• Title/Summary/Keyword: 열시차 분석

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Influence of Porosity on Dielectric Constant of Codierite Ceramic (코오디어라이트 세라믹의 유전상수에 미치는 기공율의 영향)

  • Ryu, Su-Chak;Park, Hui-Chan
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.182-187
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    • 1996
  • 물과 에탄올의 혼합용액에 HCI을 촉매로하여 금속알콕사이드의 가수분해로부터 코오디어라이트 분말을 제조하였다. 이때 HCI/precursor 몰비로써 촉매의 양을 조절하였다. 건조분말 중의 용매를 제거하기위해 80$0^{\circ}C$에서 3시간 하소처리하였다. 이들 하소된 분말에 대하여 시차열분석과 X-선회절분석을 행한 결과-92$0^{\circ}C$에서 $\mu$-cordierite, -103$0^{\circ}C$에서 $\alpha$-cordierite 결정상의 생성을 확인하였다. 또한, 하소분말을 가압성형한 후 130$0^{\circ}C$에서 4시간 열처리한 결과 HCI양에 따라 기공율 19.45-25.45%, 부피비중 2.06-1.70g/㎤, 유전상수 1.38-3.38 범위의 소결체를 얻었다. HCI양이 증가할수록 기공율은 증가한 반면에 비유전상수와 부피비중은 감소하였다.

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Implementation of Stereoscopic 3D Video Player System Having Less Visual Fatigue and Its Computational Complexity Analysis for Real-Time Processing (시청피로 저감형 S3D 영상 재생 시스템 구현 및 실시간 처리를 위한 알고리즘 연산량 분석)

  • Lee, Jaesung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.12
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    • pp.2865-2874
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    • 2013
  • Recently, most of movies top-ranked in the box office are screening in Stereoscopic 3D, and the world's leading electronics companies such as Samsung and LG are getting the hots for 3DTV sales. However, each person has different binocular disparity and different viewing distance, and thus he or she feels the severe visual fatigue and headaches if he or she is watching 3D content with the same binocular disparity, which is very different from things he or she feels in the real world. To solve this problem, this paper proposes and implement a 3D rendering system that correct the disparity of 3D content by reflecting binocular distance and viewing distance. Then, the computational complexity is analyzed. Optical-flow and Warping algorithms turn out to consume 732 seconds and 5.7 seconds per frame, respectively. Therefore, a dedicated chip-set for both blocks is strongly required for real-time HD 3D display.

Characteristic of Underfill with Various Epoxy Resin (에폭시 수지에 따른 언더필의 특성에 관한 연구)

  • Noh, Bo-In;Lee, Jong-Bum;Jung, Seung-Boo
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.3 s.40
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    • pp.39-45
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    • 2006
  • This study was investigated the thermal properties of underfill with various epoxy resins using thermal analysis methods such as differential scanning calorimetry (DSC), thermo gravimetry analysis (TGA), dynamic mechanical analysis (DMA) and thermo-mechanical analysis (TMA). And, the adhesion strength of the underfills/FR-4 substrate was evaluated. The glass transition temperature (Tg) of underfill which was composed the cycolaliphatic epoxy resin was lower than that of underfill which was not composed the cycolaliphatic epoxy resin. The thermal degradation of underfill was composed of two processes, which involved chemical reactions between the degrading polymer and oxygen from the air atmosphere. The coefficient of thermal expansion (CTE) of underfill which was composed the cycolaliphatic epoxy resin was higher than that of underfill which was not composed the cycolaliphatic epoxy resin. The excessive curing temperatures caused a weak boundary layer of epoxy resin, which resulted in a deterioration of mechanical properties in the epoxy resin and thus led to poor adhesion property between the underfill/FR-4 substrate.

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Time Series Modelling of Air Quality in Korea: Long Range Dependence or Changes in Mean? (한국의 미세먼지 시계열 분석: 장기종속 시계열 혹은 비정상 평균변화모형?)

