• 한국염색가공학회지
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• 제8권6호
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• pp.27-32
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• 1996

This research is to investigate the reaction kinetics by air-lift bioreactor using calcium hydroxide, the neutralization agent and immobilization media, for removing ethylene glycol remained after chemical pretreatment. It was found that the optimum hydraulic retention time was obtained as 24.2hours at the optimum F/M ratio of 1.32kg-$TCOD_{Mn}$/day.kg-MLVSS, and then, infiuent $TCOD_{Mn}$ and MLVSS concentration were 3,290mg/l and 2,472mg/l, respectively. During the steady state, the kinetics constants such as maximum specific substrate removal rate, half saturation velocity coefficient, yield coefficient and endogenous respiration coefficient were estimated in the base of $TCOD_{Mn}$ as substrate concentration. And they were 1.47day$^{-1}$, 3.95mg/l, 0.391 and 0.092day$^{-1}$, respectively. And also, the oxgen use coefficients for cell synthesis, a', and energy of maintenance, b', were obtained as 0.4kg-O$_{2}$/kg-$TCOD_{Mn}$ and 0.056day$^{-1}$, at the steady state by the experimental result of oxygen uptake rate.

• 한국환경과학회지
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• 제15권7호
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• pp.659-667
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• 2006

This research aims at applicability of adsorption process in order to satisfy the restricted Effluent Quality Standards for dyeing wastewater. The dyeing wastewater treated by biological process with carrier imbedded microorganisms was directly applied to the activated carbon adsorption in Process A, The dyeing wastewater treated by Fenton oxidation for the effluent of biological process was applied to the adsorption in Process B. It was found that the optimum conditions of adsorption with granular activated carbon are $20^{\circ}C$ and 120 minutes for the batch experiment. Langmuir equation was fitted better than Freundlich equation to the experimental data. The breakthrough time of adsorption column was determined by color rather than $COD_{Mn}$ for both Process A and Process B. The results revealed that the breakthrough time of adsorption for two processes was extended by the treatment of Fenton oxidation for dyeing wastewater treated by biological treatment than the direct application of dyeing wastewater treated by the biological treatment. Adsorption process can be applied in order to meet the restricted Effluent Quality Standards for dyeing wastewater.

• 한국산업융합학회 논문집
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• 제5권3호
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• pp.213-218
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• 2002

Total nitrogen is a major pollutant which mostly causes eutrophication and red tide. Wastewater effluent from printing of cotton-viscose rayon containing high concentrations of total nitrogen can not be effectively treated with a typical biological treatment process. This paper provides a new treatment process and experimental results for the removal of high strength nitrogen from dyeing wastewater. The optimum conditions of air stripping for the removal of total nitrogen include around pH 12, temperature $60^{\circ}C$ with 60 minutes of stripping time. In case of a filtration-air stripping process, an initial level ($500mg/{\ell}$) of total nitrogen was significantly reduced to below $60mg/{\ell}$. Deconite was synthesised for further decomposition of organic nitrogen. Thus, a filtration-decomposition-air stripping process was possibly achieved, by which a high level ($900mg/{\ell}$) of total nitrogen was effectively removed to below $60mg/{\ell}$ P. Finally, a continuous new process for the removal of total nitrogen is proposed and confirmed, based on batch experimental results, and its process validity is further discussed throughout.

• 한국의류학회지
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• 제24권3호
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• pp.385-392
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• 2000

The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous HCI solution and deproteination in dilute aqueous NaOH solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chitin were measured in varieties of dye concentration and dipping periods. Four kinds of dyestuffs were used, C.I.Acid Blue 29. C.I.Direct Blue 6, C.I.Reactive Orange 12 and C.I.Basic Red 18. When chtin 1g was dipped in 0.05% of dyebath with stirring, maximum adsorption ratio of each kind of dyes was exhibited as 91.6% for C.I.Acid Blue 29, 95% for C.I.Direct Blue 6, 58.2% for C.I.Reactive Orange 13 and 75.8% for C.I.Basic Red 19. It shows that chitin has better adsorption abilities of ionic dyes of acid, direct and basic dye than non-ionic reactive dye. And chitin has better adsorption abilities of anionic acid direct dyes than cationic basic dye because of the presence of nitrogen atoms. All kinds of dyestuffs used showed speedy absorption effects by chitin, so chitin can absorb much amount of dyes in 5 mimutes reach to equilibrium of adsorption in 2 hours after dipping. Basic dye was absorbed the most speedily in 5 minutes, although maximum adsorption ratio is not high. That reason can be thought that chitin surface is essentially negatively charged due to polar funtional groups.

