• Title/Summary/Keyword: 열화학이론

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Theoretical calculation of the parameters influencing on the performance of high explosives (고성능폭약의 성능에 영향을 미치는 요소들의 이론적 계산)

  • 권상기
    • Tunnel and Underground Space
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    • v.10 no.2
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    • pp.218-226
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    • 2000
  • In order to determine the performance of an explosive, various parameters such as the detonation pressure, detonation velocity, heat generation, and fume generation of the explosive should be accurately described. In this study, the pressure increase, volume expansion, temperature increase, and detonation velocity of high explosives were tried to determined theoretically based on thermochemical theories. From this study, a Fortran program for calculating the explosion parameters, which can influence on the performance of explosives, was developed and applied to the high-explosives, ANFO and NG.

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Implementation of the Probe System with Respect to the Engine Oil States Inspection (엔진오일 상태점검을 위한 프로브 시스템 구현)

  • Kim, Young-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.25-29
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    • 2012
  • In this paper, in order to measure the degree of degradation using the reflection coefficient of the probe, the measuring circuit is designed. we put pulse signal into the probe and measure the reflected signal in the circuit. As the condition of engine oil degradation, we can see that the reflected signal was increased and as the engine oil temperature increases, a phenomenon shows that the degradated dielectric constant is decreased. Finally, the theoretical values and measured values of the reflection coefficients of the probe are analyzed.

Theoretical Characteristics of the Probe with Respect to the Engine Oil States (엔진오일 상태에 대한 프로브의 이론 특성)

  • Kim, Young-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.22-24
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    • 2012
  • Depending on the status of the engine oil, the dielectric constant is changed. Dielectric constant of oil is related to the characteristic impedance of the probe and the characteristic impedance of the probe determines the reflected signal. In this paper, we derive an equivalent circuit of the probe and using the dielectric constant obtained by measuring the capacitance, the theoretical reflection coefficient of the probe was calculated. In the results, if the engine oil is deteriorated, we can see that the reflection coefficient is increased.

A Study on the Measurement of Ultrasound Velocity to Evaluate Degradation of Low Voltage Cables for Nuclear Power Plants (원전 저압케이블 열화도 평가를 위한 초음파 음속계측에 관한 연구)

  • Kim, Kyung-Cho;Kang, Suk-Chull;Goo, Charles;Kim, Jin-Ho;Park, Jae-Seok;Joo, Geum-Jong;Park, Chi-Seung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.4
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    • pp.325-330
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    • 2004
  • Several kinds of low voltage cables have been used in nuclear power plants for the supply of electric power, supervision, and the propagation of control signals. These low voltage tables must be inspected for safe and stable operation of nuclear power plants. In particular, the degradation diagnosis to estimate the integrity of low voltage rabies has recently been emphasized according to the long use of nuclear power plants. In order to evaluate their degradation, the surrounding temperature, hardness of insulation material, elongation at breaking point (EAB), etc. have been used. However, the measurement of temperature or hardness is not useful because of the absence of quantitative criteria; the inspection of a sample requires turning off of the power plant power; and, the electrical inspection method is not sufficiently sensitive from the initial through the middle stage of degradation. In this research, based on the theory that the ultrasonic velocity changes with relation to the degradation of the material, we measured the ultrasonic velocity as low voltage cables were degraded. To this end, an ultrasonic degradation diagnosis device was developed and used to measure the ultrasonic velocity with the clothing on the cable, and it was confirmed that the ultrasonic velocity changes according to the degradation of low voltage cables. The low voltage cables used in nuclear power plants were degraded at an accelerated rate, and EAB was measured in a tensile test conducted after the measurement of ultrasonic velocity. With the increasing degradation degree, the ultrasonic velocity decreased, whose potential as a useful parameter for the quantitative degradation evaluation was thus confirmed.