  • Baek, Changryong
    • The Korean Journal of Applied Statistics
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    • v.26 no.6
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    • pp.987-998
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    • 2013
  • This paper considers the statistical characteristics on the air quality (PM10) of Korea collected hourly in 2011. PM10 in Korea exhibits very strong correlations even for higher lags, namely, long range dependence. It is power-law tailed in marginal distribution, and generalized Pareto distribution successfully captures the thicker tail than log-normal distribution. However, slowly decaying autocorrelations may confuse practitioners since a non-stationary model (such as changes in mean) can produce spurious long term correlations for finite samples. We conduct a statistical testing procedure to distinguish two models and argue that the high persistency can be explained by non-stationary changes in mean model rather than long range dependent time series models.

Studies on Reduction of Harmful Compound and Combustibility of $Na_3$ Citrate-treated Cigarette (시트르산나트륨첨가(添加)에 의(依)한 담배의 연소성(燃燒性) 및 유해물감소(有害物減少)에 관한 연구(硏究))

  • Kim, Ki-Hwan;Bae, Hyo-Won;Lee, Yong-Chong;Kim, Man-Uk;Park, Taek-Kyu
    • Applied Biological Chemistry
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    • v.20 no.1
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    • pp.117-122
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    • 1977
  • Development of new burning additives against nitrate salts used in past tobacco industry examined to reduce harmful nitrogenous compounds in smoke. Among several additives treated, the best effect by means of elevation of combustibility and reduction of tar and nicotin contents in smoke was observed by adding sodium citrate from 0.6 to 1% in tabacco. The following results were obtained through investigating combustibility, chemical composition, and differential thermal analysis of the tabacco treated with the buring additives. 1) The close relation was observed between the levels of the smoke components and combustibility of the treated tabacco. 2) Differential thermal analysis (D.T.A.) of citrate-treated tobacco shows an increase in H. Value and a decrease in L. Value as compared with other tobacco sample. 3) The D.T.A. of sodium-nitrate and sodium-citrate shows that sodium-nitrate gives endothermal reaction at $270^{\circ}$ and $310^{\circ}$ and sodium citrate gives exothermal reaction at $290^{\circ}$ with endothermal reaction at $170^{\circ}\;and\;310^{\circ}$. 4) $Na_3-citrate-treated$ tobacco shows an increase in smoke generation between room temperature and $350^{\circ}$ (Zone A) and a decrease in smoke generation between $350^{\circ}$ and $900^{\circ}$ (Zone B) compared with untreated tobacco. The smoke from these tobacco also contains lower levels of Tar, Nicotine, Phenols, Nitrogen oxides and Benzpyrene, and elevation of static Burning rate.

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Assessment of Practical Use of Recycling Oil from the Pyrolysis of Mixed Waste Plastics (혼합폐플라스틱의 열분해를 통한 회수오일의 이용가능성 평가)

  • Phae Chae-Gun;Kim Young-shin;Jo Chang-Ho
    • Journal of Energy Engineering
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    • v.14 no.2 s.42
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    • pp.159-166
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    • 2005
  • In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

Dehydration Characteristics of Cationic Surfactant-Modified Montmorillonite (양이온성 계면활성제로 표면개질된 몬모릴로나이트의 탈수 특성)

  • Seung Yeop Lee;Soo Jin Kim
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.4
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    • pp.305-314
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    • 2002
  • The dehydration of hexadecyltrimethylammonium (HDTMA)-exchanged montmorillonite has been studied using X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The dehydration in HDTMA-montmorillonite seems to influence the swelling behavior of the organo-clay during heating. The basal d(001) spacing vs temperature curve of the HDTMA-montmorillonite has one broad swelling edge with a shoulder on the low-temperature side. We believe that the shoulder at $100^{\circ}C$ for the HDTMA-montmorillonite is due to interlayer swelling induced by the initial rearrangement of surfactants, and the second edge at $200^{\circ}C$ is caused by interlayer swelling resulting from the secondary vertical reorientation of alkyl chains. It seems that the dehydration of organo-clay induces a reorientation of the alkyl chains by transition to more vertical position relative to the silicate sheets, allowing instantly greater d-spacing.

