• Title/Summary/Keyword: 열적변수

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Synthesis and Characterization of PPC/Organo-Clay Nanohybrid: Influence of Organically Modified Layered Silicates on Thermal and Water Absorption Properties (PPC와 Organo-Clay 나노 조성물의 합성과 실리카층의 수분흡수와 열적특성에 대한 영향)

  • Han, Hak-Soo;Khan, Sher Bahadar;Seo, Jong-Chul;Jang, Eui-Sung;Choi, Joon-Suk;Choi, Seung-Hyuk
    • Membrane Journal
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    • v.19 no.4
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    • pp.341-347
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    • 2009
  • Nanohybrid based on environmentally friendly and biodegradable polymer, poly propylene carbonate (PPC) and cloisite 20B (PPC/C-20B) have been synthesized by solution blending method and their morphology, thermal and water absorption properties have been evaluated. The structure of PPC/C-20B nanohybrid was confirmed by X-ray diffraction (XRD). The thermal property of PPC and PPC/C-20B nanohybrid were investigated by thermal gravimetric analysis (TGA) and differential scanning calorimetric (DSC). The experimental results demonstrated that nanohybrid showed the highest thermal stability in TGA and DSC. TGA tests revealed that the thermal decomposition temperature ($T_{d50%}$) of the nanohybrid increased significantly, being $23^{\circ}C$ higher than that of pure PPC while DSC measurements indicated that the introduction of 5 mass% of clay increased the glass transition temperature from 21 to $30^{\circ}C$. Further the water absorption capacity of the PPC was significantly decreased by the incorporation of clay. Water absorption cause degradation of the coating by the moistures and affect the physical and mechanical performance. This result indicates that organic modifiers have effect on thermal and water absorption capacity of PPC and are of importance for the practical process and application of PPC.

A Generalized Model for the Prediction of Thermally-Induced CANDU Fuel Element Bowing (CANDU 핵연료봉의 열적 휨 모형 및 예측)

  • Suk, H.C.;Sim, K-S.;Park, J.H.
    • Nuclear Engineering and Technology
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    • v.27 no.6
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    • pp.811-824
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    • 1995
  • The CANDU element bowing is attributed to actions of both the thermally induced bending moments and the bending moment due to hydraulic drag and mechanical loads, where the bowing is defined as the lateral deflection of an element from the axial centerline. This paper consider only the thermally-induced bending moments which are generated both within the sheath and the fuel and sheath by an asymmetric temperature distribution with respect to the axis of an element The generalized and explicit analytical formula for the thermally-induced bending is presented in con-sideration of 1) bending of an empty tube treated by neglecting the fuel/sheath mechanical interaction and 2) fuel/sheath interaction due to the pellet and sheath temperature variations, where in each case the temperature asymmetries in sheath are modelled to be caused by the combined effects of (i) non-uniform coolant temperature due to imperfect coolant mixing, (ii) variable sheath/coolant heat transfer coefficient, (iii) asymmetric heat generation due to neutron flux gradients across an element and so as to inclusively cover the uniform temperature distributions within the fuel and sheath with respect to the axial centerline. As the results of the sensitivity calculations of the element bowing with the variations of the parameters in the formula, it is found that the element bowing is greatly affected relatively with the variations or changes of element length, sheath inside diameter, average coolant temperature and its variation factor, pellet/sheath mechanical interaction factor, neutron flux depression factor, pellet thermal expansion coefficient, pellet/sheath heat transfer coefficient in comparison with those of other parameters such as sheath thickness, film heat transfer coefficient, sheath thermal expansion coefficient and sheath and pellet thermal conductivities.

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Temperature-Dependency Thermal Properties and Transient Thermal Analysis of Structural Frames Exposed to Fire (온도의존성 열특성 계수를 고려한 화재에 노출된 철근콘크리트 골조의 해석적 연구)

  • Han, Byung-Chan;Kwon, Young-Jin;Kim, Jae-Hwan;Shin, Yeong-Soo;Choi, Eun-Gyu
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.283-292
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    • 2007
  • A research projects is currently being conducted to develop a nonlinear finite element analysis methods for predicting the structural behavior of reinforced concrete frame structures, exposed to fire. As part of this, reinforced concrete frames subjected to fire loads were analyzed using the nonlinear finite-element program DIANA. Two numerical steps are incorporated in this program. The first step carries out the nonlinear transient heat flow analysis associated with fire and the second step predicts the structural behavior of reinforced concrete frames subjected to the thermal histories predicted by first step. The complex features of structural behavior in fire conditions, such as thermal expansion, plasticity, cracking or crushing, and material properties changing with temperature are considered. A concrete material model based on nonlinear fracture mechanics to take cracking into account and plasticity models for concrete in compression and reinforcement steel were used. The material and analytical models developed in this paper are verified against the experimental data on simple reinforced concrete beams. The changes in thermal parameters are discussed from the point of view of changes of structure and chemical composition due to the high temperature exposure. Although, this study considers codes standard fire for reinforced concrete frame, any other time-temperature relationship can be easily incorporated.

