• Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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• 2003.08a
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• pp.307-314
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• 2003

해양콘크리트 구조물의 내구성에 가장 큰 영향은 미치는 요인 중의 하나가 염소 이온의 침투에 의한 철근부식이다. 염소이온이 콘크리트 구조물 내부로 확산되어 철근이 부식하게 되면 철근의 부피팽창으로 콘크리트 덮개에 균열이 발생하고 철근의 단면적도 줄어들게 된다. 따라서, 구조물은 사용연한을 채우지 못 하고 붕괴되거나 사용성에 큰 문제가 발생하게 된다. (중략)

• Journal of the Korea Concrete Institute
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• v.15 no.6
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• pp.902-912
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• 2003

The most common deteriorating processes of concrete structures are carbonation and chloride ion ingress. Many concrete structures have been suffered from chloride ions diffusion or carbonation induced reinforcement corrosion damage and many studies have been done on it. However, those studies were confined mostly to the single deterioration of carbonation or chloride attack only, although actual environment is rather of combined conditions. In case of many in-situ concrete structures, deterioration happened more for the case of combined attack than the single case of carbonation or chloride attack. In this paper, chloride profiles of carbonated concrete is predicted by considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3∼5 mm over depth from carbonation depth. The analytical modeling of chloride diffusion was suggested to depict the relative influence of the carbonation depth. The diffusion coefficients of carbonation concrete and uncarbonated concrete with elapsed time were considered in this modeling.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.525-528
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• 2008

For well-constructed concrete, its service life is a long term and it has an enough durability performance. However, for cracked concrete, it is clear that cracks should be preferential channel for the penetration of aggressive substance such as chloride ions according to author's previous researches. In order to enhance the lifetime of cracked concrete, critical issues in the performance of the concrete is the risk of chloride-induced corrosion. Even though crack width can be reduced due to the high reinforcement ratio, the question is to which extend these cracks may jeopardize the durability of cracked concrete. If the size of crack is small, surface treatment system can be considered as one of the best options to extend the service life of concrete structures exposed to marine environment simply in terms of cost effectiveness versus durability performance. Thus, it should be decided to undertake an experimental study on the effect of different types of surface treatment system, which are expected to seal the concrete and the cracks to chloride-induced corrosion in particular. In this study, it is examined the effect of surfaced treated systems on chloride penetration through microcracks. Single surface treatments of penetrant or coating and double application were considered as an experimental variation. RCM (Rapid Chloride Migration) testing is accomplished to visualize chloride penetration via cracks.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.7
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• pp.721-728
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• 2008

DBPs(Disinfection By-Products) are most formed through the reactions between chlorine and NOM(Natural Organic Matter) in water treatment. In this study, occurrence of DBPs including THMs(Trihalomethanes) is evaluated. Also, influencing factors by the seasons and raw water quality were investigated for correlation among them and the characteristics of THMs formation by prechlorination process. This study investigated the operation condition for THMs removal depending on raw water quality. Water treatment plant from intake station to gauging well flows for about 10 hours in Y Water Supply Office. It is limited to control of THMs formation because of excessive reaction time between chlorine and THMs precursors in the intake station. Therefore, as multi-points prechlorination from intake station to gauging well, THMs formation was decreased in the water treatment, and it was willing to prevent overdosage of chlorine. The concentration of THMs was 0.021 mg/L in the summer, 0.015 mg/L in the winter, respectively. Also, THMs formation showed that 0.013 mg/L in the water of gauging well after prechlorination, 0.014 mg/L in the flocculation/sedimentation/filtration, 0.016 mg/L in the water after postchlorination, respectively. THMFP(Trihalomethane Formation Potential) removed 42.7% and 50% through the flocculation/sedimentation and filtration, respectively, and it is similar TOC removal efficiency. In this study, multi-points prechlorination from intake station to gauging well decreases in contact time and concencrations of NOM and chlorine. Also, it decreases in THMs and amount of chlorine uesd. In the result of multi-points prechlorination in the summer, the concentration of THMs was 0.013mg/L in the treated water. In view of these facts, THMs formation can be decreased approximately 50%.

