• Title/Summary/Keyword: 열분석적 특성

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Synthesis of Tungsten Doped Vanadium Dioxide and Its Thermochromic Property Studies (텅스텐이 도핑된 바나듐 산화물의 합성 및 열전이 특성 연구)

  • Hwang, Kyung-Jun;Jo, Cho Won;Yoo, Jung Whan
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.44-48
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    • 2013
  • In this work, we have prepared tungsten doped vanadium oxide ($W-VO_2$) particles with a low phase transition temperature. $W-VO_2$ particles were synthesized via thermolysis method using vanadyl (IV) sulfate and ammonium bicarbonate as precursors. The structure and thermochromic property of synthesized $W-VO_2$ particles were investigated by FE-SEM, EDS, XRD, XPS, and DSC analysis. The prepared $W-VO_2$ showed a nearly platy morphology, which indicates that the tungsten was successfully doped in the crystal lattices of $VO_2$. $W-VO_2$ nanoparticles with the size of 60 nm exhibited a monoclinic crystal structure and its chemical composition and surface state were also likely to be close to that of $VO_2$. In addition, the phase transition temperature of $W-VO_2$ was $38.5^{\circ}C$, which was approximately $29.2^{\circ}C$ lower than that of pure $VO_2$ ($67.7^{\circ}C$), indicating that the prepared sample had a good reversible thermochromic stability.

THE CHARACTERISTICS OF RESIN INFILTRATED INCIPIENT CARIOUS LESIONS (Resin infiltration을 시행한 법랑질 초기 우식 병소의 특성)

  • Kim, Eun-Young;Kwon, Min-Seok;Kim, Shin;Jeong, Tae-Sung
    • Journal of the korean academy of Pediatric Dentistry
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    • v.39 no.1
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    • pp.1-10
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    • 2012
  • The concept of resin infiltration which was born in an innovative philosophy to arrest the incipient caries. However, the structural changes of resin infiltrated lesions have not yet explained completely. The liquid resin might contribute not only to maximizing the penetration but to deteriorating physical stability. This study was performed to examine some physical and histological features of resin infiltrated incipient carious lesions. With the specimen of resin infiltrated lesions, microhardness by nanoindentation in depth profile, morphology of resin tags were revealed after HCl dissolution, and degree of microleakage were assessed. The percentage of microhardness of surface layer and lesion body of untreated specimen to sound enamel was 64.6% and 24.6% respectively, while that of resin-infiltrated lesions was 72.1%, showing significant difference (p<0.05). The resin tags observed under SEM had relatively homogeneous length of 433(282~501) ${\mu}m$ on the average. Among 20 specimens for microleakage assessment, 13 specimens showed no leakage while 5 and 2 showed leakage into outer and inner half of lesion respectively. It was thought the infiltrant resin penetrates deeply and homogeneously into lesion body and improves its hardness with relatively good physical stability.

Power of SNS Authenticity on Company Reputation (기업명성과 SNS 진정성의 영향력 연구)

  • Jo, Jung-Yul
    • Journal of Digital Convergence
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    • v.13 no.2
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    • pp.73-81
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    • 2015
  • SNS is in the process of fast evolution as well. This study is about influence of authenticity and interactivity among Facebook Fan Page users. Authenticity is something people form in the process of expressing and sharing information thru SNS Facebook Fan Page. Interactivity is a level of participation of users in the process of expressing and sharing information thru SNS Facebook Fan Page. The focus of this paper is to see the power of authenticity and interactivity of SNS Facebook Fan Page users in a time of crisis. Authenticity is proven as a valuable asset for corporations for it showed a sturdy characteristic even when something terrible happened. When a crisis attacked, high authenticity user group was not willing to change their evaluation on a company reputation and image as much as low authenticity user group. Interestingly enough, the meaning interactivity level was strikingly different from what we expected. The more their level of interactivity, was the more they were likely to change their evaluation on a company in a time of crisis. A serious discussion is necessary for this contraty results.

