• Analytical Science and Technology
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• v.9 no.1
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• pp.1-12
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• 1996

The thermally labile compounds with hydroxyl group generate the [${MNH_4}^+$] ion, [$MH^+$] and [$MH^+-OH$] ion by ion-molecule reaction in LC/TSP/MS. But these ions create the trouble in the estimation of molecular weight of an unknown compound because the margin of [${MNH_4}^+$] ion and [$MH^+$] ion is same to that of [$MH^+$] ion and [$MH^+-OH$] ion. If it is compensated for the results by using of the $CF_3COOD+NH_4OH$ LC eluent, the molecular weight of analyte will be able to be confirmed. And this study was tried to recognize whether the fragment ions of thermally labile compound are generated by electron impact or by thermal degradation in ion source.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1989.11a
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• pp.41-58
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• 1989

현재 자동차엔진유를 비롯한 각종윤활유에 마찰마모방지제 및 산화방지제로 사용되고 있는 유용성 몰리부덴계 화합물은 윤활제의 첨가제로서 주목받고 있다. 이와 같은 유용성 몰리부덴계 화합물은 윤활제의 첨가제로서 마찰부분의 고온에 의해 열분해함으 2 유화몰리부덴($MoS_2$)을 생성하기 위해서 합성한 것이다. $MoS_2$는 마찰마모 감소제로서 잘 알려져 있지만 고체이기 때문에 마찰면에 COATING 하거나 윤활유에 분산시켜 사용하고 있다. 그러나 윤활유에 분산시키는 것과 마찰면에 흡착시키는 것과는 계면화학적 반대현상이므로 문제가 발생하게 된다. 그러므로 윤활유중에 안정한 분산계를 만들어 사용시에는 비교적 안정한 COLLOID 계가 파손되지 않아야 한다. 그러나 열가학적으로 불안정한 COLLOID 계를 유지하기는 어려운 문제이다. 그러므로 유용성인 몰리부덴계 화합물을 윤활유에 용해시켜 열적 혹은 TRIBOCHEMICAL 적으로 분해해 줌으로서 마찰표면에 $MoS_2$의 생성이 필요하다. 이와같은 목적으로 개발된 유용성 몰리부덴화합물은 마찰마모감소작용 및 산화방지작용의 메카니즘에 관해서는 불투명한 점이 많다. 본 논문은 유용성 몰리부덴계 화합물중 Molybdenum dialkyl dithiocarbamate (이후 MoDTC로 명함)를 윤활유 첨가제로 사용해 마찰실험을 통하여 마찰감소작용의 메카니즘을 해명하고, 특히 마찰표면에 생성될 $MoS_2$막의 효과에 관해 중점을 두고 분위기의 효과로 부터 MoDTC의 마찰감소작용의 인자에 대한 고찰을 행하였다.

• Journal of the Korean Institute of Gas
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• v.18 no.6
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• pp.21-26
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• 2014

Renewable gas fuels such as biogas and landfill gas have carbon-neutral nature which can reduce carbon dioxide. However, it is necessary to make stable combustion when this fuel is used in power generating SI(spark ignition) gas engines due to its low heating value and non-uniformity. In this study, it was shown that addition of hydrogen can increase combustion stability of gas engine which is running with high inert gas composition. Thermal efficiency and emission characteristics of this engine was also investigated. In addition, a new spark plug with a long electrode was tested and compared with a base spark plug as a way to improve engine efficiency and reduce exhaust emissions.

