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Preparation of Activated Carbon from Wasted Food by Chemical Activation with Zinc Chloride  

Kang, Hwa-Young (Department of Civil and Environment, Hanyeong College)
Lee, Young-Dong (Division of Environmental and Chemical Engineering, Chonbuk National University)
Kim, Se-Hoon (Division of Environmental and Chemical Engineering, Chonbuk National University)
Park, Sung-Bong (Division of Civil and Environmental Engineering, Sunchon National University)
Jung, Jae-Sung (Division of Civil and Environmental Engineering, Sunchon National University)
Park, Sang-Sook (Division of Civil and Environmental Engineering, Sunchon National University)
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Abstract
It was studied to utilize wasted food as a starting material to produce for activated carbon. The wasted food was chemically activated with zinc chloride. Experiments were carried out at different chemical ratios(activating agent/wasted foods), activation temperatures, and activation time. The activated products were characterized by measuring the iodine and methylene blue number, the BET surface area, the pore volume, the micropore ratio, the pore diameter, the yields and the scanning electron microscope(SEM). For the products activated by impregnation ratio of 1.0 of ZnCl$_2$ at 500$^{\circ}C$ for 60 min in a rotary kiln reactor had iodine number of 480 mg/g, methylene blue number of 95 mL/g, BET surface area of 410 m$^2$/g, pore volume of 0.248 cm$^3$/g, and average pore diameter of 2.43 nm, respectively. The activated carbon obtained had the contribution of micropore area of 70.7% to the total pore area and micropore volume of 53.2% to the total pore volume.
Keywords
Activated Carbon; Chemical Activation; Iodine/methylene Blue Number; BET Surface Area; Pore Volume;
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1 Pastor-Villegas, J., Gomez-Serrano, V., Duran-Valle, C. J., Higes-Rolando, F. J., 'Chemical study of extracted rockrose and of chars and activated carbons prepared at different temerature,' J. Anal. Appl. Pyrolysis, 50, 1-16(1999)   DOI   ScienceOn
2 Ru-Ling Tseng, 'Physical and chemical properties and adsorption type of activated carbon prepared from plum kernels by NaOH activation,' J. Hazard. Mater., 147, 1020-1027(2007)   DOI   ScienceOn
3 Kaustubha, M., Mousam J., Meikap, B.C., Biswas, M.N., 'Preparation and characterization of activated carbons from thrminalia arjuna nut with zinc chloride activation for the removal of phenol from wastewater,' Ind. Eng. Chem. Res., 44(11), 4128-4138(2005)   DOI   ScienceOn
4 Guo, J., Chong Lua, A., 'Characterization of Chars Pyrolyzed from Oil Palm Stones for the Preparation of Activated Carbons,' J. Anal. Appl. Pyrolysis, 46, 113-125(1998)   DOI   ScienceOn
5 Bansal, R.C., Donnet, J-B., Stoeckli, F., 'Active Carbon,' Marcel Dekker, New York(1988)
6 Hsisheng Teng and Tien-Sheng Yeh, 'Preparation of Activated Carbons from Bituminous Coals with Zinc Chloride Activation,' Ind. Eng. Chem. Res., 37(1), 58-65(1998)   DOI   ScienceOn
7 Robert Dipanfilo, Nosa O. Egiebor, 'Activated carbon production from synthetic crude coke,' Fuel Process. Technol., 46, 157-169(1996)   DOI   ScienceOn
8 Olivares-Marin, M., Fernandez-Gonzalez, C., Macias-Garcia, A., Gomez-Serrano, V., 'Porous structure of activated carbon prepared from cherry stones by chemical activation with phosphoric acid,' Energy Fuels, 21(5), 2942-2949(2007)   DOI   ScienceOn
9 Abdel-Nasser, A., El-Hendawy, 'Surface and adsorptive properties of carbons prepared from biomass,' Appl. Surf. Sci., 252, 287-295(2005)   DOI   ScienceOn
10 한국공업규격(Korean Standard Methods, KSM) 1802(1994)
11 Wolfgang Heschel and Erhard Klose, 'On the suitability of agricultural by-products for the manufacture of granular activated carbon,' Fuel, 74(12), 1786-1791(1995)   DOI   ScienceOn
12 Zhonghua, H. and Vansant, E. F., 'A new composite adsorbent produced by chemical activation of elutrilithe with zinc chloride,' J. Colloid Interface Sci., 176(2), 422-431(1995)   DOI   ScienceOn
13 Serkan Timur, Cem Kantarli I., Erdinc Ikizoglu, Jale Yanik, 'Preparation of activated carbons from Oreganum stalks by chemical activation,' Energy Fuels, 20(6), 2636-2641(2006)   DOI   ScienceOn
14 Laszlo, K., Nagy, L. G., Subklew, G., Schwuger, M. J., 'Fractal Approach of Activated Carbons from Solid Waste Materials,' Colloids Surf. A: Physicochemical and Engineering Aspects, 138, 29-37(1998)   DOI   ScienceOn
15 Ahmadpour, A., Do, D.D., 'The Preparation of Activated Carbons from Coal by Chemical and Physical Activation,' Carbon, 34(4), 471-479(1996)   DOI   ScienceOn
16 John Kennedy, L., Judith Vijaya, J., Sekaran, G., 'Effect of two-stage process on the preparation and characterization of porous carbon composite from rice husk by phosphoric acid activation,' Ind. Eng. Chem. Res., 43(8), 1832-1838(2004)   DOI   ScienceOn
17 Amina, A.A., Badie, S.G., Nady, A.F., 'Removal of methylene blue by carbons derived from peach stones by $H_3PO_4$ activation: batch and column studies,' Dyes and Pigments, 76, 282-289(2008)   DOI   ScienceOn
18 Bota, A., Laszlo, K., Nagy, L.G,, Copitzky, T., 'Comparative study of active carbons from different precursors,' Langmuir, 13(24), 6502-6509(1997)   DOI   ScienceOn
19 Ozgul Gercel, Ferdi Gercel, H., 'Adsorption of lead(II) ions from aqueous solutions by activated carbon prepared from biomass plant material of Euphorbia rigida,' Chem. Eng. J., 132, 289-297(2007)
20 El-Hendawy, A.A., Samra, S.E., Girgis, B.S., 'Adsorption characteristics of activated carbons obtained from corncobs,' Colloids Surf., A: Physicochem. Eng. Aspects, 180, 209-221(2001)   DOI   ScienceOn
21 Otowa, T., Tanibata, R., Itoh, M., 'Production and adsorption characteristics of MAXSORB: high-surface-area active carbon,' Gas Sep. Purif., 7(4), 241-245(1993)   DOI   ScienceOn
22 Satya Sai, P. M. and Jaleel Ahmed, 'Production of Activated Carbon from Coconut Shell Char in a Fluidized Bed Reactor,' Ind. Eng. Chem. Res., 36, 3625-3630(1997)   DOI   ScienceOn