• Title/Summary/Keyword: 열화학

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Electrical Characteristics of PECVD $Ta_2O_5$ Dielectic Thin Films on HSG and Rugged Polysilicon Electrodes (입체표면 폴리실리콘 전극에서 PECVD $Ta_2O_5$ 유전박막의 전기적 특성)

  • Cho, Yong-Beom;Lee, Kyung-Woo;Chun, Hui-Gon;Cho, Tong-Yul;Kim, Sun-Oo;Kim, Hyeong-Joon;Koo, Kyung-Wan;Kim, Dong-Won
    • Journal of the Korean Vacuum Society
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    • v.2 no.2
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    • pp.246-254
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    • 1993
  • In order to increase the capacitance of storage electrode in the DRAM capacitor, two approaches were performed. First, hemispherical and rugged poly silicon films were made by LPCVD to increase the effective surface area of storage electrode. The even surface morphology of conventional poly silicon electrode was changed into the uneven surface of hemispherical of rugged poly silicon films. Second, PECVD $Ta_2O_5$ dielectric films were deposited and thermally treated to study the dielectrical characteristics of $Ta_2O_5$ film on each electrode. MIS capacitors with $Ta_2O_5$ films were electrically characterized by I-V, C-V and TDDB measurements. As a result, the capacitance of the electrode with uneven surface were increased by a factor of 1.2~1.5 and leakage current was increased compared with those of even surface. TDDB result indicates that the electrode with uneven surface has dielectrically more degraded than that of even surface. These results can be helpful as a basic research to develop new generation DRAM capacitors with $Ta_2O_5$ films.

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The Effects of Electrode Materials on the Electrical Properties of $Ta_2O_5$ Thin Film for DRAM Capacitor (DRAM 커패시터용 $Ta_2O_5$ 박막의 전기적 특성에 미치는 전극의존성)

  • Kim, Yeong-Wook;Gwon, Gi-Won;Ha, Jeong-Min;Kang, Chang-Seog;Seon, Yong-Bin;Kim, Yeong-Nam
    • Korean Journal of Materials Research
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    • v.1 no.4
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    • pp.229-235
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    • 1991
  • A new electrode material for $Ta_2O_5$ capacitor was developed to obtain both high dielectric constant and improved electrical properties for use in DRAM. High leakage current and low breakdown field of as-deposited $Ta_2O_5$ film on Si is due to the reduction of $Ta_2O_5$ by silicon at $Ta_2O_5$/electrode interface. $Dry-O_2$ anneal improves the electrical properties of $Ta_2O_5$ capacitor with Si electrode, but it thickens the interfacial oxide and lowers the dielectric constant, subsequently. $Ta_2O_5$ capacitor with TiN exectrode shows better electrical properties and higher dielectric constant than post heat treated $Ta_2O_5$ film on Si. No interfacial oxide layer at $Ta_2O_5$/TiN interface suggests that there\`s no Interaction between $Ta_2O_5$ and electrode. TiN is a adequate electrode material for $Ta_2O_5$ capacitor.

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Improvement of Durability in Concrete Structures Using CRM (내화학성 적층보강공법(CRM)을 활용한 콘크리트 구조물의 내구성능 향상)

  • Kim, Chun-Ho;Kim, Sang-Doh;Kim, Nam-Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.6
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    • pp.145-152
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    • 2013
  • As a typical construction material, concrete has been used in building all kinds of structures since the late $19^{th}$ century. Although it was recognized to secure durability as long as the regulations on design and construction have been reasonably complied, the trends of life-shortening and deterioration have frequently occurred due to all kinds of the external effects that have been experienced during the procedures of using the structures. To make matters even worse, deterioration of the concrete structures according to deterioration can not be controlled any more. Finally, the reality is that repair and maintenance are necessary in the maintenance aspect of the concrete structure. In this study, CRM(Chemical Resistance of Laminating Reinforcement Method), which had been developed to reinforce the surface of concrete and specially improve chemical resistance performance, has been applied to enhance the existing repairing and maintenance method. Therefore, the result has been drawn with comparison and analysis of the specimens applied with the general repairing and maintenance method and CRM through a variety of durability test in this study. With the result of the test, durability of the specimen applied with CRM has been more improved than the existing repairing and maintenance method, which is judged as because of the laminating effect due to reinforcement of epoxy impregnated of alkali-resistance fiber and double layered fiber reinforced seat.