• Microbiology and Biotechnology Letters
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• v.17 no.1
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• pp.69-73
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• 1989

Cellular autolytic enzyme was isolated from the supernatant fluid of exponentially growing cuiture of Cl. butyricum ID-113. The autolysin was partially pruified by ammonium sulfate fractionation, chromatography on DEAE-Sephadex A-50 and gel filtration through Sephadex G-200. This autolytic enzyme lysed SDS-treated cell wall fractions of Cl. butyricum ID, but not whole cells at all. Its optimum pH and temperature were 5.0 and 37$^{\circ}C$, respectively. This enzyme was relatively stable at neutral pH, but sensitive to heat treatment. Enzyme activity was not influenced by the addition of various divalent cation, but inhibited by Cu$^{++}$.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.3
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• pp.1352-1358
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• 2012

The dynamic analysis of delaminated composite structures is carried out based on the higher order plate theory. In the finite element (FE) formulation, the seven degrees of freedom per each node are used with transformations in order to fit the displacement continuity conditions at the delamination region. The boundaries of the instability regions are determined using the method proposed by Bolotin. The numerical results obtained for skew plates are in good agreement with those reported by other investigators. The new results for delaminated skew plate structures in this study mainly show the effect of the interactions between the geometries and other various parameters.

• The Journal of the Korea Contents Association
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• v.16 no.5
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• pp.449-462
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• 2016

The aim of this study is to look into the role stress, job insecurity, self-efficacy and job engagement among broadcasting staffs. It is the ultimate goal for this study to probe how their job engagement affected by three factors - role stress, job insecurity, self-efficacy. 343 respondents participated and the results show they are suffering for the role stress, especially role conflict. Their awareness of the self-efficacy and job engagement is above average, meanwhile of job insecurity is comparably low. It is revealed that the less role ambiguity and the more self-efficacy affect their job engagement and the most influential factor is self-efficacy.

• The Korean Journal of Applied Statistics
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• v.21 no.5
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• pp.727-738
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• 2008

If a cointegrating relation is affected by important economic and political events occurred in the sample period, the assumption of the time-invariant cointegrating vector is violated, which leads to the misrep-resentation of the actual relations between the variables. From such a viewpoint, this study utilizes the recursive estimation process in testing for the stability of the long-run equilibrium of the domestic stock market system and then attempts to develop the framework for stabilizing time-variant cointegraing relations by introducing the dummy variables where the structural changes are found to exist.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.853-858
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• 2001

The knowledge of flame structure is essential for control of combustion instability phenomena. Some results of an experimental study on mechanism of naturally occurring combustion oscillations with a single dominant frequency are presented. Tests were conducted in a laboratory-scale dump combustor at atmospheric pressure. Sound level meter was used to track the pressure wave inside the combustor. The observed instability was a longitudinal mode with a frequency of $\sim341.8Hz$. Instability map was obtained at the condition of inlet temperature of $360^{\circ}C$, mean velocities of $8.5\sim10.8m/s$ and well premixed mixture. It showed that combustion instability was susceptible to occur in the lean conditions. In this study, unstable flame was observed from stoichiometric to 0.7 in overall equivalence ratio. At selected unstable conditions, phase-resolved OH chemiluminescence images were captured to investigate flame structure with various mean velocities. As mean velocity is increased, the flame grows and global heat release was changed. Due to these effects, combustion instability can be maintained at more lean air-fuel ratio. Also, these results give an insight to the controlling mechanism for an increasing heat release at maximum pressure.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.11a
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• pp.119-122
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• 2007

The present study employs experimental approach to identify combustion stability characteristics of fuel-rich gas generators. The gas generator of interest, fueled by LOx and Jet A-1, experienced combustion instability coupled to a longitudinal resonant mode of the combustion chamber at about 1200 Hz. The occurrence of instability is strongly associated with acoustic boundary condition at the exit .and axial location of maximum heat release. As a result, stretching heat release zone in the axial direction by increase of the fuel nozzle diameter has dramatically stabilized combustion.

• Journal of the Institute of Electronics and Information Engineers
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• v.52 no.8
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• pp.148-155
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• 2015

The Levenberg-Marquardt method is a well known solution about the least square problem. However, in a Target Motion Analysis(TMA) application most of researches have used the Gauss-Newton method as a batch estimator, which of inverse matrix calculation may causes instability problem. In this paper, Levenberg-Marquardt method is applied to TMA problem to prevent its divergence. In experiment, its performance is compared with Gauss-Newton in domain of range, course and speed. Monte Carlo simulation reveals the convergence time and reliability of the TMA based on Levenberg-Marquardt.