• 제목/요약/키워드: 열화학적특성

검색결과 115건 처리시간 0.027초

Degradation Quantification Method and Degradation and Creep Life Prediction Method for Nickel-Based Superalloys Based on Bayesian Inference (베이지안 추론 기반 니켈기 초합금의 열화도 정량화 방법과 열화도 및 크리프 수명 예측의 방법)

  • Junsang, Yu;Hayoung, Oh
    • Journal of the Korea Institute of Information and Communication Engineering
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    • 제27권1호
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    • pp.15-26
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    • 2023
  • The purpose of this study is to determine the artificial intelligence-based degradation index from the image of the cross-section of the microstructure taken with a scanning electron microscope of the specimen obtained by the creep test of DA-5161 SX, a nickel-based superalloy used as a material for high-temperature parts. It proposes a new method of quantification and proposes a model that predicts degradation based on Bayesian inference without destroying components of high-temperature parts of operating equipment and a creep life prediction model that predicts Larson-Miller Parameter (LMP). It is proposed that the new degradation indexing method that infers a consistent representative value from a small amount of images based on the geometrical characteristics of the gamma prime phase, a nickel-base superalloy microstructure, and the prediction method of degradation index and LMP with information on the environmental conditions of the material without destroying high-temperature parts.

Recent Development of Thermo-chemical Conversion Processes with Fluidized Bed Technologies (유동층 공정을 이용한 열화학적 전환 공정의 최신 개발 동향)

  • Hyun Jun Park;Seung Seok Oh;Olusola Nafiu Olanrewaju;Jester Lih Jie Ling;Chul Seung Jeong;Han Saem Park;See Hoon Lee
    • Korean Chemical Engineering Research
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    • 제61권1호
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    • pp.8-18
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    • 2023
  • Increasing of energy demand due to the rapid growth of global population and the development of world economy has inevitably resulted in the continuously increase of fossil fuel usage in the world. However, highly dependence on fossil fuels has necessarily brought about critical environmental issues and challenges such as severe air pollutions and rapid global warming. In order to settle these environmental and energy problems, clean energy generations in the conventional combustion processes have widely adapted in the world. In particular, novel thermochemical conversion processes such as pyrolysis and gasification have rapidly been applied for generating clean energy. Fluidized bed technologies having advantages such as various fuel use, easy continuous operation, high heat and material transfer, isothermal operation, and lower operation temperature are widely adopted and used because they are suitable for thermochemical energy conversion. The latest research trends and important findings in the thermo-chemical conversion process with fluidized bed technologies are summarized in this review. Also, the need for research such as layered materials and substances to reduce fine dust (biomass, natural resource waste, etc.) was suggested. Through this, it is intended to increase interest and understanding in fluidized bed technology and to present directions for solving future challenges in fluidized bed process technology development.

Growth of Amorphous SiOx Nanowires by Thermal Chemical Vapor Deposition Method (열화학 기상 증착법에 의한 비정질 SiOx 나노와이어의 성장)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • 제7권5호
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    • pp.123-128
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    • 2017
  • Nanostructured materials have received attention due to their unique electronic, optical, optoelectrical, and magnetic properties as a results of their large surface-to-volume ratio and quantum confinement effects. Thermal chemical vapor deposition process has attracted much attention due to the synthesis capability of various structured nanomaterials during the growth of nanostructures. In this study, silicon oxide nanowires were grown on Si\$SiO_2$(300 nm)\Pt(5~40 nm) substrates by two-zone thermal chemical vapor deposition with the source material $TiO_2$ powder via vapor-liquid-solid process. The morphology and crystallographic properties of the grown silicon oxide nanowires were characterized by field-emission scanning electron microscope and transmission electron microscope. As results of analysis, the morphology, diameter and length, of the grown silicon oxide nanowires are depend on the thickness of the catalyst films. The grown silicon oxide nanowires exhibit amorphous phase.