Experimental Study on Dilution Effect of Exhaust Gas in SNG Combustion on a Model Gas Turbine (가스터빈에서 SNG 연료 조성에 대한 희석제의 배기배출물 저감효과에 대한 실험적 연구)

  • Joo, Seongpil;Yoon, Jisu;Kim, Jeongjin;Kim, Seongheon;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.7
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    • pp.603-610
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    • 2016
  • This paper describes experimental results about emission and NOx reduction of dilution effect (Nitrogen and carbon dioxide) about various fuel compositions of synthetic natural gas (SNG). Combustion experiment was performed to investigate the combustion characteristics for SNG with various hydrogen ratio in SNG, heat input and equivalence ratio in a partially premixed model gas turbine combustor. NOx emission was similar to each hydrogen ratio and flame characteristics was investigated from OH chemiluminescence images. There was a singularity of CO emission in stoichiometric condition and it can be identified using OH chemiluminescence intensity. In addition, dilution effect was studied in using nitrogen and carbon dioxide as diluent to reduce the NOx emission. Carbon dioxide diluent was more effective to NOx reduction than nitrogen diluent because of its high diluent specific heat and its heat capacity.

The effect of aluminum coating to corrugated packaging on quality characteristics of paprika during storage (골판지 포장재에 알루미늄 코팅이 파프리카의 저장 중 품질특성에 미치는 영향)

  • Kim, Ah-Na;Ha, Myeong-Hwa;Lee, Kyo-Yeon;Rahman, M. Shafiur;Kim, Nam-Sub;Choi, Sung-Gil
    • Food Science and Preservation
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    • v.24 no.7
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    • pp.934-941
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    • 2017
  • The objective of this study was to investigate the effect of corrugated packaging coated with aluminum (Al) on quality characteristics of red paprika during storage at $25^{\circ}C$. Characteristics such as weight loss, hardness, total phenolic content, antioxidant activities, polygalacturonic acid (PG) activity, and oxidative enzyme activities (polyphenol oxidase and peroxidase activities) of paprikas, packed in corrugated packaging with or without Al-coating were compared as a function of storage time. Al coating inside of corrugated box was found to inhibit PG activity, resulting in prevention of weight loss and maintenance of hardness of paprika during storage, compared to the control sample. This may be due to Al coating treatment that enhance moisture-proof property and hinder gas transmission of corrugated packaging. Furthermore, paprika in Al-coated-corrugated packaging was lower in oxidative enzyme activities than the control, which caused higher total phenolic content and antioxidant activities during storage. As a results, the Al coated-corrugated packaging can be used as a functional packaging material to extend the shelf-life and improve the storage quality of paprika by preventing their respiration and transpiration.

Quality differences of retorted Samgyetangs as affected by F0-value levels (레토르트 삼계탕의 F0값 수준에 따른 품질 차이)

  • Lee, Jin Ho;Song, Gi Chang;Lee, Keun Taik
    • Food Science and Preservation
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    • v.23 no.6
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    • pp.848-858
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    • 2016
  • This study was conducted to determine the $F_0$-values of a retort machine at different locations and to evaluate the effects of these $F_0$-values on various quality characteristics of retorted Samgyetang samples. Samples were divided into three groups based on $F_0$-values-T1, 10~20; T2, 20~30; T3, >30. Mineral content in Samgyetang broth and breast meat mostly increased with increasing $F_0$-values. In general, the free amino acid values, hardness, and springiness, except for bone springiness, of Samgyetang decreased significantly at higher $F_0$-values. Protein content of meat and broth of the treated samples were significantly lower than that of the control. An increase in the digestion rate of meat and porridge, as well as the turbidity of the broth was observed in most of the treated samples with increasing $F_0$-values. With increasing $F_0$-values, the $L^*$ and $b^*$ values of meat and the $b^*$ values of broth tended to increase, while the $a^*$ value of broth increased significantly. Electronic nose analysis revealed different flavor patterns for samples treated at different $F_0$-values. For sensory traits, samples treated with higher $F_0$-values tended to receive lower evaluations. Particularly, the color and texture of T3 samples were lower than those of T1 and T2 samples. In conclusion, to improve the quality of Samgyetang, the efficiency and optimization of retort machines as well as the standardization of sterilization techniques are needed.

Effect of pretreatment and packaging methods on quality of cold vacuum dried peach (전처리 및 포장방법이 냉풍감압건조 복숭아의 품질에 미치는 영향)

  • Kwon, Gi-Man;Kim, Jae-Won;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.20 no.3
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    • pp.317-322
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    • 2013
  • This study was conducted to investigate the effects of pretreatment and different packaging methods on the physicochemical properties of cold vacuum-dried peaches. All the dried peach samples were stored such as $N_2$ gas substitution, vacuum and passive packaged with polyethylene (PE) film and oriented polypropylene (OPP)/aluminum (Al)/PE film at $40^{\circ}C$ for 50 days. The weight change, pH, soluble solids content, titratable acidity, soluble solid-acid ratio (SS/TA), delta E, browning degree and phenolic compounds were analyzed. The weight change and pH were lower in the 0.1% vitamin C-treated group and were significantly lowest in the vacuum-treated OPP/AL/PE. The soluble solids content and the SS/TA were higher in the non-treated groups than in the vitamin C-treated groups. According to the packaging methods, the $L^*$ values were higher in the vacuum, $N_2$ gas and passive package, in that order. In addition, the browning degree and the delta E value were lower in the pretreated groups and significantly lowest in the vacuum-treated OPP/AL/PE with 0.1% vitamin C group. The phenolic compounds were high for the pretreated groups, according to the packaging methods (vacuum > $N_2$ gas> passive), and the OPP/AL/PE was significantly higher than the PE. These results suggest that different packaging materials and pretreatment methods affected the quality of the dried peaches, and the vacuum-OPP/AL/PE film packaging group showed a high quality.

