• Title/Summary/Keyword: 염소 감소

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The scale dependent effect of hydraulic conductivity and longitudinal dispersivity in the alluvial aquifer with high permeability (고투수성 충적층에서 수리전도도와 종분산지수의 규모종속효과)

  • Kang, Dong-Hwan;Kim, Tae-Yeong;Kim, Sung-Soo;Kim, Dong-Soo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.1899-1903
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    • 2008
  • 대수층의 저유량이 풍부한 강변여과수 개발 예정지역의 충적층(지표면하 $25{\sim}35\;m$ 구간)에서 수리전도도와 종분산지수의 규모종속효과를 규명하기 위해 양수시험과 수렴흐름 추적자시험이 수행 되었다. 양수시험과 추적자시험의 규모는 2 m 와 5 m 이었으며 양수시험은 5개 공, 추적자시험은 3개 공을 이용하여 수행되었다. 양수시험은 일정한 양수율($2,500\;m^3/day$)로 수행되었으며, 양수 시작 후 경과시간에 따른 수위변화 자료를 AQTESOLV 3.5 프로그램에 입력하여 해석하였다. 시험 대수층의 수리전도도는 양수정에서 $1.745{\times}10^{-3}\;m/sec$, 양수정에서 이격거리가 2 m 구간에서는 $2.161{\times}10^{-3}\;m/sec$$2.270{\times}10^{-3}\;m/sec$ 이었으며, 이격거리가 5 m 구간에서는 $2.452{\times}10^{-3}\;m/sec$$2.591{\time}10^{-3}m/sec$로 산정되었다. 그리고, 양수정에서 회복시험 시 Theis(Recovery) 방법에 의해 해석된 수리전도도는 $1.603{\times}10^{-3}\;m/sec$이었다. 양수정에서 관측정의 이격거리(d)에 따른 수리전도도(K) 증가함수는 log K=0.0693 log d-2.671와 log K=0.0817 log d-2.655로 추정되었으며, 결정 계수는 각각 0.965와 0.979로서 매우 높게 나타났다. 따라서 양수정에서의 이격거리가 멀수록 수리전도도가 증가하는 규모종속을 확인하였으며, 또한 시험대수층의 수리전도도가 방사상으로 유사하게 분포하고 있음을 알 수 있었다. 수렴흐름 추적자시험의 양수율은 $2,500\;m^3/day$ 이었으며, 2개의 주입정에 염소이온 5 kg을 순간 주입하였다. 염소이온의 농도이력곡선을 작성하여 초기도달시간과 최고농도의 차이를 분석하였으며, 누적질량회수곡선을 통해 양수 후 경과시간에 따른 염소이온의 질량회수율을 분석하였다. 그리고, 염소이온농도 대 누적질량회수율의 이력그래프를 작성하여 누적질량회수율에 따른 염소이온농도의 증가와 감소 변화를 분석하였다. 또한, 염소이온농도의 증가/감소 구간에 대한 선형회귀분석을 수행하여 농도 증가율과 감소율의 변화를 파악하였다. 양수정에서 관측된 경과시간별 염소이온농도 자료를 CATTI 코드의 "Converging Radial Flow With Instantaneous Injection" 해석법에 적용하여 종분산지수를 추정하였다. 양수정에서 이격거리가 2 m인 경우의 종분산지수는 0.4152 m, 이격거리가 5 m인 경우의 종분산지수는 3.2665 m이었다. 따라서 양수정에서 이격거리가 멀수록 종분산지수가 증가하는 규모종속효과를 확인하였으며, 또한 이격거리에 대한 종분산지수의 비는 각각 0.21과 0.65 정도로서 증가하였다.

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The Scale-Dependent Dispersion Through Convergent Flow Tracer Tests in Alluvial Aquifer with High Permeability at the Ttaan isle, Gimhae City (김해 딴섬의 고투수성 충적층에서 수렴흐름 추적자시험에 의한 규모종속 수리분산 연구)

  • Kang, Dong-Hwan;Shim, Byoung-Ohan;Kwon, Byung-Hyuk;Kim, Il-Kyu
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.17-25
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    • 2007
  • Convergent flow tracer test for 2 m (IW-1 well) and 5 m (IW-2 well) of test scale was conducted at the alluvial aquifer with high permeability and storativity. Pumping rate for convergent flow tracer test were $2,500m^3/day$, and the chloride tracer of 5 kg was instantaneously injected into IW-1 and IW-2 wells. Differences of first arrival time and peak concentration were analyzed by using the concentration breakthrough curves of chloride. Recovered chloride mass were analyzed by recovered cumulative mass curves. And, increment and decrement for chloride concentration were analyzed through chloride concentration versus recovered cumulative mass ratio graphs. Also, increment and decrement ratios of chloride concentration were estimated through linear regression analyses for increment and decrement intervals of chloride concentration. Longitudinal dispersivities were estimated by quot;Converging Radial Flow With Instantaneous Injectionquot; method using CATTI code. Longitudinal dispersivities estimated by CATTI code were 0.4152 m between pumping well and IW-1 well, and 3.2665 m between pumping well and IW-2 well. Longitudinal dispersivity was increased according to far distance from the pumping well. The longitudinal dispersivity according to distance were estimated as 0.21 between pumping well and IW-1 well, and 0.65 between pumping well and IW-2 well.

