• Journal of the Korea Concrete Institute
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• v.26 no.4
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• pp.517-524
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• 2014

Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.600-608
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• 2022

This study investigates the effect of layered double hydroxide (LDH) on the healing performance of self-healing concrete by assessing the chloride penetration resistance of self-healing cement mortars using electrical chloride ion migration-diffusion test. Test results show that both mortars containing healing materials only and mortars containing healing materials and Ca-Al LDH together mostly had higher migration-diffusion coefficients right after cracking, but the migration-diffusion coefficients decreased more than that of OPC with increasing healing ages, and thus, they yielded higher healing capacities than OPC. Also, mortars containing Ca-Al LDH together with healing materials showed higher reduction of their migration-diffusion coefficients, and thus, higher healing capacities than mortars containing healing materials only. This suggests that as the self-healing product increases on the crack surface, the binding of chloride ions by LDH inside the crack increases.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.1
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• pp.48-55
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• 2022

This study uses the recovered water as mixing water and artificial lightweight aggregate pre-wetting water as part of a study to increase the recycling rate and reduce greenhouse gas of the ready-mixed concrete recovered during the concrete transport process, and cement fine powder of blast furnace slag(BFS) and fly ash(FA). The engineering characteristics of the three-component lightweight aggregate mortar used as a substitute were reviewed. For this purpose, the flow, dry unit mass, compressive strength, drying shrinkage, neutralization depth, and chloride ion penetration resistance of the three-component lightweight aggregate mortar were measured. When used together with the formulation, when 15 % of BFS and 5 % of FA were used, it was found to be positive in improving the compressive strength and durability of the mortar.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.451-454
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• 2000

Recently, the antiwashout underwater concrete has been increasingly used for underwater structure such as high strength massive concrete structures. However, Concrete has poor quality ad durability due to dilution with separating cementitious material. In this study, specimens were made with antiwashout underwater concrete replaced with mineral admixtures to improve their properties and were placed in air, water, and salt water. To estimation the chloride ion permeation in concrete, ASTM C 1202 Test was performed. The experimental results demonstrate that the increase of the admixtures improved the properties of antiwashout underwater concrete.

• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.112-118
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• 2022

In this study, the diffusion characteristics were evaluated using the concrete mix design of nuclear safety-related structures. Among the concrete structures related to nuclear power safety, we selected the composition of intake and drainage structures that are immersed in seawater or located on the tidal platform and evaluated the chloride ion permeation resistance by compressive strength and electrical conductivity and the diffusion characteristics by immersion in salt water. analyzed. Compressive strength was measured on the 1st, 7th, 14th, 28th, 56th, and 91st days until the 91st day, which is the design standard strength of the nuclear power plant concrete structure, and chloride ion permeation resistance was evaluated on the 28th and 91st. After immersing the 28-day concrete specimens in salt water for 28 days, the diffusion coefficient was derived by collecting samples at different depths and analyzing the amount of chloride. As a result, it was found that after 28 days, the long-term strength enhancement effect of the nuclear power plant concrete mix with 20% fly ash replacement was higher than that of concrete using 100% ordinary Portland cement. It was also found that the nuclear power plant concrete mix has higher chloride ion permeation resistance, lower diffusion coefficient, and higher resistance to salt damage than the concrete mix using 100% ordinary Portland cement.

• Journal of the Korea Concrete Institute
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• v.20 no.4
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• pp.439-449
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• 2008

Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

• Journal of the Korea Institute of Building Construction
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• v.12 no.3
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• pp.275-283
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• 2012

Nitrite-type hydrocalumite (calumite) is a material that can adsorb the chloride ions ($Cl^-$)that cause the corrosion of reinforcing bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. In this study, VA/E/MMA-modified mortars with calumite were prepared with various calumite contents and polymer binder-ratios, and tested for corrosion inhibition, chloride ion penetration, carbonation and drying shrinkage. As a result, regardless of polymer-binder ratio, the replacement of ordinary Portland cement with hydrocalumite has a marked effect on the corrosion inhibiting property of the polymer-modified mortars. However, chloride ion penetration and carbonation depths are somewhat increased with higher calumite content, but can be remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to increase with the polymer-binder ratio and calumite content. VA/E/MMA-Modified mortars with 10 % calumite did not satisfy KS requirements. Accordingly, a calumite content of 5 % is recommended for the VA/E/MMA-modified mortars with calumite.

• Polymer(Korea)
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• v.37 no.2
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• pp.148-155
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• 2013

The purpose of this study is to clarify the effect of the emulsifier ratio on the properties of the polymer cement mortars based on styrene-butyl acrylate (S/BA) latexes, and to obtain necessary basic data to develop appropriate latexes for cement modifiers. The polymer dispersions for cement modifiers was synthesized using styrene and butyl acrylate. Polymer cement mortars based on S/BA latexes were prepared with various monomer and emulsifier ratios, and their water-cement ratio, air content, flexural and compressive strengths, water absorption and chloride ion penetration were tested. From the test results, the maximum flexural and compressive strengths of polymer cement mortars based on S/BA latexes were obtained at a bound styrene content of 60% and an emulsifier ratio of 6%. Also, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the bound styrene and emulsifier content. Accordingly, it is judged that S/BA latexes can be used place of the conventional polymer dispersions of cement modifier.

• Journal of the Korea Concrete Institute
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• v.16 no.4 s.82
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• pp.485-492
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• 2004

In this study, ASTM C 1202 which is most commonly used for evaluating the penetration resistance into the concrete is reviewed. The test results by ASTM C 1202 showed that the passed charge could be underestimated as the $OH^-$ ion concentration in the concrete is lowered when the concrete is mixed with the admixtures. Therefore, the modified method using the distilled water was proposed in the paper. According to the test results, the modified method is not susceptible to $OH^-$ ion and temperature rise. In addition, the long term emersion test for the concrete mixed with the admixtures in the NaCl solution showed that the chloride diffusion coefficient tested by the modified method have higher correlation compared to the conventional ASTM method.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.44-49
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• 2016

Among the deteriorating agents, chloride ion is reported to be one of the most harmful ions due to its rapid diffusion and direct effect on steel corrosion. Cold joint which occurs in mass concrete placing is vulnerable to shear resistance and more severe deterioration. The paper presents an quantitative evaluation of chloride diffusion coefficient in OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag) concrete containing cold joint. GGBFS concrete shows $6.6{\times}10^{-12}m^2/sec$ which is almost 30% level of OPC concrete results and the trend is repeated in the case of cold joint concrete. Compared with OPC concrete, GGBFS concrete is evaluated to have better resistance to chloride penetration, showing 0.30 times of chloride diffusion coefficient in concrete without cold joint 0.39 times with cold joint, respectively.