Characterization and Application for Hydrogel Lens Material of Acrylate Monomers Containing Hydroxyl Group (하이드록시기를 포함한 아크릴레이트계 모노머들의 하이드로젤 친수성 렌즈 소재로의 응용 및 특성)

  • Lee, Min-Jae;Kim, Tae-Hun;Sung, A-Young
    • Journal of the Korean Chemical Society
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    • v.60 no.3
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    • pp.181-186
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    • 2016
  • The hydrophilic ophthalmic lens with addition of 2-hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (HEMA), hydroxypropyl methacrylate (HPMA) and Ag nanoparticles were manufactured. And also, the cross-linker ethylene glycol dimethacrylate (EGDMA) and the initiator azobisisobutyronitrile (AIBN) were used for polymerization. The polymerization of the hydrogel lens material was conducted through thermal polymerization in 100 ℃ for 1h. The optical and physical characteristics of hydrogel lens were evaluated by measuring water content, refractive index and optical transmittance. The water content of sample containing HEA, HEMA and HPMA was in the average of 82.12%, 37.06% and 21.57%, respectively. And also, refractive index of the sample containing HEA, HEMA and HPMA was in the average of 1.3540, 1.4330 and 1.4649, respectively. In case of the optical properties of the sample, the results showed that the near-UV transmittance was 82.67%, 80.32% and 79.83%, and the visible transmittance was 89.72%, 88.24% and 86.89%, respectively. And also, optical transmittance of the sample containing Ag nanoparticles showed that the near-UV transmittance of 10.59% and visible transmittance of 43.74% were obtained. From the results, the molecular length influenced on the water content and refractive index of the polymerized material.

A Study on the Mechanical Properties of Gas Pressure Welded Splices of Deformed Reinforcing Bar (가스압접 이형철근의 기계적 강도 특성 연구)

  • Jeon, Juntai
    • Journal of the Society of Disaster Information
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    • v.11 no.4
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    • pp.520-526
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    • 2015
  • Reinforcing bar splices are inevitable in reinforced concrete structure. In these days, there are three main types of splices used in reinforced concrete construction site - lapped splice, mechanical splice and welded splice. Low cost, practicality in construction site, less time consuming and high performance make gas pressure welding become a favorable splice method. However, reinforcing bar splice experiences thermal loading history during the welding procedure. This may lead to the presence of residual stress in the vicinity of the splice which affects the fatigue life of the reinforcing bar. Therefore, residual stress analysis and tensile test of the gas pressure welded splice are carried out in order to verify the load bearing capacity of the gas pressure welded splice. The reinforcing bar used in this work is SD400, which is manufactured in accordance with KS D 3504. The results show that the residual stresses in welded splice is relatively small, thus not affecting the performance of the reinforcing bar. Moreover, the strength of the gas pressure welded splice is high enough for the development of yielding in the bar. As such, the reinforcing bar with gas pressure welded splice has enough capacity to behave as continuous bar.

A Study on the Estimate and Characteristics of Recreational Use in Mt. Kyeryong National park (계룡산(鷄龍山) 국립공원(國立公園)의 레크리에이션 이용특성(利用特性) 및 이용객(利用客) 예측(豫測)에 관(關한) 연구(硏究))

  • Seong, In Kyeong;Cho, Eung Hyouk
    • Journal of Korean Society of Forest Science
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    • v.77 no.3
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    • pp.322-330
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    • 1988
  • This study was analyzed the behavior of recreational use through interviewing visitors with the questionnaire (1986.11-1987.9) in Mt. Kyeryong National Park. The number of visitors have been forecasted by tune series data of the past number of visitors, population, GNP, and number of cars (1974-1986) in korea. The results of the study can be summarized as follows : 1) Visitor's subjective evaluation about recreational environment evaluated to be fair in Mt. Kyeryong National Park. 2) They preferred natural forest resources to historic remains, tourist facility, etc.. 3) Number of participation was mostly once or five times over. 4) Visitors were affirmative to re-visit to the Mt. Kyeryong National Park. 5) Most of visitors stay for one day. 6) The most suitable estimated user regression model was : Y=-5753.7350+0.1726 Pop. -0.6564 NO. of Car. According to this equation, the total number of visitors will he increased by 3% per year from 1,023 thousands people in 1987 to 1,698 thousands in 2000.