Influence of Reactive Oxygen Species Produced by Chlorine Dioxide on Induction of Insect Cell Apoptosis (이산화염소의 활성산소 유발에 따른 곤충 세포의 아폽토시스)

  • Kim, Minhyun;Kumar, Sunil;Kwon, Hyeok;Kim, Wook;Kim, Yonggyun
    • Korean journal of applied entomology
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    • v.55 no.3
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    • pp.267-275
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    • 2016
  • Chlorine dioxide has an insecticidal activity via its production of reactive oxygen species (ROS). Its cytotoxic activity has been regarded as a main cause of the insecticidal activity. This study tested a hypothesis that cytotoxicity of chlorine dioxide is resulted from its induction of apoptosis against target cells using ROS. Injection of chlorine dioxide significantly reduced total hemocyte counts of Plodia interpunctella larvae and subsequently killed the larvae. To analyze the cytotoxicity with respect to apoptosis, terminal deoxyribonucleotidyl transferase nick end translation (TUNEL) assay was performed. An insect cell line (Sf9) cells were exposed to different concentrations of chlorine dioxide. TUNEL assay showed that chlorine dioxide induced significant apoptosis of Sf9 cells in a dose-dependent manner. When different concentrations of chlorine dioxide were injected to larvae of P. interpunctella, it showed a dose-dependent induction of apoptosis against hemocytes. However, addition of vitamin E significantly suppressed the apoptosis induction and insecticidal activity of chlorine dioxide in a dose-dependent manner. These results suggest that cytotoxicity of chlorine dioxide is resulted from its induction of apoptosis against insect cells using ROS.

Characteristic of Microcracks with Mixing Proportional Properties of Concrete (미세균열이 콘크리트의 염소이온 침투에 미치는 영향 III; 배합조건 특성에 따른 미세균열의 특성)

  • Yoon, In-Seok;Kim, Young-Geun;Park, Ki-Bong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.469-475
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    • 2008
  • It is obvious that chloride penetration through cracks can threaten the durability of concrete substantially, according to the previous studies of author. It was proposed that crack depth corrseponded with critical crack width from the surface is a crucial factor in view of durability design of concrete structures. It is now necessary to deal with chloride penetration through microcracks characterized with the mixing features of concrete. The purpose of this study is examining the effect of mix proportional features of concrete such as coarse aggregate, high strengtherize of concrete and reinforcement of steel fiber on chloride penetration through cracks. Although small size of coarse aggregate can lead to many microcracks in concrete, the cracks should not impact on chloride penetration directly. On the contrary, chloride should penetrate through cracks easily in concrete with a large size of coarse aggregate because mixrocracks are connected to each other. Second, high strength concrete has an excellent performance to resist with chloride penetration. However, for cracked high strength concrete, its performance is reduced upto the level of ordinary concrete. Finally, steel fiber reinforcement is effective to reduce chloride penetration through cracks because steel fiber reinforcement can lead to reduce crack depth significantly.

Experimental Study on Chloride Penetration into Concrete under Combined Exposure Conditions of Chlorides and High Concentrated Sulfates (고농도 황산염 이온이 함께 존재하는 경우의 염소이온 침투특성에 관한 실험 연구)

  • Oh, Byung-Hwan;Jung, Sang-Hwa;Jiang, Yi-Rong;Kim, Jee-Sang
    • Journal of the Korea Concrete Institute
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    • v.15 no.2
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    • pp.173-182
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    • 2003
  • Recently, the durability of concrete structures has received great attention as the number of sea-side structures, such as new airport, bridges, and nuclear power plants, increases continuously. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the effects of combined deterioration due to chlorides and sulfates in concrete structures. To this end, comprehensive experimental program has been set up to observe the chloride penetration behavior for various test series. The test results indicate that the chloride penetration is more pronounced for the case of combined attack than the case of single chloride attack. The surface chloride content is found to increase with time and the diffusion coefficient for chloride is found to decrease with time. The prediction equations for surface chloride content and diffusion coefficient were proposed according to test results. The equations for chloride penetration considering the time-dependent diffusion coefficients and surface chlorides were also suggested. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of chlorides and high concentration sulfates but the future studies for combined environment will assure the precise assessment.

