• Title/Summary/Keyword: 열분석적 특성

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Kinetic Analysis for the Pyrolysis of Solid Refues Fuel Using Livestock Manure (축분 고형연료의 열분해 동역학 연구)

  • Jang, Eun-Suk;Song, Eunhye;Yoon, Jonghyuk;Kim, Young-Min
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.443-451
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    • 2020
  • In this study, the physico-chemical properties and pyrolysis kinetics of livestock mature solid fuel were investigated to know its feasibility as a fuel. Ultimate and proximate analysis results showed that livestock mature solid fuel has high contents of volatile matter (64.94%), carbon (44.35%), and hydrogen (5.54%). The low heating value of livestock mature solid fuel (3880 kcal/kg) was also higher than the standard requirement of solid fuel (3000 kcal/kg). Thermogravimetic analysis results indicated that livestock mature solid fuel has three decomposition temperature regions. The first temperature zone (130~330 ℃) was consisted with the vaporization of extracts and the decomposition of hemicellulose and cellulose. The second (330~480 ℃) and third (550~800 ℃) temperature regions were derived from the decomposition of lignin and additional decomposition of carbonaceous materials, respectively. The activation energy derived from model free kinetic analysis results including Friedman, Flynn-Wall-Ozawa (FWO), and Kissinger-Akahira-Sunose (KAS) methods for the pyrolysis of livestock mature solid fuel was in the range of 173.98 to 525.79 kJ/mol with a conversion rate of 0.1 to 0.9. In particular, the activation energy increased largely at the higher conversion than 0.6. The kinetic analysis using a curve-fitting method suggested that livestock mature solid fuel was decomposed via a multi-step reaction which can be divided into five decomposition steps.

Thermal Behavior and Leaf Temperature in a High Pressure Sodium Lamp Supplemented Greenhouse (고압나트륨등 보광 온실의 열적 거동 및 엽온 분석)

  • Seungri Yoon;Jin Hyun Kim;Minju Shin;Dongpil Kim;Ji Wong Bang;Ho Jeong Jeong;Tae In Ahn
    • Journal of Bio-Environment Control
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    • v.32 no.1
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    • pp.48-56
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    • 2023
  • High-pressure sodium (HPS) lamps have been widely used as a useful supplemental light source to emit sufficient photosynthetically active radiation and provide a radiant heat, which contribute the heat requirement in greenhouses. The objective of this study to analyze the thermal characteristics of HPS lamp and thermal behavior in supplemented greenhouse, and evaluate the performance of a horizontal leaf temperature of sweet pepper plants using computational fluid dynamics (CFD) simulation. We simulated horizontal leaf temperature on upper canopy according to three growth stage scenarios, which represented 1.0, 1.6, and 2.2 plant height, respectively. We also measured vertical leaf and air temperature accompanied by heat generation of HPS lamps. There was large leaf to air temperature differential due to non-uniformity in temperature. In our numerical calculation, thermal energy of HPS lamps contributed of 50.1% the total heat requirement on Dec. 2022. The CFD model was validated by comparing measured and simulated data at the same operating condition. Mean absolute error and root mean square error were below 0.5, which means the CFD simulation values were highly accurate. Our result about vertical leaf and air temperature can be used in decision making for efficient thermal energy management and crop growth.

Thermal and Mechanical Properties of Epoxy Composites Using Silica Powder (실리카 파우더를 이용한 에폭시 복합소재의 열적/기계적 특성)

  • Lee, Hye Ryeon;Song, JeeHye;Kim, Daeyeon;Lim, Choong-Sun;Seo, BongKuk
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.7-14
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    • 2016
  • Epoxy composites with concentrations of 5-70 wt% of silica particles were prepared in order to improve mechanical property and poor thermal stability. The mechanical and thermal properties were investigated and compared to the corresponding properties of neat epoxy composite. Furthermore, the effects of silane compound treatment on silica particles were observed by the experimental results of the tensile strength, glass transition temperature, and thermal stability of epoxy composite. Tensile strength of epoxy composites was measured by universal testing machine (UTM) and after that, the structure and morphology analysis of epoxy nanocomposites were analyzed by field emission scanning electron microscope (FE-SEM) and energy dispersive spectroscopy (EDS). The increased solid content of CA0030 particle improved the tensile strength of epoxy/ modified composites to give 30-50 MPa. The thermal expansion coefficients (CTE) of neat epoxy resin and epoxy/silica composites measured with a thermomechanical analyzer (TMA) showed that the incorporation of silica particles was helpful to reduce the CTE of neat epoxy resin.