• 한국응용과학기술학회지
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• 제15권4호
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• pp.87-93
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• 1998

In spite of various applications of chitin derivatives from waste marine sources, commercial use of chitin has been limited due to resistance to chemicals and the absense of proper solvents. We prepared chitin through decalcification, bleaching and deproteination from protunus trituberculatus shells by the application of Hackman's method. Structural and chemical properties of chitin were investigated to have proper specific surface area and particle size by IR, BET and PSA. The amount of absorbed water of chitin reached equilibrium by stirring about 15 minutes. The amount of absored water of the prepared chitin were large than the commercial chitin. When prepared chitin tested on dyeing wastewater, they showed better treatment efficiency in COD, suspended solid, and color tests than the commercial chitin. The adsorption capacity increased with decreasing particle size for the prepared chitin. Treatment efficiency for color was increased as the sitirring rate increased. Results show the possibility of the prepared chitin from waste marine sources as a treatment system for dyeing wastewater.

• 한국물환경학회지
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• 제25권5호
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• pp.758-763
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• 2009

This study presents the optimal conditions of zero-valent iron (ZVI) pretreatment for color removal from real dye wastewater. Removal of color by ZVI was strongly subject to the acidity of the wastewater buffering the pH increased after ZVI reduction. The real dye wastewater did not contain a sufficient amount of acidity and thus it was necessary to supplement acid to the dye wastewater before treatment. In continuous operation of iron column, the empty bed contact time (EBCT) and initial pH were varied to find the optimal conditions. A non-linear regression model fitted well the experimental result predicting that the optimal EBCT and pH for 80% removal efficiency was present in the range of 57~90 and 5~5.9, respectively. Color of column effluents could be further removed in the following biological oxidation step and the biodegradability of wastewater was also enhanced after iron pretreatment.

• 한국물환경학회지
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• 제23권6호
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• pp.881-888
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• 2007

In order to investigate the characteristics of the non-biodegradable material, the $BOD_5/COD_{Cr}$ ratio was used. The average ratio of industrial complex's influent wastewater was 2.29~2.96, the effluent ratio was 4.29~19.0. The removal efficiency of $UV_{254}$ by physicochemical treatment was 22.8~94.7% and 5.3~77.2% by biological treatment, respectively. Of the wastewater removal efficiency for each of the items, the $BOD_5$ treatment efficiency was the greatest at 97.3% and the color & TN treatment efficiency was 40~70%. The study of the economical assessment showed that the complex as well as the individual companies spent 722~1,298 won for each ton of treated wastewater. All of the wastewater treatment facilities spent the most money on chemicals needed to treat the wastewater. The total cost for Nylon manufacturing wastewater treatment plant was the greatest while the total cost for cotton manufacturing wastewater treatment plant turned out to the lowest. As respects of removal efficiency and economocal assessment, Polyester A and Cotton manufacturing wastewater treatment plants were better effective than a dyeing industrial complex wastewater treatment plant.

• Korean Chemical Engineering Research
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• 제40권6호
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• pp.715-718
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• 2002

폴리에스터의 염색공정에서 발생하는 폐수문제를 근원적으로 해결하기 위해서 초임계 유체를 이용한 건식염색기술이 관심의 대상이 되고 있다. 본 연구에서는 반 유통형인 초임계유체 평형실험장치를 이용하여 초임계 상태의 HFC-134a에 대한 분산염료인 C. I. disperse red 60의 용해도를 382.2 K와 413.2 K의 온도와 50, 70, 100, 130, 160 bar의 압력에서 측정하였다. 초임계유체를 고압의 액체로 간주하는 확장액체모델에 측정된 데이터들을 상관하면 실험값과 계산값이 잘 일치하였다.

• 한국환경과학회지
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• 제14권7호
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• pp.683-689
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• 2005

The consecutive combination process of a biological process as the pre-treatment and a chemical process as the post-treatment is applied for the dyeing wastewater. The poor efficiency of biological treatment using pure oxygen makes the chemical treatment cost high. It is necessary to improve the efficiency of biological treatment in order to reduce the cost of chemical treatment. The purpose of this paper is to find the minimum dose of chemical reagent to fit the Discharged Water Quality Standards for the different biological treatment effluents. Results revealed that the minimum dosage of Fenton's reagent lead to save the cost of chemical treatment based on the guideline dose in the treatment plant. The possible maximum saving reagents was up to $70\%$ for the effluent of the pilot plant packed with the carrier imbedded microorganisms which were selected from the present treatment plant.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.2141-2143
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• 2000

In this paper, high concentration yield multi-discharge type ozonizer (MDO) of new discharge type using superposed silent discharge was designed and manufactured, MDO can be consisted with 3 kind of multi discharge type ozonizer (MDO) in accordance with power supply method that supplying power, which has 180[$^{\circ}$] phase difference, to 3 electrodes and double gap. At the moment, discharge characteristics and ozone generation characteristics of each MDO were investigated in accordance with quantity of supplied gas, the number of MDO, and the shapes of each MDO. In result, ozone generation characteristics of 17185[ppm] and 783[g/kWh] were obtained, and when ozone of 17185 [ppm] was in contact with dyeing water waste, decolorization characteristics was excellent, so it confirmed that MDO could be used as water environment improvement facility.