NBI 가열 플라즈마에서 고속이온 분포의 수치적 계산 및 측정결과 비교

  • Wang, Seon-Jeong;Kim, Seon-Ho;Kim, Seong-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.263-263
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    • 2012
  • 핵융합 플라즈마에서의 고속이온은 NBI 및 ICRF에 의한 이온 가열과 핵융합 반응에 의하여 발생하며, 핵융합 반응률을 크게 하고 일차적으로 그 에너지를 전자에게 전달하는 특성을 갖는다. 따라서 핵융합을 지향하는 플라즈마에서는 그 성능을 나타내는 지표이기도 하면서, 맥스웰 분포를 갖는 열화 플라즈마의 수송특성을 크게 변화 시킨다. 또한 알펜파 등의 파동 또는 불안정성을 유발시키며 이로 인한 플라즈마 손실은 국지적인 일차벽의 가열을 유발할 수 있는 것으로 여겨진다. 본 연구에서는 일반적인 기하학적 구조를 갖는 토카막에서의 NBI 가열에 의한 고속이온 발생과 위상공간에서의 수송 및 손실을 시간 의존적인 Fokker-Planck 방정식을 수치적으로 풀어서, 위치에 따른 고속이온 분포의 변화를 계산한다. NBI 입사의 기하학적 모델에서는 각 계산 위치에서의 피치각 변화와 stagnation point의 변화에 의한 영향을 고려하며, 일반적인 고속이온의 각종 모멘트 뿐 아니라 즉발 이온 손실률을 계산에 포함한다. 해석된 고속이온 분포는 중성입자 검출기에서 측정한 KSTAR 플라즈마의 고속이온 에너지 분포와 비교한다. 차후에는 본 연구에서 사용한 Fokker-Planck 출동연산자에 고주파 가열에 의한 고속이온발생 항을 추가하여 ICRF 가열에 의한 효과를 예측할 수 있도록 할 것이다.

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Aging Characteristics of Power Transformer Oil and Development of its Analysis using KOSM (전력용 변압기유의 열화 특성에 KSOM에 의한 분석기법 개발)

  • 임재윤;지평식;이종필;남상천;이승렬
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • 제13권3호
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    • pp.56-63
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    • 1999
  • In power system, substation facilities have become too complex and large according to extended power system. Also, some facilities becorre old and often break down unexpectedly. In order to improve the sectrity of transformer out of substation facilities, the development of diagnosis technique to transformer is very needed. In this paper, we developed a method to be analysis the origin and degree of aging by KSOM based on the dissolved gases in power transfonrer. KSOM can do topological mapping for the multi-dimensional pattern based on the dissolved gases to two dimensional plane. And potential possibility and degree of aging for nonna1 transfonrer are presented using the proposed quantitative criterion. Furtherrrore, the aging process of transfonrer is analyzed based on the proposed criterion to special transfonrer. To demonstrate the validity of peoposed method, case study is performed and its results are presented.sented.

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Characterization of Thermal Degradation of Polymide 66 Composite: Relationship between Lifetime Prediction and Activation Energy (폴리아미드 66 복합소재의 열 열화 특성: 수명 예측과 활성화 에너지의 상관관계)

  • Jung, Won-Young;Weon, Jong-Il
    • Polymer(Korea)
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    • 제36권6호
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    • pp.712-720
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    • 2012
  • Thermal degradation for glass fiber-reinforced polyamide 66 composite (PA 66) with respect of thermal exposure time has been investigated using optical microscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. As the thermal exposure time was prolonged, a slight increase in tensile strength for only initial stage and afterward, a proportional decrease of tensile strength was observed. These results can be explained by the increase of crystallinity, followed by the increase of crosslinking density, chain scission and the decrease in chain mobility, due to thermal oxidation with the exposure time. Fourier transform infrared spectroscopy results showed the increase of ketone peak and silica peak on the surface of thermally exposed PA 66. In addition, the thermal decomposition kinetics of PA 66 was analyzed using thermogravimetric analysis at three different heating rates. The relationship between activation energy and lifetime-prediction of PA 66 was investigated by several methodologies, such as statistical tool, UL 746B, Ozawa and Kissinger. The activation energy determined by thermogravimetric analysis had a relatively large value compared with that from the accelerated test. This may result in over-estimating the lifetime of PA 66. In this study, a master curve of exponential fitting has been developed to extrapolate the activation energy at various service temperatures.