Solvothermal Synthesis and Characterization of Cu3(BTC)2 Tubular Membranes Using Surface Modified Supports (표면 개질된 지지체를 이용한 Cu3(BTC)2 튜브형 분리막의 용매열 합성 및 특성분석)

  • Noh, Seung-Jun;Kim, Jinsoo
    • Korean Chemical Engineering Research
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    • v.52 no.2
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    • pp.214-218
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    • 2014
  • In this study, nanoporous $Cu_3(BTC)_2$ membranes were synthesized on macroporous alumina tube supports by solvothermal method. It is very difficult to prepare uniform and crack-free $Cu_3(BTC)_2$ layer on macroporous alumina support by in situ solvothermal method. In this study, continuous and crack-free $Cu_3(BTC)_2$ tubular membranes could be obtained by in situ solvothermal process after surface modification of alumina support. The surface modification was conducted by spraying Cu precursor solution on the alumina support heated at $200^{\circ}C$. The prepared $Cu_3(BTC)_2$ tubular membranes were characterized by XRD, FE-SEM and gas permeation experiments. $H_2$ permeance through $5{\mu}m$ thick $Cu_3(BTC)_2$ tubular membrane was calculated to be $7.8{\times}10^{-7}mol/s{\cdot}m^2{\cdot}Pa$ by single gas permeation test, with the ideal selectivities of $H_2/N_2=11.94$, and $H_2/CO_2=12.82$.

Precision Improvement of GPS Height Time Series by Correcting for Atmospheric Pressure Loading Displacements (대기압하중에 의한 지각변위 보정을 통한 GPS 수직좌표 시계열 정밀도 향상)

  • Kim, Kyeong-Hui;Park, Kwan-Dong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.27 no.5
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    • pp.599-605
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    • 2009
  • Changes of atmospheric pressures cause short- and long-term crustal deformations and thus become error sources in the site positions estimated from space geodesy equipments. In this study, we computed daily displacements due to the atmospheric pressure loading (ATML) at the 14 permanent GPS sites operated by National Geographic Information Institute. And the 10-year GPS data collected at those stations were processed to create a continuous time series of the height estimate. Then, we corrected for the ATML from the GPS height time series to see if the correction changes the site velocity and improves the precision of the time series. While the precision improved by about 4% on average, the velocity change was not significant at all. We also investigated the overall characteristics of the ATML in the southern Korean peninsula by computing the ATML effects at the inland grid points with a $0.5^{\circ}{\times}0.5^{\circ}$ spatial resolution. We found that ATML displacements show annual signals and those signals can be fitted with sinusoidal functions. The amplitudes were in the range of 3-4 mm, and they were higher at higher latitudes and lower at the costal area.

A New Bootstrap Simulation Method for Intermittent Demand Forecasting (간헐적 수요예측을 위한 부트스트랩 시뮬레이션 방법론 개발)

  • Park, Jinsoo;Kim, Yun Bae;Lee, Ha Neul;Jung, Gisun
    • Journal of the Korea Society for Simulation
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    • v.23 no.3
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    • pp.19-25
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    • 2014
  • Demand forecasting is the basis of management activities including marketing strategy. Especially, the demand of a part is remarkably important in supply chain management (SCM). In the fields of various industries, the part demand usually has the intermittent characteristic. The intermittent characteristic implies a phenomenon that there frequently occurs zero demands. In the intermittent demands, non-zero demands have large variance and their appearances also have stochastic nature. Accordingly, in the intermittent demand forecasting, it is inappropriate to apply the traditional time series models and/or cause-effect methods such as linear regression; they cannot describe the behaviors of intermittent demand. Markov bootstrap method was developed to forecast the intermittent demand. It assumes that first-order autocorrelation and independence of lead time demands. To release the assumption of independent lead time demands, this paper proposes a modified bootstrap method. The method produces the pseudo data having the characteristics of historical data approximately. A numerical example for real data will be provided as a case study.

Analysis on the Supply Chain of Port & Logistics, Industry from the Viewpoint of its Relationship (관계 유형 관점에서의 항만물류 공급망 분석)

  • Choi Hyung-Rim;Park Nam-Kyu;Kwon Hae-Kyoung;Yoo Dong-Yeol
    • Journal of Korea Society of Industrial Information Systems
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    • v.10 no.3
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    • pp.38-47
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    • 2005
  • To efficiently manage the supply chain of an industry, the structure and characteristics of a supply chain have to be predefined and it is strongly required to get a framework to analyze a supply chain. We have developed a framework to analyze a supply chain from the viewpoint of chain relationship. It is possible to evaluate the degree of supply chain of each entity by using the framework. We have applied the framework to the port & logistics industry. From this research, we have identified tile current status of supply chain of port & logistics industry in the Korea and extracted some considerations for the healthy supply chain of Korean port & logistics industry.