Liquid Crystalline Thermoset Films Based on Wholly Aromatic Copolymers (전방향족 공중합체의 열경화성 액정필름)

  • Moon, Hyun-Gon;Ahn, Yong-Ho;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.369-375
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    • 2010
  • We used melt polymerization method to prepare a series of aromatic liquid crystals (LCs) based on aromatic ester and amide units with the reactive methyl-maleimide end group, and then the resulting thermally cross-linked LCs to produce LC thermoset films by means of solution casting and the followed heat treatment. The synthesized LCs and LCTs were characterized by Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), thermomechanical analysis (TMA), X-ray diffractometry (XRD), and polarizing optical microscopy (POM) with a hot stage. All of the LCs prepared by melt polymerization method formed smectic mesophases. The thermal properties of the LC and LCT films were strongly affected by the mesogen units in the main chain structures. The thermal expansion coefficients of samples were in the range of 27.72~50.95 ppm/$^{\circ}C$.

The Solubility of Synthetic Schwertmannite (합성 슈워트마나이트의 용해도)

  • 박미선;유재영
    • Journal of the Mineralogical Society of Korea
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    • v.14 no.1
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    • pp.21-30
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    • 2001
  • 투석을 이용한 투석법과 투석을 이용하지 않은 평형 실험을 통해 슈워트마나이트를 합성하였다. 이 합성실험 동안 일정시간 간격을 두고 합성 용액 시료와 합성괸 침전물 시료를 채취하였으며, 이러한 시료들에 대해 X-선 회절 분석(XRD), 시차열분석(DTA), 원자흡수분광분석(AA), 유도결합 플라즈마 원자방출분광분석(ICP-AES), 이온크로마토그래피(IC)분석 등을 실시하였다. 컴퓨터 프로그램 MINTEQA2를 이용하여 분석된 합성용액의 화학조성으로부터 침전물과 공존하는 용액 내 각 화학조성으로부터 침전물과 공존하는 용액 내 각 화학종의 분포와 활동도를 계산하였다. 연구 결과 투석법을 이용하여 합성을 하면 비평형 상태를 유지하게 되므로 순수한 슈워트마나이트의 용해도를 얻고자 할 때는 투석을 이용하지 않은 합성법을 수행하여야 하는 것이 밝혀졌다. 투석을 이용하지 않은 합성 실험 결과 슈워트마나이트 침전후 72시간이 경과한 후에 평형상태에 도달함이 확인되었다. 평형상태일 때 순수하게 합성된 슈워트마나이트의 용해도 상수 pKs는 $-6.11\pm$1.16의 값을 갖는 것으로 나타났다. 순사한 슈원트마나이트의 분석된 화학조성으로 계산된 화학식은 $Fe_{8}$ /O sub 8/ (OH)$_{4.16}$ ($SO_4$)$_{1.92}$ .$6.74H_2$O, $Fe_{8}$ /O$_{8}$ (OH)$_{4.18}$ ($SO_4$)$_{ 1.91}$.$6.89H_2$O이다.

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Effect of PC(Polycarboxylate) Type Superplasticizer on the Hydration Reaction of Cement Paste (PC(Polycarboxylate)계 고유동화제가 시멘트 수화 반응에 미치는 영향)

  • Chae, Eun-Jin;Shin, Jin-Yong;Suh, Jeong-Kwon;Lee, Jung-Min;Park, Jin-Won
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.569-576
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    • 2006
  • PC-type copolymers were synthesized using MPEG(polyethylene glycol methyl ether methacrylate, Mn=2080) to different mole ratios of mono-carboxylic acid(AA : acylic acid). The mole ratios of AA were 2, 3, 4 and PC-type terpolymers were synthesized using mono-, dicarboxylic acid(ITA : itaconic acid MAL : maleic acid) with the same graft chain. To investigate effects of PC-type co-, ter-polymers on the hydration of cement experiments involving FT-IR, XRD, DSC, SEM have been analysed with cement paste specimens to 1, 3, 28 day. The hydration reaction rate of cement paste was slightly delayed at 1 day, due to increase in molar ratio of [AA]/[MPEG], it was recovered in the days after and the copolymer was more active than the terpolymer, because of low carboxylic acid content PC-type copolymers applied 2AA-type were fastest copolymer on hydration reaction of cement paste to 3 day and the more AA mole ratios increased, the more hydration was retarded.