Bending Fatigue Characterization of Al6061 Alloy by Acoustic Nonlinearity of Narrow Band Laser-Generated Surface Wave (협대역 레이저 여기 표면파의 음향버선형성을 이용한 A16061 합금의 굽힘피로손상 평가)

  • Nam, Tae-Hyung;Choi, Sung-Ho;Jhang, Kyung-Young;Kim, Chung-Seok;Lee, Tae-Hun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.139-145
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    • 2010
  • Bending fatigue of aluminium alloy was characterized by acoustic nonlinearity of narrow band laser-generated surface wave. The higher harmonic components generated intrinsically by arrayed line laser beam were analyzed theoretically and acoustic nonlinearity was measured successfully on the surface of fatigue damaged aluminium 6061 alloy. The acoustic nonlinearity increased as a function of fatigue cycles and has close relation with damage level. Consequently, the nonlinear acoustic technique of laser-generated surface wave could be potential to characterize surface damages subjected to fatigue.

Delamination Evaluation of Thermal Barrier Coating on Turbine Blade owing to Isothermal Degradation Using Ultrasonic C-scan Image (초음파 C-scan을 이용한 터빈 블레이드 열차폐코팅의 등온열화에 의한 박리 평가 기법)

  • Lee, Ho-Girl;Kim, Hak-Joon;Song, Sung-Jin;Seok, Chang-Sung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.5
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    • pp.353-362
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    • 2016
  • Thermal barrier coating (TBC) is an essential element consisting of a super-alloy base and ceramic coating designed to achieve long operational time under a high temperature and pressure environment. However, the top coat of TBC can be delaminated at certain temperatures with long operation time. As the delamination of TBC is directly related to the blade damage, the coupling status of the TBC should be assured for reliable operation. Conventional studies of nondestructive evaluation have been made for detecting generation of thermally grown oxide (TGO) or qualitatively evaluating delamination in TBC. In this study, the ultrasonic C-scan method was developed to obtain the damage map inside TBC by estimating the delamination in a quantitative way. All specimens were isothermally degraded at $1,100^{\circ}C$ with different time, having different partial delamination area. To detect partial delamination in TBC, the C-scan was performed by a single transducer using pulse-echo method with normal incidence. Partial delamination coefficients of 1 mm to 6 mm were derived by the proportion of the surface reflection signal and flaw signal which were theoretical signals using Rogers-Van Buren and Kim's equations. Using the partial delamination coefficients, the partial delamination maps were obtained. Regardless of the partial delamination coefficient, partial delamination area was increased when degradation time was increased in TBC. In addition, a decrease in partial delamination area in each TBC specimen was observed when the partial delamination coefficient was increased. From the portion of the partial delamination maps, the criterion for delamination was derived.

A Pulse-Echo Testing Model for Partially Damaged Ultrasonic Transducers (부분 손상을 입은 초음파 탐촉자의 펄스-에코 시험 모델)

  • Song, Sung-Jin
    • Journal of the Korean Society for Nondestructive Testing
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    • v.16 no.2
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    • pp.95-108
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    • 1996
  • In ultrasonic testing, flaw signal from which quantitative information on flaws is determined is influenced by 3 factors : (1) the incident wavefield.produced by the transducer, (2) the scattered waves produced by flaws, and (3) the reception of the scattered waves back at the transducer. So even small changes in transducer performance due to aging or unexpected damages can produce the changes in the characteristics of flaw signal and finally the changes in the quantitative information on flaws. Thus a reliable calibration method of transducer performance is desired. Recently, theoretical models for ultrasonic testing have been employed as reference standards for the calibration of transducers which are considered as circular planar piston sources in the most of cases. But this simplification cannot be applied to partially damaged transducer which has lost their symmetry in performance, even not in appearance. Unfortunately there has been no reliable practical model which can be used for the calibration of partially damaged transducers. Here a pulse-echo testing model for partially damaged ultrasonic transducers was developed with experimental verification. The experimental responses agree very well with the theoretical prediction. So we expect that this model can be served as a theoretical reference standards for transducer calibration.

