• Polymer(Korea)
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• v.26 no.4
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• pp.501-507
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• 2002

In this work, diglycidylether of bisphenol-S (DGEBS) epoxy resin was prepared by alkaline condensation of bisphenol-S (BPS) with epichlorohydrin (ECH) in the presence of NaOH catalyst. The structure of the synthesized DGEBS epoxy resin was confirmed by IR, NMR spectra, and elemental analysis. The curing reaction and glass transition temperature ($T_g$) of DGEBS epoxy resin cured with phthalic anhydride (PA) and tetrahydrophthalic anhydride (THPA) at curing agents were studied by dynamic differential scanning calorimetry (DSC). The thermal stability of the cured specimen was investigated by thermogravimetric analysis (TGA). As a result, the activation energy ($E_a$) of DGEBS/PA system was higher than that of DGEBS/THPA system, whereas $T_g$, initial decomposed temperature (IDT), and decomposition activation energy ($E_t$) of DGEBS/PA were lower than those of DGEBS/THPA. This was probably due to the fact that the crosslinking density of DGEBS/THPA was increased by ring strain of curing agent.

• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.317-322
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• 2012

The microstructures were examined by SEM, FT-IR spectra, tensible properties mole % of [NCO/OH], and particle size analyzer. Growing concerns in the environment-friendly industries have led to the development of solvent-free formulations that can be cured. We had synthesized the polyurethane resin having the ability to protect stainless steel against corrosion. Compared with general packing materials and coatings, this resin is highly stronger in intensity and longer durability. Polyurethane resins were composed of polyols, IPDI, silicone surfactant, catalyst and crosslink agent. Moreover, thermal fillers such as $Al_2O_3$, fume silica and $ZrO_2$ not only accelerated the curing rate but also improved the physical property as thermal barriers. The rigid segments of polyurethane in mechanical properties were due to crosslink agent and the increase of [NCO/OH]. In conclusion, the polyurethane microstructure with crosslink agent can be good material for themoset coating of metal substrates such as stainless steel.

• Polymer(Korea)
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• v.28 no.1
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• pp.35-40
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• 2004

The formation mechanism of void defect which deteriorate composite's property is various according to each composite process. In this paper, void formation and growth mechanism is analyzed by thermal analysis and GC/MS. We made a vacuum chamber for observing pressure effect. Thermal analysis has been done in various condition. Elements of volatiles during resin curing were turned out by GC/MS. The most of volatiles of polyester were composed of styrene (over 80%) and a small quantity of toluene. In case epoxy resin, butyl glycidyl ether was the main element of volatiles (over 90%). We concluded that the original sites of void growth existed in resin and they were eliminated by vacuum and heating process. And the growth of void was influenced by water, diluents, solvent, and reactants in resin.

• The Korean Journal of Rheology
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• v.9 no.4
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• pp.174-182
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• 1997

결정성 고분자수지는 가공조건에 의해 결정되는 미세구조의 변화에 따라 최종물성 이 현저히 달라지므로 최종 성형품의 물성을 극대화하기 위해서는 성형가공 중에 필연적으 로 부가되는 열이력 뿐만 아니라 전단이력이 결정화 거동에 미치는 영향을 규명하고 가공조 건의 최적화를 통하여 미세구조를 적절히 제어하는 것이 요구된다. 따라서 본 연구에서 in-situ 상태로 전단유도 결정화거동을 조사할수 있는 rheo-kinetic 실험 방법을 개발하고 결정화 거동에 미치는 열이력과 전단이력의 영향을 규명하고자 하였다. 이를 위해 비교적 결정화 속도가 빠른 폴리 부틸렌 테레프탈레이트 수지를 대상으로 냉각조건, 전단부가시간, 전단속도등을 다양하게 변화시키면서 plate-plate 레오미터로 시간에 따른 전단응력의 변화 를 조사하는 rheo-kinetic 연구를 수행하였다. 아울러 실험 중에 액체 질소로 급냉하여 얻은 시료를 대상으로 등온 및 비등온의 열분석 실험을 수행하고 JMA식과 Hoffman-Lauritzentlr 을 사용하여 분석한 다음, 그 결과를 rheo-kinetic 해석결과와 비교함으로써 결정화 거동에 미치는 전단응력의 영향을 규명하였다. 일정전단속동하에서 수행한 rheo-kinetic 실험결과, 시간에 따른 저난응력의 증가와 용융열이 증가하는 경향이 매우 유사한 거동을 보이므로 전 단응력의 증가는 결정화가 일어남에 기인한 결과임을 확인할수 있었으며 고분자수지가 전단 이력을 받게 되면 분자배향의 결과로 결정화 유도시간이 짧아지고 결정화속도가 증가할 뿐 만 아니라 보다 더 높은 온도에서 결정화가 일어나게 됨을 알수 있었다. 또 결정화 반가기 시간과 Hoffman-Lauritzen 식의 매개변수들이 전단속도, 전단부가시간, 결정화 온도 등의 이력에 무관하게 전단응력에 따라 선형적으로 변하고 있으므로 전단유도 결정화거동은 수지 에 부가되는 전단응력에 직접적인 영향을 받음을 알수 있었다. 이상과같은 전단유도 결정화 거동에 관한 결과를 가공공정상의 열전달 현상과 결합하여 해서하면 성형품 내부의모폴로지 의 예측이 가능하므로 성형품 물성의 극대화 방안의 수립에 이용될수 있을것으로 사료된다.