Development of numerical model for estimating thermal environment of underground power conduit considering characteristics of backfill materials (되메움재 특성을 고려한 전력구 열환경 변화 예측 수치해석모델 개발)

  • Kim, Gyeonghun;Park, Sangwoo;Kim, Min-Ju;Lee, Dae-Soo;Choi, Hangseok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.2
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    • pp.121-141
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    • 2017
  • The thermal analysis of an underground power conduit for electrical cables is essential to determine their current capacity with an increasing number of demands for high-voltage underground cables. The temperature rises around a buried cable, caused by excessive heat dissipation, may increase considerably the thermal resistance of the cables, leading to the danger of "thermal runaway" or damaging to insulators. It is a key design factor to develop the mechanism on thermal behavior of backfilling materials for underground power conduits. With a full-scale field test, a numerical model was developed to estimate the temperature change as well as the thermal resistance existing between an underground power conduit and backfill materials. In comparison with the field test, the numerical model for analyzing thermal behavior depending on density, moisture content and soil constituents is verified by the one-year-long field measurement.

Analysis of Structural and Thermal Parameters for Evaluating Fire Resistance of Steel Beams (철골보의 내화시간 평가를 위한 구조 및 열적 변수해석)

  • Park, Han Na;Ahn, Jae Kwon;Lee, Cheol Ho
    • Journal of Korean Society of Steel Construction
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    • v.21 no.6
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    • pp.609-618
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    • 2009
  • This paper proposes a versatile formula which can be used to evaluate the fire resistant time of steel beams under various design conditions. Towards this end, the key parameters which affect the fire performance of steel beams were first determined through thermo-mechanical considerations, and classified into two groups: structural parameters and thermal parameters. Then the degree of influence of each parameter on the fire performance was investigated through a fully coupled thermo-mechanical analysis up to the occurrence of run-away deflection. The accuracy of the numerical model used was verified using an available full-scale fire test before conducting an extensive parametric analysis. Multiple linear regression analysis was performed to obtain the formula which can be used to predict the fire resistance time of steel beams under various design conditions. The statistical analysis showed that the proposed formula is very robust. The application of the formula in practical fire design under the current code was illustrated in detail. The economy and other advantages of the proposed formula were clearly shown.

Preparation of Monodispersed Silica-Rubitherm®Microparticles Using Membrane Emulsification and Their Latent Heat Properties (막유화법을 이용한 단분산성 실리카-루비덤® 마이크로 입자의 제조 및 잠열 특성)

  • Kim, Soo-Yeon;Jung, Yeon-Seok;Lee, Sun-Ho;You, Jin-Oh;Youm, Kyung-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.215-225
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    • 2015
  • Recently, the importance of energy saving and alternative energy is significantly increasing due to energy depletion and the phase change material (PCM) research for saving energy is also actively investigating. In this research, the membrane emulsification using SPG membrane was used to make various microencapsulated phase change material (MPCM) particles which were comprised of $Rubitherms^{(R)}$ (RT-21 and RT-24) core and silica coating. We investigated the pressure of the dispersion phase, the concentration of surfactant, and the ratio of $Rubitherm^{(R)}$ and silica to prepare various MPCM particles. The DSC and TGA were used to examine the heat stability and latent heat properties. Also, PSA, SEM, and optical microscopy were used to confirm the size of $Rubitherm^{(R)}$ particles and the thickness of silica shell. The average of particle size was $7-8{\mu}m$. And, FT-IR was also used to enforce the qualitative analysis. Finally, the MPCM particles obtained from membrane emulsification showed monodispersed size distribution and the heat stability and latent heat were kept up to 80% compared to pure $Rubitherm^{(R)}$. So, it can be effectively used for wallpaper, buildings and interior products for energy saving as PCMs.