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Chlorination of Uranium Dioxide for the preparation of Uranium Tetrachloride (사염화우라늄 제조를 위한 이산화우라늄의 염소화반응)

  • Yang, Yeong-Seok;Hwang, Seong-Chan;Ju, Geun-Sik;Lee, Hong-Gi;Gang, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.7 no.4
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    • pp.317-321
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    • 1997
  • 사염화우라늄 제조를 위해 염소가스와 탄소를 이용한 이산화우라늄의 염소화반응에 대하여 연구하였다. 이론적측면에서 열화학적 자료를 이용한 계산을 통하여 일어날 수 있는 반응들을 확인하였으며, 염소화반응이 진행되는 동안 초래될 현상에 대하여 검토하였다. 실험결과로 부터 반응온도, 반응시간 및 질소가스 주입비율이 사염화우라늄 제조에 미치는 영향을 정량적으로 평가하였다. 순수한 이산화우라늄을 사용한 사염화우라늄 제조공정에서의 적절한 반응시간과 반응온도는 각각 약 2시간과 50$0^{\circ}C$-$700^{\circ}C$범위였으며, 질소가스의 적정 주입량은 염소가스의 약 50%로 나타났다.

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Pyrolytic Reaction Pathway of Chloroethylene in Hydrogen Reaction Atmosphere (수소 반응분위기에서 Chloroethylene 열분해 반응경로 특성)

  • Won, Yang-Soo
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.510-515
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    • 2011
  • The pyrolytic reaction of 1,1-dichloroethylene($CH_2CCl_2$) has been conducted to investigate thermal decomposition of chlorocarbon and product formation pathways under hydrogen reaction environment. The reactions were studied in a isothermal tubular flow reactor at 1 atm total pressure in the temperature range $650{\sim}900^{\circ}C$ with reaction times of 0.3~2.0 sec. A constant feed molar ratio $CH_2CCl_2:H_2$ of 4:96 was maintained through the whole experiments. Complete decay(99%) of the parent reagent, $CH_2CCl_2$ was observed at temperature near $825^{\circ}C$ with 1 sec. reaction time. The important decay of $CH_2CCl_2$ under hydrogen reaction environment resulted from H atom cyclic chain reaction by abstraction and addition displacement. The highest concentration (28%) of $CH_2CHCl$ as the primary product was observed at temperature $700^{\circ}C$, where up to 46% decay of $CH_2CCl_2$ was occurred. The secondary product, $C_2H_4$ as main product was detected at temperature above $775^{\circ}C$. The one less chlorinated ethylene than parent increase with temperature rise subsequently. The HCl and dechlorinated hydrocarbons such as $C_2H_4$, $C_2H_6$, $CH_4$ and $C_2H_2$ were the main products observed at above $825^{\circ}C$. The important decay of $CH_2CCl_2$ resulted from H atom cyclic chain reaction by abstraction and addition displacement. The important pyrolytic reaction pathways to describe the features of reagent decay and intermediate product distributions, based upon thermochemical and kinetic principles, were suggested.

Quasi 1D Nonequilibrium Analysis and Validation for Hypersonic Nozzle Design of Shock Tunnel (충격파 풍동의 극초음속 노즐 설계를 위한 Quasi 1D 비평형 해석 및 검증)

  • Kim, Seihwan;Lee, Hyoung Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.8
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    • pp.652-661
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    • 2018
  • It is necessary to resolve the absolute velocity as well as Mach number to reflect the high temperature effect in high speed flow. So this region is classified as high enthalpy flows distinguished from high speed flows. Many facilities, such as arc-jet, shock tunnel, etc. has been used to obtain the high enthalpy flows at the ground level. However, it is difficult to define the exact test condition in this type of facilities, because some chemical reactions and energy transfer take place during the experiments. In the present study, a quasi 1D code considering the thermochemical non-equilibrium effect is developed to effectively estimate the test condition of a shock tunnel. Results show that the code gives reasonable solution compared with the results from the known experiments and 2D axisymmetric simulations.