• Composites Research
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• v.30 no.3
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• pp.215-222
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• 2017

The effect of a multi walled carbon nanotubes (MWNCT) on the adhesive properties and thermal properties of epoxy were studied by double lap-shear tests. Epoxy/MWCNT resins were prepared from a different amount of the MWCNT incorporated into the epoxy resins (araldite 2011). Steel plates and carbon fiber reinforced plastics (CFRP) were chosen as materials. Mechanical tests were performed by a universal testing machine (UTM). The analysis of thermal properties were conducted by a thermogravimetric analyzer (TGA) and a differential scanning calorimetry (DSC). The fracture surface morphology was examined using a scanning electron microscopy (SEM) and optical microscope. Compared to neat epoxy, it was found that the mechanical properties of epoxy/MWCNT resins are increased.

• Composites Research
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• v.35 no.4
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• pp.288-297
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• 2022

This study investigated the effect of addition of zirconia(zirconium oxide) powder on the curing behavior of phenolic resins. The heating rate controlled curing and isothermal curing behaviors of the phenol resin according to the content of the zirconia powder were analyzed. The viscosity and thermal decomposition characteristics of the phenolic resin with the zirconia content were also examind. From the DSC analysis, the degree of cure and the rate of cure were obtained. Finally, the activation energy for the cure reaction were calculated from the DSC data of the zirconia added phenolic resin. As a found, the higher the zirconia content, the longer the curing was delayed and the greater the activation energy required for curing. Additionally, the TGA result that as the content of zirconia increased, less weight loss was observed. The surface tackiness of the Carbon/Phenol prepreg was partially changed according to the zirconia content, but had no significant effect.

• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2003.10a
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• pp.176-179
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• 2003

범용 엔지니어링 플라스틱(Engineering plastic)인 PET(Polyethylene terephthalate)수지는 투명성, 강도특성, 내열특성, 기체차단성 등 물성이 우수하여 합성섬유, 이축연신 film, 식음료용 bottle 등의 용도로 널리 사용되는 적용범위가 매우 넓은 고분자 소재이다. 그러나 폐기된 PET 수지를 물질재활용(material recycling) 방법으로 재가공할 경우 수지 자체가 갖는 가수분해(hydrolysis)와 열분해(thermal degradation) 특성으로 인해 가공성 및 기계적 특성이 현저히 저하되는 단점이 있다.(중략)

• Rubber Technology
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• v.8 no.2
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• pp.136-153
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• 2007

• Journal of Conservation Science
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• v.33 no.5
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• pp.345-354
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• 2017

A mural was discovered in the Ssanggyesa temple located in Jindo island, during repair of the Daeungjeon Hall. A study was conducted to determine the binding medium used for preparing the mural. Pyrolysis/GC/MS and IR spectrometry were used to analyze a painting specimen. Direct approach and on-line methylation approach were attempted for the pyrolysis/GC/MS. In IR analysis, the spectra of the specimen were found to be different from those of Asian lacquer, yellow lacquer, animal glue, and acrylic emulsion resin. They were also not identical to the standard IR spectra of drying oils such as linseed oil. Pyrolysis/GC/MS results of the specimen were different from those of Asian lacquer, yellow lacquer, animal glue, and acrylic emulsion resin. In the mean time, palmitic acid, octadecanoic acid, nonanedioic acid, and octadecenoic acid, which are characteristic pyrolysis products of dried drying oil, were detected. In addition, the pyrolysis/GC/MS chromatograms of the specimen and dried drying oil were also very similar. Therefore, it was concluded that the painting was prepared using drying oil as a binding medium.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.1585-1590
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• 2010

토양으로부터 발생하는 증발과 식물에서 일어나는 증산을 모두 포함하는 증발산은 일반적으로 연구된 물리식과 경험식 등을 이용하여 산정하고 lysimeter 실측 자료를 이용하여 지역 특성에 맞게 검증하는 방법을쓰고 있다. 하지만 이와 같은 방법은 어느 한 점에만 국한되어 적용되기 때문에 공간적인 제약이 있으며 외부환경의 영향을 크게 받는 증발산의 특성상 이를 일반화하는 데에도 어려움이 따른다. 따라서 이러한 점들을 보완하고 해결하기 위해 원격탐사 (Remote Sensing)를 이용하여 넓은 지역에 분포되어 있는 증발산량을 공간적으로 산정하고자 한다. 증발산량은 크게 물수지, 에너지수지 방법을 이용하여 구할 수 있으며, 본 연구에서는 에너지수지 방법을 기반으로 한 원격 이미지 처리 모형을 이용하여 에너지 수지식의 각 항을 이루는 순복사 에너지, 토양열 플럭스, 현열 플럭스와 함께 증발산을 나타내는 잠열 플럭스를 통합적으로 처리하여 산정, 이를 지도로 나타내고 기본적인 통계분석을 실시하였다. 작성된 지도는 유역 내 토지 피복, 식생 분포, 고도 등 외부 인자들의 변화에 따라 증발산량이 공간적으로 어떻게 변화하는지를 알아볼 때 유용하게 쓰일 것이며, 다른 증발산 지도와의 비교를 통해 연구지역에서의 시간 변동성을 파악하는 데에도 도움이 될 것이다.