Diffusion Characteristics of Chloride ion under Single and Combined Attacks in Concrete Structures (콘크리트 구조물의 단일 및 복합열화 환경하에서의 염소이온 확산특성)

  • 오병환;강의영;인광진;이성규;서정문
    • Journal of the Korea Concrete Institute
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    • v.14 no.5
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    • pp.708-717
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    • 2002
  • Durability is a major concern in the design and construction of concrete structures which are located in the sea environments. In particular, the combined action of chlorides, sulfates, and carbonation nay influence greatly the deterioration behavior of concrete structures. The purpose of the present study is to explore the diffusion characteristics of chloride ions in concrete structures under combined deterioration conditions. The present test results indicate that the chloride penetration into concrete structures is more pronounced under combined attacks of chlorides, sulfates and carbonation. The diffusion coefficients and surface chloride contents were found to increase under combined multiple deterioration conditions. The present study provides quantitatively the penetration and diffusion characteristics of chloride ions in concrete structures under various deterioration conditions. The results of present study may be efficiently used for the realistic design of concrete structures under combined deterioration conditions.

Disinfection Effects of Chlorine and Monochloramine on Campylobacter jejuni (Campylobacter jejuni에 대한 염소 및 Monochloramine의 살균효과)

  • 윤만석;오학식;김치경
    • Microbiology and Biotechnology Letters
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    • v.17 no.6
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    • pp.539-544
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    • 1989
  • Campylobacter jejuni, bacterial agent causing human diarrhea, were studied for their disinfection effects with chlorine and monochloramine. The cells treated with the chemical agents were observed by scanning electron microscopy to know their morphological and structural changes. The proteins and DNA in the chemical-treated cells were also examined by gel electrophoresis for structural changes. When C. jejuni were chlorinated at concentrations of 0.5 and 1.0 mg/l for 15 minutes, the organisms were disinfected by 4 and 6 log, respectively. Those disinfection effects were higher at acidic pH, while lowered at neutral and alkaline values of pH. The effects of monochloramine were lower than those of chlorine at the game concentration for the same period of reaction time. The shapes of C. jejuni cells treated with the agents appeared to be deformed from spiral rod into spherical forms, showing some destruction in surface structure of the cells. Some of the proteins and DNA of the chlorinated cells did not appear in the gel electrophoresis when the chlorination was at concentration of 10 mg/l or higher.

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A Study on the Characteristics of Clinker and Cement as Chlorine Content (염소 함량에 따른 클링커 및 시멘트의 물성에 관한 연구)

  • Lee, Young-Jun;Kim, Nam-Il;Cho, Jeong-Hoon;Seo, Sung-Kwan;Chu, Yong-Sik
    • Resources Recycling
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    • v.30 no.5
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    • pp.10-16
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    • 2021
  • In this study, a clinker was prepared using raw materials with CaCl2. The characteristics of the chlorine-added clinker and cement were analyzed. The clinker modulus were set to Lime Saturation Factor (LSF) 92, Silica modulus (SM) 2.5, and Iron Modulus (IM) 1.5. The physical properties of cement using the chlorine-containing clinker were characterized. As the chlorine content increased, the free-CaO content in the clinker decreased, and that in the 2000 ppm clinker was reduced by approximately 40% compared to that in the 0 ppm clinker. There was an increase in the amount of chlormayenite, with a content of up to 3.4% present in the 2000 ppm clinker. The amounts of alite and belite also slightly increased. The compressive strength of mortar at 3 days and 7 days increased as the chlorine content increased. This trend was presumed to arise from the effect of hydration, which was promoted by the presence of chlorine. The compressive strength of 1000 ppm mortar increased by approximately 20% compared to that of 0 ppm mortar.

Gaseous Chlorine Dioxide Treatment to Produce High Quality Paprika for Export (고품질 수출용 파프리카 생산을 위한 이산화염소 가스 훈증 처리)

  • Kang, Ji Hoon;Park, Shin Min;Kim, Hyun Gyu;Son, Hyun Jung;Song, Kyoung Ju;Cho, Miae;Kim, Jong Rak;Lee, Jeong Yong;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.7
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    • pp.1072-1078
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    • 2015
  • To maintain high quality and microbiological safety of paprika during storage for export, paprika samples after harvest were treated with 75 ppmv chlorine dioxide ($ClO_2$) gas and stored at $8^{\circ}C$, which is the optimal storage temperature, for 30 days. $ClO_2$ gas treatment reduced initial populations of total aerobic bacteria in samples by 1.62 log CFU/g as well as yeast and molds by 1.45 log CFU/g compared to those of the control. During storage, weight loss of all samples increased, and samples treated with $ClO_2$ gas showed lower weight loss than the control. In addition, total soluble solid and total phenolic contents were not significantly different between the samples during storage, whereas vitamin C content and hardness of all samples decreased. Hunter L, a, and b values of paprika samples were not significantly different between the treatments. These results suggest that $ClO_2$ gas treatment can be effective for improving microbiological safety and maintaining high quality of paprika during storage.