• 조명전기설비학회논문지
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• 제13권2호
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• pp.71-79
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• 1999

본 노문에서는 무성방전의 중첩을 이용한 새로운 방전형식의 고농도.소수율 다중방전형 오존발생기를 설계.제작하였다. 다중반전형 오존발생기(MDO)는 설치된 3개의 전극과 길이가 다른 2개의 방전간극에 $180[^{\circ}]$의 위상차를 가진 2개의 고류고전압 전원의 인가에 따라서 무성방전의 중첩에 의하여 오존생성특성이 각기 다른 3가지 형태의 중첩방전형 오존발생기(SDO)의 형태변화에 따른 방전특성과 오존생성특성을 연구한 결과, 최대 17185[ppm] 및 783[g/kwh]의 오존생성특성을 얻을 수 있었으며, 17185[ppm] 의 오존을 염색폐수에 접촉시켰을 때, 탈색특성이 우수하여 다중방전형 오존발생기가 수질환경개선 설비로 적용가능함을 확인하였다.

• 한국환경과학회지
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• 제8권4호
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• pp.525-532
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• 1999

This study was conducted to evaluate capability of dyeing wastewater treatment for 3 type reactors. These reactors were Packed Bed Reactor(PBR), Fluidized Bed reactor(FBR) and Moving Media Complete Mixing Activated Sludge reactor(MMCMAS). Experiments of PBR and FBR were performed by various packing ratios and organic loading rates, experiments of MMCMAS were performed by various organic loading rates. In order to obtain ${SBOD}_5$ removal efficiencies of more than 90%, the F/Mv ratios of PBR, FBR, MMCMAS were 0.11 kgBOD/kgMLVSS$\cdot$d, 0.12 kgBOD/kgMLVSS$\cdot$d, and 0.37 kgBOD/kgMLSS$\cdot$d, respectively. So MMCMAS system which has more active microorganisms showed better capability of organic removal and also stronger dynamic and shock loadings than those of PBR and FBR. In PBR and FBR, the media packing ratio of 20% showed better performance of organic matters removal effciencies than 10% and 30%, but sludge production rate at media packing ratio of 30% was relatively lower than that of 10% and 20%. When more than 90% organic matters removal efficiency was obtained, the ratios of attached biomass to total biomass at PBR, FBR, MMCMAS were 89~99%, 87~98%, and 54~80%, respectively. The ratio of attached biomass to total biomass was low in MMCMAS. This was formation of thin biofilm due to shear force between rotaing disc and water. The average sludge production rates(kgVSS/kgBODrem.) of PBR, FBR and MMCMAS were 0.20, 0.29 and 0.54, respectively.

• 대한환경공학회지
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• 제31권12호
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• pp.1081-1088
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• 2009

Rhodamine B (RhB)의 제거를 위해 철 전극을 이용한 전기응집 (EC) 공정의 성능에 대해 연구하였다. RhB 제거 효율에 대한 전극 물질 (알루미늄, 철), 전류밀도, NaCl 첨가량, 초기 pH 및 초기 염료 농도와 같은 운전인자의 영향을 연구하였다. 이들 운전 인자에 대한 최적 운전 범위는 실험을 통하여 결정되었다. 희생 전극 물질로서 철 전극의 성능이 알루미늄 전극보다 우수하였다. 최적 전기분해 시간, 전류밀도, NaCl 첨가량 및 pH는 각각 10 분, 1630 A/$m^2$, 4 g/L 및 중성의 pH 이었다. 최적의 공정 조건하에서 RhB 농도가 230 mg/L인 조건에서 RhB는 효과적으로 제거되었고 (> 93.4%), RhB의 COD도 역시 감소하였다(> 88.9%). RhB의 색도와 COD 제거에 대한 상기 조건에서의 전기 에너지 소비량은 각각 10.3 and 10.8 kWh/kg RhB으로 나타났다. 전기응집 공정은 RhB와 같은 염색폐수 처리에 효과적인 것으로 나타났다.