• Journal of Veterinary Clinics
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• v.16 no.2
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• pp.467-468
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• 1999

인도의 도축장에서 27두의 염소의 폐를 검사하여 진균성 폐렴의 발생을 조사하였다. 27두 중 노령의 쇠약한 암컷 염소 1두에서 Candida albicans에 의한 폐렴이 진단되었다. 이 염소의 부검소견으로서 폐엽에 다양한 경화와 회백색의 결정상 병변이 관찰되었다. 폐렴병변 조직의 날인표본을 만든 후 Gram과 PAS 염색을 한 결과 Candida albicans와 일치하는 많은 수의 가성균사와 효모균이 관찰되었다. 병변조직을 Pal 배지와 Sabouraud 한천배지에 접종한 결과 Candida albicans가 두텁게 증식되었다. 혈청으로 실시한 한천 겔 면역확산시험에서 Candida albicans에 대한 가느다란 침강선이 생성되었다. 쇠약하고 노령인 환축에 있어서 기회성 진균의 역할이 강조되었다.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.18-18
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• 2018

상수관망 시스템(Water Distribution System, WDS)은 이용자에게 양질의 상수도를 공급하기 위해 구축된 사회기반시설물로써, 정수된 물이 사용처에 도달하기까지 송수과정에서 발생 가능한 수질저하를 고려해야 한다. 일반적으로 정수장에서 염소처리를 한 후, 도달시간을 고려한 시스템 내 잔류 염소농도를 유지함으로써 수질저하를 예방한다. 여기서 상수도 내 잔류 염소농도는 미생물 번식 및 관내 부식물 등 다양한 생물 화학적 오염을 효과적으로 예방하는 반면, 과다할 경우 이용자의 음용성을 저해할 수 있어 시스템 전반에 걸쳐 염소농도의 적절한 관리가 요구된다. 특히, 상수관망에서는 공급경로 및 공급량에 따라 각 수요처의 도달 염소농도가 다르게 분포할 수 있으므로, 시설운영자는 균등하고 적절한 염소농도를 유지하기 위해 추가적인 염소 재투입시설을 설치하여 함께 관리하고 있다. 이 때, 염소투입 시설의 운영계획은 EPANET과 같은 상수관망 해석모형의 수질모의를 바탕으로 수립된다. 그러나 일반적으로 수질모의는 수리해석과는 달리 긴 시간이 소요되는 단점이 존재한다. 본 연구에서는 이러한 단점을 개선하기 위해, 특정 네트워크의 수질모의 결과를 학습시킨 인공신경망(ANN) 모형을 구축하고 이를 이용하여 상수관망 수질모의 계산시간을 단축하고자 하였다. 여기서 ANN모형의 학습은 EPANET을 통해 미리 선정된 다양한 염소 투입지점의 염소 투입농도와 용수 공급량 자료, 그리고 주요 관측지점에서 측정된 염소농도자료를 이용하였다. 학습된 ANN모형을 EPANET 수질모의 결과와 비교 및 검증을 실시한 결과, 사전에 소요된 학습시간을 제외하면 수질모의 소요시간 측면에서 큰 개선효과를 보였으며, 대표지점에서의 수질모의 결과가 유사하였다. 추가적으로, 본 연구에서는 학습된 ANN모형과 최적화 알고리즘인 GA(Genitic Algorithm)를 연계하여 상수관망에서의 염소 재투입 스케줄링을 최적화하는 프로그램을 개발함으로써, 안전하고 경제적인 상수관망의 수질운영에 기여하고자 하였다.

• Journal of the Korean Society of Safety
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• v.6 no.3
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• pp.27-34
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• 1991

This paper is for the properties of the oxidation-proof of the partially discharged and of the molecular motion on chlorinated PE Film. this paper also shows the properties of the molecular motion of the ${\gamma}$ ray irradiated PE Film. 1 In the surface of the PE Film enforce chlorination, C-Cl be distributed up to 10 $\mu$m deep. 2. In according to the development of the chlorination, the measure of crystalization decreased and cross link occured. 3. Chlorination PE Film control the oxidation on ozone to occuratlon by partial discharge and it lost bonding chlorine. 4. in according to chlorination, ${\gamma}$ absorption in motion of CH2 main chain of PE drcreased by chlorine stbstitution.