Conservation condition of academic museum cultural properties and biological environmental investigation (대학박물관 수장환경조사 및 생물학적 환경조사)

  • 이중수;배미현;이민수;박지선;황석연;김기현
    • KOMUNHWA
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    • 64호
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    • pp.111-131
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    • 2004
  • Academic museum have to prevent damage about a microorganisms(bacteria, fungi) and damage in current facilities and environmental condition, and an exhibition or garnered relics and are so, analysis checks maintenance environmental condition of an academi

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PVAc Latex 접착제의 열적특성

  • 권재범;이내우;강돈오;설수덕
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 한국안전학회 2002년도 추계 학술논문발표회 논문집
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    • pp.297-300
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    • 2002
  • 고분자물질의 용도는 다양하다. 그러나, 열에 약한 것이 고분자물질의 가장 큰 단점으로서 이러한 열화현상은 피하거나 예방되어야 할 과제이다. 이런 과정을 제거하거나 지연시키는 작업 즉, 안정화가 필요하다. 따라서 공중합물질을 제조하는 과정은 안정화에 큰 영향을 미치고, 특히 유리전이온도나 기계적 강도를 높이기 위하여는 공중합에 의한 조성변화가 필요하다. 그 외에 형태학적 입자나 오염물질들도 안정화에 영향을 미치고, 고분자의 입체규칙도 역시 안정화에 영향을 미친다.(중략)

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Preparation and Characterization of Sulfonated Poly(Arylene Ether Sulfone) Random Copolymer Reinforced Membranes for Fuel Cells (연료전지용 술폰화 폴리아릴렌에테르술폰 랜덤공중합체 강화복합막의 제조 및 특성)

  • Ahn, Juhee;Lee, Chang Hyun
    • Membrane Journal
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    • 제26권2호
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    • pp.146-151
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    • 2016
  • Sulfonated poly (arylene ether sulfone) (SPAES) random copolymers have merits such as high proton conductivity, relatively low production cost, and thermochemical resistance when applied as polymer electrolyte membranes for fuel cells. However, it is difficult to directly employ SPAES copolymers into practical fuel cell membrane applications owing to their low chemical stability and dimensional instability under harsh operation conditions. A plausible solution is to impregnate SPAES copolymers into support films (e.g., electrospun polyimide support) with interconnected pore structures and high thermochemical toughness. In this study, a SPAES copolymer with a swivel group, which induces high free volume for fast ion transport, is chosen as ionomers to prepare pore-filling membranes (PFMs). The feasibility of the resulting membranes is evaluated via membrane characterizations.

Key Factors that can Affect the Chemical Reaction Kinetics of Aged Metals/KClO4-based Energetic Materials (수분노화된 금속/KClO4 산화제 기반 고에너지 물질의 화학반응역학 변화를 유발하는 주요인자 확인)

  • Oh, Juyoung;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • 제26권4호
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    • pp.28-43
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    • 2022
  • To minimize such loss due to aging, research on energetic materials is being actively conducted though, there are difficulties in identifying the comprehensive aging mechanisms as they focused on the respective materials. In this study, thermal and surface analysis were performed on energetic materials composed of metals(W, Ti, and Zr) and KClO4 oxidizer to solve the blind spots of this aging study. It was newly found that the metals in the hygrothermally aged compounds can cause significant changes in performance. For example, the growth in the thickness of the oxide film on the metals led to an increase in the average value of activation energy(Eα). In addition, the standard deviation of Eα tends to dependent on the type of metal, which is due to the difference in electronegativity.