A Research on Thermal Properties & Fire Resistance of A Water Film Covered Glazing System for Large Atrium Space (대규모 아트리움에 적용되는 수박형성 유리벽의 열적 특성 및 내화성능에 관한 연구)

  • 박형주;지남용
    • Fire Science and Engineering
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    • v.13 no.4
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    • pp.38-55
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    • 1999
  • In order practically to use fire-defective glazing materials for the compartment wall where a fire-protection rating is mandated, there have been many trials internationally, This research focuses on a feasibility that, if certain water film covered all surface of glass, the glazing system can endure without breaking out under the compartment fire. First of all, a water film spray system was specially designed to wet the entire surface of the glass and also to have tiny small amount of water rebounded from the surface after emitted from nozzles. After this system has proven to have perfect performance, small-scale tests were done to find out if the water film covered glazing system react to the high temperature curve in a small furnace room. Finally, on basis of the obtained data, full-scale experiments were done so that water-film covered glazing system can pass the Korean Standard (KS) test for fire resistance, KS F2257.

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A Study on the Factors Affecting Land Prices Caused by the Development of Industrial Complex (산업단지 개발에 따른 지가형성요인에 관한 연구)

  • Kim, Young-Joon;Sung, Joo-Han;Kim, Hong-Bae
    • Journal of Cadastre & Land InformatiX
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    • v.47 no.1
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    • pp.143-160
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    • 2017
  • Since officially assessed land price system was introduced, it has functioned as the criterion for establishing and implementing real estate policies. However, there is a controversial issue about the adequacy of the officially assessed land price system. The problem is that it is difficult to establish a statistical model due to too many land characteristics. Also, local economy, macroeconomic environments and development plans are not reflected in the land price evaluation model. Considering longitudinal and cross-sectional variables, a two-way error component panel model was used in this study. This analysis model includes variables reflecting land characteristics, macroeconomic volatility, and development project. The Paju LCD Industrial Complex was selected as a analysis area and an empirical analysis was performed. According to the analysis, the number of significant land characteristic variables were 14(31%) under 5% significance level. Macroeconomic volatility has had an influence on the land price and year variable reflecting development project has consistently been significant since the industrial complex was designated. Therefore, this study suggests that the land price evaluation model should be improved by simplifying land characteristic variables and including macroeconomic and regional economic variables.

The Changing Financial Properties of KSE Listed Companies -Focusing on the Modified Jones Model- (상장기업의 재무적 특성 변화 분석 -수정 Jones 모형을 중심으로-)

  • Ko, Young-Woo
    • Journal of Digital Convergence
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    • v.19 no.5
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    • pp.241-247
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    • 2021
  • This study analyzed the changes in explanatory power of the modified Jones model(1995) for estimating the amount of accruals for Korean Stock Market listed companies from 1990 to 2019. We hypothesized that if the properties of financial variables used in the existing model change over time or change in discretionary ratios, the model's explanatory power will change. As the result of regression models, I found that the explanatory power of the modified Jones model(1995) gradually declined over time. The results may be derived from the increase in accruals itself and the changes in the distribution of variables contained in the model. The results of this research's chronological approach are expected to give important implications to both academic researchers and accounting information users.

Application of Snowmelt Parameters and the Impact Assessment in the SLURP Semi-Distributed Hydrological Model (준 분포형 수문모형 SLURP에서 융설매개변수 적용 및 영향 평가)

  • Shin, Hyung-Jin;Kim, Seong-Joon
    • Journal of Korea Water Resources Association
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    • v.40 no.8
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    • pp.617-628
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    • 2007
  • The purpose of this paper is to prepare snowmelt parameters using RS and GIS and to assess the snowmelt impact in SLURP (Semi-distributed Land Use-based Runoff Process) model for Chungju-Dam watershed $(6,661.5km^2)$. Three sets of NOAA AVHRR images (1998-1999, 2000-2001, 2001-2002) were analyzed to prepare snow-related data of the model during winter period. Snow cover areas were extracted using 1, 3 and 4 channels, and the snow depth was spatially interpolated using snowfall data of ground meteorological stations. With the snowmelt parameters, DEM (Digital Elevation Model), land cover, NDVI (Normalized Difference Vegetation Index) and weather data, the model was calibrated for 3 years (1998, 2000, 2001), and verified for 1 year (1999) using the calibrated parameters. The average Nash-Sutcliffe efficiencies for 4 years (1998-2001) discharge comparison with and without snowmelt parameters were 0.76 and 0.73 for the full period, and 0.57 and 0.19 for the period of January to May. The results showed that the spatially prepared snow-related data reduced the calibration effort and enhanced the model results.