• Journal of Korea Water Resources Association
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• v.55 no.spc1
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• pp.1197-1210
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• 2022

Recently, users' complaints on drinking water quality are increasing according to emerging interest in the drinking water service issues such as pipe aging and various water quality accidents. In the case of drinking water quality complaints, not only the water pollution but also the inconvenience on the chlorine residual for disinfection are included, thus various efforts, such as rechlorination treatment, are being attempted in order to keep the chlorine concentration supplied evenly. In this research, for a more accurate water quality simulation of water distribution network, the water quality reaction coefficients were estimated, and an optimization method of chlorination/ rechlorination scheduling was proposed consideirng satisfaction of water quality standards and chlorine residual equalization. The proposed method was applied to a large-scale real water network, and various chlorination schemes were comparatively analyzed through the grid search algorithm and optimized based on the suitability and uniformity of supplied chlorine residual concentration.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.707-711
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• 2007

낙동강과 밀양강의 합류지점에 위치한 김해시 딴섬 지역의 지표면하 $25{\sim}35\;m$ 구간에 형성되어 있는 고투수성 충적층 내 염소이온의 수리분산특성을 연구하기 위한 수렴흐름 추적자시험(convergent flow tracer test)이 수행되었다. 추적자로는 IW-1공과 IW-2공에서 각각 염소이온 5kg이 순간주입(instantaneous injection) 되었으며, PW공에서 일정한 양수율(2,500 m3 /day)로 채수하면서 염소이온농도를 관측하였다. 염소이온 주입 후 경과시간에 따른 염소이온농도 자료를 이용하여 농도이력곡선과 누적질량회수곡선이 산출되었으며, 관측된 염소이온농도의 정규분포를 검증하기 위한 일반통계분석이 수행되었다. 그리고, 농도이력의 증가/감소 구간에서의 함수를 추정하였으며, 두 시험에서 동일한 시간에 관측된 염소이온농도의 상관성이 분석되었다. 본 현장에서 수행된 추적자시험에 의한 종분산지수의 추정은 CATTI 코드(Sauty and Kinzelbach, 1992)에 의해 해석되었다. 추정된 종분산지수는 IW-1공과 PW공 구간에서는 0.4152 m, IW-2공과 PW공 구간에서는 0.4158 m 로서 매우 유사한 값으로 나타났다. 이는 추적자시험이 수행된 충적층에서의 용질이송이 방사상으로 비교적 균일함을 의미하는 것이다. 본 연구에서 수행된 추적자시험의 규모(2 m)를 Xu and Eckstein(1995)이 제시한 방정식에 대입하여 산정된 종분산지수는 0.0458 m 이었다. 이러한 결과는, 본 연구지역에서 수렴흐름 추적자시험에 의해 추정된 고투수성 충적층의 종분산지수가 일반적인 자연대수층에 비해 9.1배 정도 높다는 것을 의미한다. 이는 시험대수층의 투수성이 매우 높아 염소이온의 용질이송이 매우 빠르게 발생되었기 때문이다. 본 연구에서 추정된 종분산지수를 Gelhar et al.(1992)의 연구 결과와 비교 분석한 결과에서도 시험규모에 비해 매우 높은 수리분산이 발생된 것으로 나타났다. 그리고 염소이온의 확산면적을 추정하기 위해, 수렴흐름 추적자시험에 의한 종분산지수와 시험대수층의 평균선형유속을 이용하여 종분산계수를 구하였다. 현장에서 수행된 양수시험에 의한 평균선형유속 22.44 m/day와 평균 종분산지수 0.4155 m를 적용하여 산정된 종분산계수는 $9.32\;m^2/day$이었다. 따라서, 시험부지 내 충적층에서 일정한 양수율$(2,500\;m^3/day)$로 지하수를 개발할 시에 양수정 주변지역으로 유입되는 염소이온의 확산면적은 1일 $9.32\;m^2$ 정도일 것으로 나타났다.

• Journal of Korea Water Resources Association
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• v.56 no.11
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• pp.705-720
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• 2023

In South Korea, ongoing incidents related to drinking water quality have eroded consumer trust. Specifically, beyond quality incidents, there have been complaints about taste, odor, and other issues stemming from the presence of chlorine. To address this, water service operators are employing various management strategies from both temporal (scheduling) and spatial (rechlorination) perspectives to ensure uniform and safe distribution of chlorine residuals. In this study, we focus on the optimal monthly management of chlorine residuals, based on water distribution network analysis. Water quality reaction coefficients, including bulk fluid and wall reaction coefficients, were estimated through lab-scale tests and EPANET water quality simulations, respectively, accounting for temperature variations in a large-scale water distribution network. Utilizing these estimated coefficients, we examined the monthly variations in chlorine residual distribution under different chlorine injection conditions. The results indicate that the efficient concentration for chlorine injection, which satisfies the residual chlorine limit range, varies with temperature changes. Consequently, it is imperative to establish a specific and quantitative chlorine injection plan that considers the accurate spatial distribution of monthly chlorine residuals.