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Analysis of the Hydrologic Cycle in Pangyo Watershed Using Distributed Hydrologic Model (분포형 수문모형을 이용한 판교유역 물순환 해석)

  • Jang, Cheol-Hee;Kim, Hyeon-Jun;Noh, Seong-Jin;Kim, Chul-Gyum
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.1315-1319
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    • 2008
  • 본 연구에서는 WEP 모형을 통해 판교신도시 개발 전의 물순환을 해석하였다. 정밀한 해석을 위해 대상유역을 30m 크기의 정방형 격자로 구분하고 기상 조건, 지표면 조건, 하천, 토양, 지하대수층, 농업용수 이용 등 물순환에 관련된 광범위한 입력자료를 기존 측정 자료 및 관련 문헌, 현장 조사를 통해 각각 구축하였다. 물순환 해석 결과는 개발 전 모의에 대해 하천유출, 유황곡선 및 물수지, 수문요소 공간분포 분석을 통해 수행하였다. 모의 결과의 전 후처리는 WEP+(Water and Energy transfer Process model Plus)를 통해 수행되었으며, WEP+는 WEP 모형의 방대한 양의 입력자료를 효과적으로 구축하고, 다양한 시계열 및 공간분포 출력자료를 효과적으로 분석할 수 있는 인터페이스를 지닌 전 후처리 프로그램이다(한국건설기술연구원, 2007). 향후 판교신도시 개발후의 물순환 특성 변화를 평가하여 개발전후의 수문요소의 변화를 정량적으로 비교분석 함으로써 효율적인 저감 대책의 수립에 활용할 계획이다. 즉 도시개발로 인해 변화되는 지형, 토지이용, 토양, 지하대수층, 용수이용 등의 각 요소들을 모형에 적용하여 각 매개변수들이 수문순환 요소에 미치는 영향을 분석할 계획이다.

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Design of 3MW class outer rotor type PMSG for wind turbine (풍력 발전용 3MW급 외전형 영구자석 동기발전기 설계)

  • Kim, Taehun;Kim, Geohwa;Kim, Dongeun;Chung, Chinhwa;Park, H.C.
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.179.1-179.1
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    • 2010
  • 포항공과대학교 풍력특성화대학원에서는 3MW급 외전형 영구자석 동기발전기 설계를 진행하고 있다. 여기서 외전형이란 RFPM 발전기에서 회전자가 바깥에서 회전하는 형태로 기존의 RFPM 발전기와 비교하여 같은 공극직경에 더 많은 자석을 채택할 수 있고, 회전자와 터빈 블레이드를 직접 연결이 가능하다. 또한, 회전자를 외부에 노출 시킬 수 있으므로 냉각에 유리한 면이 있다. 설계 변수 중 출력과 회전수를 고정시키고 각 극수와 공극 직경, 전압을 변화함에 따른 전기적 특성을 비교하고, 그 중 최적의 모델을 선택한다. 선택된 모델의 전자기장 해석, 손실 계산, 열분석을 수행한다. 본 논문에서는 각 경우에 따른 결과를 비교하고 최적 모델에 대한 해석 결과에 대해 요약한다.

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한국 남해 대륙붕 후 제4기 퇴적층의 순차 층서 모델

  • 유동근;이호영;남승일
    • Proceedings of the Korean Quaternary Association Conference
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    • 2004.06a
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    • pp.7-7
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    • 2004
  • 한국 남동해역 대륙붕에서 취득된 고해상 탄성파 탐사자료와 퇴적물 시료의 분석에 의하면 후 제4기 퇴적층은 마지막 빙하기 이후의 해수면 변화에 의해 조절되는 저해수면계열, 해침계열, 고해수면계열로 구성된다. 시퀀스 경계면 위의 저해수면계열(층서단위 I)은 마지막 빙하기 동안 퇴적된 니질사 혹은 사질니 퇴적물로 구성되며 대륙붕단과 해곡의 외해역에 분포한다. 해침면과 최대 해침면 사이에 위치하는 해침계열(층서단위 II)은 지난 15,000-6,000년 사이에 퇴적되었으며 주로 사질퇴적물로 구성된다. 해침계열은 연구해역 전반에 걸쳐 넓게 분포하지만 저해수면계열과 고해수면계열에 비해 박층으로 분포한다. 이러한 해침계열은 분포특성에 따라 3개의 소퇴적단위로 세분된다. 즉, 대륙붕단의 초기해침계열(Unit IIa), 중간대륙붕의 중기해침계열(Unit IIb), 내대륙붕의 후기해침계열(Unit IIc)등으로 이들은 후배열층서의 특성을 가진다. 최대해침면 상부에 놓이는 고해수면계열(층서단위 III)은 해수면이 현 수준에 도달한 지난 약 6,000년 이후에 퇴적된 현생 니질 퇴적물로 구성되며 내대륙붕의 연안을 따라 제한적으로 분포한다.

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