• Title/Summary/Keyword: 열적 NO

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Studies on the Deactivation-resistant Ru Catalyst (Ru 촉매의 비활성화 억제를 위한 연구)

  • Kim, Young-Kil;Yie, Jae-Eui;Cho, Sung-June;Ryoo, Ryong
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.808-818
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    • 1994
  • Effects of ceria additive on the activity and thermal aging behavior of supported Ru catalysts were investigated using Ru/${\gamma}$-$Al_2O_3$and Ru/$CeO_2$-${\gamma}$-$Al_2O_3$. The catalysts were characterized by $^{129}Xe$-NMR and $H_2$ chemisorption. The cataltic activity for conversion of CO, HC and $NO_x$ was measured using simulated automobile engine exhausts under lean, rich and stoichiometric conditions. For both fresh and aged catalysts, Ru/$CeO_2$-${\gamma}$-$Al_2O_3$ was more active than Ru/${\gamma}$-$Al_2O_3$ for all three pollutants. Results of $^{129}Xe$-NMR and $H_2$ chemisorption indicated that sintering of Ru particles occurred to the same extent for both catalysts during the thermal aging process. After thermal aging at 673K, however, the catalytic activity of the aged Ru/$CeO_2$-${\gamma}$-$Al_2O_3$ was substantially higher than that of the fresh one, while the activity of Ru/${\gamma}$-$Al_2O_3$ decreased after the thermal aging. This finding may suggest new active sites were created during the thermal aging, probably in the vicinity of the interface between Ru and Ce. For more quantitative investigation of the effect of a cation such as Ce on the thermal aging of Ru metal particles, Ru catalysts supported on cation-exchanged Y-zeolites were used as the model catalysts. The results indicated that when Ba, Ca, La, Y or Ce was used for the cation exchange, the exchanged cation did not affect the thermal aging behavior of Ru in Y-zeolite, as evidenced by $^{129}Xe$-NMR and EXAFS.

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Analysis for Thermal Effect by an Unheated Housing Unit in Apartment (공동주택에서 비난방세대가 미치는 열적 영향)

  • Lee, Eun-Ju;Koo, Junemo;Hong, Hiki
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.1
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    • pp.42-47
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    • 2016
  • Adjacent housing units suffer inevitable thermal losses if an unheated unit exists in an apartment building. Thermal loss of the units adjoining the unheated apartment can be neglected because the contact area is small and insulators are located in the walls. When insulators are not included in the slab between the upper and lower units, 70% of the heat supplied by an Ondol system may be used in the original unit, but 30% is transferred to the unit on the lower floor. Another 30% can be obtained from the ceiling if the upper floor housing unit is heated. This strong thermal connection is a characteristic of Ondol heating in apartment buildings. When there is an unheated unit, the lower floor unit uses 42.3% more heating energy if there is no insulation and 19.5% if a 35 mm insulator is used as in the current guidelines. Therefore, much thicker insulation should be applied to weaken the thermal connection.

The effects of various thermal parameters on coil temperature rise in TEFC induction motor (여러가지 열적 변수가 전폐형 유도전동기의 코일온도상승에 미치는 영향에 관한 연구)

  • Yun, Myeong-Geun;Ha, Gyeong-Pyo;Go, Sang-Geun;Lee, Yang-Su;Han, Song-Yeop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.4
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    • pp.570-578
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    • 1997
  • At design stage of new motor or when taking remedial action of old motor, a lot of information can be obtained from thermal parameters analysis. This study focused on the temperature rise of TEFC induction motor with respect to various thermal parameters. Frame heat transfer had the most important effect on coil temperature rise. But those of air gap and rotor fan had no effect. This fact shows fan action is more important than fin action in the case of rotor fan. Coil temperature can be more decreased by cooling near the heat sources than any other parts from the results of thermal conductivity and loss tests. Variation of cooling air flow rate and motor volume effects on coil temperature were also tested. These tests suggest that improvement of cooling fan performance is important in reducing the coil temperature rise. Thermal equivalent program was verified by comparison of some experimental results.

Comparison of Cooling Effects by Body Part to Increase Thermal Comfort (열적 쾌적성 증대를 위한 부위별 냉각 효과 비교)

  • Soyoung Park;Yejin Lee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.48 no.3
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    • pp.501-510
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    • 2024
  • This study aimed to compare the cooling effect of specific body parts to increase workers' thermal comfort. The parts to be cooled comprised the head and neck; the coolant was a phase change material. The participants were ten men in their 20s of average size according to the 8th Size Korea. The experiment was conducted under the following conditions: 28.0 ± 0.5℃, 60.0 ± 5.0% RH, and 0.2 ± 0.1m/s. The exercise consisted of participants moving for 15 min at a constant speed of 80 BPM; later, a subjective sensation was performed, and the clothing surface temperature was measured. In doing so, heat, wetness, and discomfort after exercise were confirmed to have increased without a coolant. Significant differences over time appeared only when no coolant was used, showing that thermal comfort decreased. Despite the addition of coolant, the clothing surface temperature gradually increased over time, but it decreased with coolant rather than without it. Therefore, additional coolant areas, a lower temperature, and simultaneous cooling convection were required to improve thermal comfort.

Heat Transfer Analysis for $NO_2$ Micro Gas Sensor Fabricated by MEMS Technology (MEMS 공정으로 제작한 $NO_2$ 마이크로 가스센서의 열전달 해석)

  • 주영철;이창훈;김창교
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.5 no.2
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    • pp.132-136
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    • 2004
  • A flat type $NO_2$ micro gas sensor was fabricated by MEMS technology. In order to heat up gas sensing material such as $WO_3$ to a target temperature, a micro hotplate was built on the gas sensor. The temperature distribution of micro gas sensor was analyzed by a CFD program, FLUENT. The results showed that the temperature of silicon wafer base was almost similar to that of the room temperature, which indicates that the heat generated at the micro hotplate heated up effectively the sensing material and its thermal isolation was kept. The uniformity of temperature on the sensing material can be improved by modifying the shape of micro hotplate.

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A Study of NO Fmission Characteristics in a Non-premixed Counterflow Flame with $H_2/CO_2/Ar$ Blended-fuel (수소/이산화탄소/알곤 혼합 연료의 비예혼합 대향류 화염에서 NO 배출 특성 연구)

  • Lee, Kee-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.4
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    • pp.146-153
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    • 2007
  • The detailed chemistry with reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions, have been numerically conducted to investigate the flame structure and NO emission characteristics in a non-premixed counterflow flame of blended fuel of $H_2/CO_2/Ar$. The combination of $H_2,\;CO_2$, and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of $CO_2$. Radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. All mechanisms including thermal, $NO_2,\;N_2O$, and Fenimore are also taken into account to separately evaluate the effects of $CO_2$ addition on NO emission characteristics. The increase of added $CO_2$ quantity causes flame temperature to fall since at high strain rates diluent effect is prevailing and at low strain rates the breakdown of $CO_2$ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the ratio of the contribution by Fenimore mechanism to that by thermal mechanism in the total mole production rate becomes much larger with increase in the $CO_2$ quantity and strain rate, even though the absolute quantity of NO production is deceased. Consequently, as strain rate and $CO_2$ quantity increase, NO production by Fenimore mechanism is remarkably augmented.