• 한국환경과학회지
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• 제20권3호
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• pp.291-299
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• 2011

The main objectives of this research are to investigate characteristics of ozone solubility due to low solubility of conventional bubbles-ozone generators, evaluate the treatment characteristics of reclaiming textile wastewater for industrial water by means of micro/nano bubbles-dissolved ozone flotation(MNB-DOF) process. The textile wastewater used in this research was obtained from final effluent of the textile wastewater in B city. There is a 400L reactor which consists of a micro-nano bubble system and a ozone generator for experiments. As a result of generating micro-nano bubbles (below $0.5{\mu}m$) by using of MNB-DOF process, it improved ozone solubility due to higher ozone transfer rates. Consequently, the shorter ozonation time clearly indicates the lower power costs. The reported results clearly indicated that MNB-DOF process can be effectively and inexpensively. Results of the experiments through MNB-DOF process in this study satisfy all reclaiming standards as industrial water: pH 6.5~8.5, SS 10 mg/L or below, $BOD_5$) 6 mg/L or below, turbidity 10 NTU or below, Coliforms 1,000/100 mL or below. Therefore there is a possibility of the reclaiming of the textile wastewater as industrial water.

• 한국염색가공학회지
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• 제30권1호
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• pp.51-61
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• 2018

In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

• 한국물환경학회지
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• 제24권5호
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• pp.537-542
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• 2008

Textile industry has been recognized as an important pollution source due to its consumption of large volumes of water and chemicals. Textile wastewater contains very diverse chemicals in types and composition, among them the presence of dyes is highly visible and undesirable. In spite of these problems, there has not been a proper control for the wastewater because many dyes are difficult to be degraded or decolorized due to their complex structure and synthetic characteristics. This study has been progressed to evaluate more easily the potential decolorization of advanced treatment processes. It has been surveyed with the Y textile complex wastewater treatment plant, the raw wastewater has appeared very difficult biodegradability by 4.7 of $CODcr/BOD_5$ and 1,158.9 degree of color. In view of CODcr fractions, biodegradable COD portion was 46.4%, colloidal COD and real soluble COD was 45.3% and 31.5% each others. From research on unit processes, the degradable coefficient (k) became from 0.065 to $0.125d^{-1}$ by the processes, the decolorization appeared best efficiency by 30.1% (458.4 degree) in pre-ozone process. On the effluent from the biological process, the filterable CODcr became 129.3 mg/L, the biodegradable portion appeared 64.7% (83.6 mg/L), and the fixed dissolved solid (FDS), non-reactivity (NR), appeared very heavy portion by 80.5% (1,659.0 mg/L).

• 한국환경보건학회지
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• 제30권3호
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• pp.185-190
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• 2004

Acute aquatic toxicity of effluents discharged from five dyeing plants in Gyeong-gi province were evaluated to assess whether the current Korean water quality standards(KWQS) could protect aquatic life. Chemical analyses of all parameters regulated under KWQS, except for E-coli, were also carried out to determine regulation compliance of the samples. All the effluent samples were satisfied with KWQS except for the color in only one sample. In acute Daphnia magna toxicity tests, significant mortality was observed in one of five samples and EC50 was 12.1%(95% confidence interval 9.1-16.2), which was in compliance with KWQS. The result of the Microtox assay indicated that acute microbial toxicity existed in effluents from three out of five plants, two of which were in compliance with KWQS. The agreement between regulation compliance of chemical concentrations of effluent and observed toxicity from various biological toxicity tests was very poor to fair (kappa = 0.194~0.250). The data presented suggest that exposure to dyeing wastewater which were in compliance with Korean water quality standards may not be safe to aquatic biota, and multiple tropical levels should be considered in aquatic toxicity monitoring of dyeing industry.