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Studies on the New Analytical Methods for Separation and Recovery of Rare Earth Metals (I) : Adsorption Characteristics of U(VI) Ion by New Synthetic Resins with Macrocyclic Compounds (희토류금속 분리 및 회수를 위한 분석화학적 연구 (제1보) : 우라늄(VI)의 분리회수를 위한 선택이온교환수지 합성과 우라늄(VI) 금속이온의 흡착특성)

  • Jung Oh Jin;Hak Jin Jung;Joon Tea Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.358-370
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    • 1988
  • Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, 4%, and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium, rare earths and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat at $280^{\circ}C$. The $UO_2^{+2}$ aqueous solution are not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+},\;Cu^{2+}\;and\;Nd^{3+}$.

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An Experimental Study on Hydration and Strength Development of High Blain Cement at Low Temperature (저온환경에서 고분말도 시멘트의 수화반응 및 강도발현 특성에 관한 실험적 연구)

  • Mun, Young-Bum;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Kim, Jae-Young;Lee, Han-Seung;Kim, Mok-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.367-373
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    • 2015
  • In this study, fundamental properties of cement were reviewed to apply high fineness cement at low temperature environment. The classified high fineness cement has large proportion of particles below $10{\mu}m$ which affects early hydration: an overall reaction of cement hydration faster. As a result of using high fineness cement, setting time of concrete was reduced and compressive strength was higher than OPC at all ages. Especially, compressive strength was more than double its value compared with OPC after three days curing in low temperature. Faster reaction and higher heat of hydration was verified by calorimetry early and maximum heat of hydration was analyzed by adiabatic temperature raising test. The analysis of this study confirmed that high fineness cement can be suitable to be used in low temperature environment.

Sequence Stratigraphy of Late Quaternary Deposits in the Southeastern Continental Shelf, Korea (한국 남동 대륙붕 후 제4기 퇴적층의 시퀀스 층서)

  • 유동근;이치원;최진용;박수철;최진혁
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.4
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    • pp.369-379
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    • 2003
  • Analysis of high-resolution seismic profiles and sediment data from the southeastern continental shelf of Korea reveals that the late Quaternary deposits consist of a set of lowstand (LST), transgressive (TST), and highstand systems tracts (HST) that corresponds to the sea-level change after the Last Glacial Maximum. LST (Unit I) above the sequence boundary consists of sandy mud or muddy sand deposited during the last glacial period and is confined to the shelf margin and trough region. TST (Unit II) between transgressive surface and maximum flooding surface consists of sandy sediments deposited during the postglacial transgression (15,000-6,000 yr BP). Although TST is widely distributed on the shelf, it is much thinner than LST and HST. On the basis of distribution pattern, TST can be divided into three sub-units: early TST (Unit IIa) on the shelf margin, middle TST (Unit IIb) on the mid-shelf, and late TST (Unit IIc) on the inner shelf, respectively. These are characterized by a backstepping depositional arrangement. HST(Unit III) above the maximum flooding surface is composed of the fine-grained sediments deposited during the last 6000 yrs when sea level was close to the present level and its distribution is restricted to the inner shelf along the coast.

An Experimental Study on the Thermal Property of Concrete under the Load Ratio Condition in Fire (화재시 하중재하에 따른 콘크리트의 열적특성에 관한 실험적 연구)

  • Kim, Hyung-Jun;Kim, Heung-Youl;Park, Kyung-Hun;Jung, Jae-Young;Kwan, Ki-Hyuk
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.66-74
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    • 2009
  • When a fire occurs, the concrete structure's strength decreases by the increasing temperature under the fire in certain condition of constant load. And, the ratio of the axial force is changed by such decreased strength so that the structure is deformed. In this research, considering such case, we have conducted an actual fire test for the concrete lining with constant loading condition and various fire conditions. The specimen adopts the shape condition for small practical specimen defined by the EFNARC and we used 24MPa, 40MPa and 50MPa to analyze the thermal properties by the strength. The ratio of loading is imposed by a certain loading condition based on 20% and 40% of the sectional stress in concrete and MHC Fire is selected to realize the thermal impact of the concrete by rapid increasing temperature. As the result of the experiment, in the same ratio of loading, the 50MPa specimen shows more cracks and spalling as time goes on. The area damaged by the fire, according to the functional criteria of the concrete lining under the fire in ITA, does not satisfy with the standard in lack of 50mm depth from the heating surface at total 200mm lining.