The Effects of Thermal Degradation and Creep Damage on the Microstructure and Composition of the Carbides in the CrMo Steels for Power Plant (발전 설비용 CrMo강의 탄화물 구조와 조성 변화에 미치는 열화 및 크리프 손상의 영향)

  • Ju, Yeon-Jun;Hong, Gyeong-Tae;Lee, Hyeon-Ung;Sin, Dong-Hyeok;Kim, Je-Won
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.1018-1024
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    • 1999
  • The effects of operating temperature and stress on degradation of components in high temperature steam generator were investigated. Several 2.25CrlMo tubes which had operated over 20 years and an unused 9CrlMoVNb tube were tested. For the former samples, the amount of $\textrm{M}_{6}\textrm{C}$ carbide and its size are increased with the aging or operating time. The precipitation behavior of carbides ($\textrm{M}_{2}\textrm{O}$, $\textrm{M}_{6}\textrm{C}$) is changed with the operating temperature of the tubes. However, unused 9CrlMoVNb samples show a different carbide precipitation process due to high chromium, vanadium, and niobium contents. The amount of Cr-rich $\textrm{M}_{23}\textrm{C}_{6}$ carbide is significantly increased with aging time, but that of $\textrm{M}_{6}\textrm{C}$ type carbide is rarely changed with aging time at elevated temperatures.

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Effects of B Addition and Heat Treatment on the Magnetic and Magnetostrictive Properties of Amorphous $SmEe_2$ thin Films (비정질 $SmFe_2 $합금의 자기적 및 자기변형 특성에 미치는 B 첨가와 열처리 영향)

  • Choi, K.G.;Jang, Ho;Han, S.H.;Kim, H.J.;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.10 no.5
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    • pp.237-245
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    • 2000
  • Effects of B addition and heat treatment on the magnetic and magnetostrictive properties of amorphous SmFe$_2$ thin films are investigated. A significant improvement in the magnetostrictive properties at low magnetic fields is observed with the addition of B. This improvement, however, is achieved at a heavy cost of intrinsic properties such as saturation magnetostriction. For example, at a magnetic field of 30 Oe, magnetostriction of a thin film with a B content of 9.9 at.% is increased from 190 to 333 ppm, but saturation magnetostriction is decreased by more than 50 %. This result is in accord with the deterioration (reduction) of saturation magnetization and the improvement (reduction) of coercive force at this B content. The magnetostrictive properties are also improved by annealing and optimum annealing temperature is found to be in the range 300-400 $^{\circ}C$. The main reason for the improvement is mainly considered to be due to the reduction of coercive force caused by stress relief, not due to the ultrafine SmFe$_2$ precipitates which were originally expected to form by annealing.

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Characteristics of Silicon Rich Oxide by PECVD (PECVD에 의한 Sirich 산화막의 특성)

  • Gang, Seon-Hwa;Lee, Sang-Gyu;Park, Hong-Rak;Go, Cheol-Gi;Choe, Su-Han
    • Korean Journal of Materials Research
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    • v.3 no.5
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    • pp.459-465
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    • 1993
  • By making the inter-metal PECVD $SiO_2$ as a Si rich oxide under the SOG, the hydrogen and water related diffusants could be captured a t SI dangling bonds. This gettering process was known to prevent the device characteristics degradations related to the H, $H_20$. The basic characteristics of Si rich oxide have been studied according to changing high/low frequency power and $SiH_4/N_2O$ gas flow ratio in PECVD. As increase in low frequency power, deposition rate decreased but K.I. and compressive stress increased. Decrease of the water peaks of FTIR spectra at the wave number range of 3300~3800$\textrm{cm}^{-1}$' also indicated that intensty the films were densified. As increase in SiH, gas flow rate, deposition rate, R.I. and etch rate increased while compressive stress decreased. F'TIK spectra showed that peak intensity corresponding to Si-0-Si stretching vibration decreased and shifted to the lower wave numbers. But AES showed that Si dangl~ng bonds were increased as a result of lower Si:O(l: 1.23) ratlo inthe Si rich oxide as compared to Si : O(1 : 1.98) ratio of usual oxide.

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