• 한국염색가공학회지
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• 제19권3호
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• pp.26-36
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• 2007

This study was carried out to treat the aqueous solutions containing reactive dyes(RB19, RR120 and RY179) by the Ozone demand flask method and adsorption process using activated carbon fiber(ACF) which are one of the main pollutants in dye wastewater. Ozone oxidation of three kinds of the reactive dyes was examined to investigate the reactivity of dyes with ozone, competition reaction and ozone utilization on various conditions for single- and multi-solute dye solution. Concentration of dyes was decreased continuously with increasing ozone dosage in the single-solute dye solutions. Competition quotient values were calculated to investigate the preferential oxidation of individual dyes in multi-solute dye solutions. Competition quotients(CQi) and values of the overall utilization efficiency, ${\eta}O_3$, were increased at 40mg/l of ozone dosage in multi-solute dye solutions. ACF(A-15) has much larger specific surface area$(1,584m^2/g-ACF)$ in comparison with granular activated carbon adsorbent (F400, $1,125m^2/g-GAC$), which is commonly used, and most of pores were found to be micropores with pore radius of 2nm and below. It was found that RB19 was most easily adsorbed among the dyes in this study. In the case of PCP (p-chlorophenol) and sucrose, which are single component adsorbate, adsorption capacities of ACF(A-15) were in good agreement with the batch adsorption measurement, and saturation time predicted of ACF columns for these components was also well agreed with practically measured time. But in the case of reactive dyes, which have relatively high molecular weight and aggregated with multi-components, adsorption capacities or saturation time predicted were not agreed with practically measured values.

• 분석과학
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• 제18권4호
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• pp.320-328
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• 2005

산업폐수 중 염화폐놀류 5종 (4-chloro-3-methylphenol, 2,4,5-trichlorophenol, 2,4,6-trichlorophenol, 2,3,4,6-tetrachlorophenol, pentachlorophenol)의 잔류량을 GC/MS를 사용하여 측정하였다. 산업폐수 시료는 석유화학, 섬유염색, 가죽피혁 분야의 공장에서 방류되는 원수 및 방류수를 채취하여 분석하였다. 본 논문에서는 USEPA 3510 방법을 변형하여 새로운 방법을 확립하였다. 각 시료들은 pH 2와 5~6조건에서 디클로로메탄을 사용하여 액체-액체 추출법으로 추출한 다음 GC/MS에 주입하여 SIM방법으로 분석하였다. 그 결과 0.1 ng/mL~10.0 ng/mL과 0.5 ng/mL~10.0 ng/mL 정량구간내에서 $R^2=0.9943$ 이상의 좋은 직선성을 나타내었으며, 검출한계는 0.1 ng/mL~0.5 ng/mL이었다. 실제 시료측정에 앞서서 1, 5, 10 ng/mL 농도에서 회수율을 측정하였는데, PCP의 경우를 제외하고는 71.6-98.9%의 양호한 절대회수율을 나타내었다. 상대표준편차(RSD)는 1.2~14.3% 범위의 좋은 재현성을 나타내었고, 정밀도를 나타내는 bias는 낮은 농도(1 ng/mL)에서 약간 높은 값(11.3~22.l%)을 나타내었지만 그 이상의 농도에서는 좋은 정밀도를 나타내었다.

• 한국환경과학회지
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• 제24권9호
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• pp.1189-1197
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• 2015

The aim of this study was to investigate the nutrient removal using Mg-Sericite flocculant in the dyeing wastewater. Mg-Sericite flocculant was removed successfully > 98% of the Color, SS. COD and BOD in the dyeing wastewater at the following optimal Mg-Sericite dosage: 100 mg/L for Colour and SS, 300 mg/L for BOD and COD. The removal of TN and TP was obtained 92.00% with 50 mg/L and 87.80% with 100 mg/L Mg-Sericite dosage, respectively. These results was indicated that the amount of 0.79~1.31, 0.22~0.37, 0.5 and 0.16 mg/L Mg-Sericite was necessary for 1 mg/L removal BOD, COD, TN and TP, respectively. The biopolymer, Mg-Sericite, can be a promising flocculants due to its high efficiency and low dose requirements. In addition, Mg-Sericite does not contaminate treated wastewater, which can be recycled to reduce not only the cost and the demand for water but also the extra operational costs for reusing wastewater. This flocculation method is helpful to lower the wastewater treatment cost.