Food by Chemical Activation with Zinc Chloride (염화아연 약품활성화를 이용한 음식물쓰레기로부터 활성탄 제조)

  • Kang, Hwa-Young;Lee, Young-Dong;Kim, Se-Hoon;Park, Sung-Bong;Jung, Jae-Sung;Park, Sang-Sook
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.9
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    • pp.900-906
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    • 2008
  • It was studied to utilize wasted food as a starting material to produce for activated carbon. The wasted food was chemically activated with zinc chloride. Experiments were carried out at different chemical ratios(activating agent/wasted foods), activation temperatures, and activation time. The activated products were characterized by measuring the iodine and methylene blue number, the BET surface area, the pore volume, the micropore ratio, the pore diameter, the yields and the scanning electron microscope(SEM). For the products activated by impregnation ratio of 1.0 of ZnCl$_2$ at 500$^{\circ}C$ for 60 min in a rotary kiln reactor had iodine number of 480 mg/g, methylene blue number of 95 mL/g, BET surface area of 410 m$^2$/g, pore volume of 0.248 cm$^3$/g, and average pore diameter of 2.43 nm, respectively. The activated carbon obtained had the contribution of micropore area of 70.7% to the total pore area and micropore volume of 53.2% to the total pore volume.

Pore Structure and Adsorption Characteristics of Metals and Nutrient Salt of Activated Carbon Produced from Different Chemical Treatment (서로 다른 약품처리를 이용하여 제조한 활성탄의 세공구조 및 중금속과 영양염류 흡착특성)

  • Lee, Young-Dong;Kang, Hwa-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1319-1330
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    • 2000
  • Activated carbons prepared by chemical activation of organic waste sludges with $ZnCl_2$ and $K_2S$ have been studied in terms of their pore development and adsorptivity. Pore development of the carbons prepared from organic waste sludges was characterized by the nitrogen adsorption at 77K. The $ZnCl_2$-activated carbon produced by chemical activation with zinc chloride exhibited type I isotherm characteristics according to the BDDT classification, suggesting the presence of micropores formed by activation process. The isotherms of the commercial powdered activated carbon and $K_2S$-activated carbon reveal a hysteresis similar to that of type IV in BDDT classification, indicating the formation of mesopores. This result implies that the major pores of $K_2S$-activated carbon are composed of meso and micropores, and a macropores are minor. The adsorptive capacities of metal on the $K_2S$-activated carbon prepared from organic waste sludges were found to be superior to those on a commercial granular activated carbon. The Langmuir and Freundlich isotherms yield a fairly good fit to the adsorption data, indicating a monolayer adsorption of metals onto $K_2S$-activated carbon. The adsorptive capacity of the $K_2S$-activated carbon was superior to $ZnCl_2$-activated carbon for $PO_4$-P, and vice versa for $NO_3$-N. From the results of the studies reported here, it can be concluded that activated carbons with adsorptivity superior to commercial granular activated carbons can be produced from organic waste sludge using a two-step carbonization/activation procedure with zinc chloride or potassium sulfide as the activating agents.

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Zn-Cr Alloy Plating from Acidic Chloride Bath: Effect of Temperature and Current Densities on Composition of Electrodeposits (산성염화욕에서의 Zn-Cr합금도금 : 합금화에 미치는 전류밀도와 온도의 영향)

  • Kang, Soo Young
    • Journal of the Korea Convergence Society
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    • v.9 no.11
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    • pp.285-290
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    • 2018
  • The steel has been used in modern industry, car maker and electric appliance. The steel have some problem, specially corrosion problem. To solve corrosion problem, Zn electrodeposit on steel have been adapted. Recently, The modern industry asks to increase corrosion resistance. Naturally, Increasing corrosion resistance increases the thickness of Zn electrodeposit. But increasing thickness of Zn electrodeposit has some problems. In making part, There are some crack. This crack cause to decrease corrosion resistance. To solve this problem, it is interested in Zn Based alloy electrodeposit such as Zn-Cr. Here, the influence of the electrolytic conditions on the composition of the alloy plating in the chloride bath was investigated. The results are explained by the cathode overvoltage curve of Cr and Zn. As the current density of the cathode increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase. As the temperature of the electrolyte increases, Zn content of electrodeposit decrease and Cr content of electrodeposit increase.

화학적 활성법에 의한 셀룰로오스계 활성탄소의 제조와 흡착특성에 관한 연구

  • 오규환;윤창훈;박종래
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.473-476
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    • 1998
  • 활성탄소는 입자내 공극이 잘 발달된 무정형 탄소로서 흡착성 및 촉매성이 뛰어나 대기오염의 주범인 유독성 배기가스의 흡착이나 폐수처리, 정수처리 등에 널리 사용되고 있다. 환성탄소 제조공정은 크게 보아 탄화 및 활성화 공정으로 나눌 수 있으며 활성화 방법에 따라 화학적 활성법과 물리적 가스 활성법으로 나눌 수 있다. 가스 활성법은 고온에서 수증기나 $CO_2$,O$_2$ 그 외의 산화성가스를 char와 접촉시키는 방법이고, 화학적 활성법은 염화아연, 인산, 수산화칼륨등과 같은 탈수, 산화, 침식성이 큰 화학약품으로 탄소질을 침식시키는 방법이다. (중략)

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Redrying Fire - Retardant - Treated Structural Plywood (구조용(構造用) 내화처리(耐火處理) 합판(合板)의 재건조(再乾燥)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Schaffer, E.L.
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.4
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    • pp.1-21
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    • 1981
  • Exterior grades of Douglas-fir and aspen plywood were impregnated with interior fire-retardant chemicals and redried under low-, intermediate-, and high-temperature drying conditions. Fire-retardant treatments included borax-boric acid, chromated zinc chloride, minalith, pyresote, and a commercial formulation. Drying processes included kiln and press-drying. Evaluated were drying rates and defects generated. The borax-boric acid and the commercial treatments redried at rates similar to water-treated controls. Other salt treatments were significantly slower drying and more defect prone. Chromated zinc chloride treatment was consistently the slowest drying and most defect prone. Press drying was three times faster at an equivalent temperature level. However, thickness shrinkage doubled because of 50 1b/in. platen pressure.

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