• Title/Summary/Keyword: 열분석적 특성

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Design and Construction of a Bottoming Organic Rankine Cycle System for an Natural Gas Engine (가스엔진용 유기랭킨사이클의 설계 및 제작)

  • Lee, Minseog;Baek, Seungdong;Sung, Taehong;Kim, Hyun Dong;Chae, Jung Min;Cho, Young Ah;Kim, Hyoungtae;Kim, Kyung Chun
    • Journal of the Korean Institute of Gas
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    • v.20 no.6
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    • pp.65-72
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    • 2016
  • ORC system was designed and constructed for utilizing the heat of the exhaust gas and coolant released from the gas engine which was modified to use natural gas as a fuel. In this paper the components of the ORC system were designed and manufactured based on measured data of the gas engine. The components are composed of two plate heat exchanger, the 5kW-class expander and multi stage centrifugal pump. The thermodynamic performance of the ORC system was analyzed by using the electric heater. Also, the developed ORC system was implemented to modified natural gas engine. Two gas engines were used to supply heat to the ORC system. As a result of test bench, when the heat source temperature is $110^{\circ}C$ expander shaft power, the pressure ratio and cycle efficiency is 5.22kW, 7.41, 9.09%. As a result of field test, when the heat source temperature is $86^{\circ}C$ expander shaft power, the pressure ratio and cycle efficiency is 2kW, 3.75, 6.45%.

Cure and Mechanical Behaviors of Cycloaliphatic/DGEBA Epoxy Blend System using Electron-Beam Technique (전자선 조사에 의한 고리지방족/DGEBA 에폭시 블렌드 시스템의 경화 및 기계적 특성)

  • 이재락;허건영;박수진
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.210-216
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    • 2003
  • 4-Vinyl-1-cyclohexene diepoxide (VCE)/diglycidyl ether of bisphenol-A (DGEBA) epoxy blends with benzylquinoxalinium hexafluoroanti-monate were cured using an electron-beam technique. The effect of DGEBA content to VCE on cure behavior, thermal stabilities, and mechanical properties was investigated. The composition of VCE/DGEBA blend system vaned within 100:0, 80:20, 60:40, 40:60, 20:80, and 0:100 wt%. The cure behavior and thermal stability of the cured specimens was monited by near-infrared spectroscopy and thermogravimetric analysis, respectively. Also, the critical stress intensity factor ($_{4}$) test of the cured specimens was performed to study the mechanical interfacial properties. As a result, the decreases of short side-chain structure and chain scission were observed in NIR measurements as the DGEBA content increases, resulting in varying the hydroxyl and carbonyl groups. And, the initial decomposition temperature (IDT), temperature of maximum weight loss (T$\_$max/), and decomposition activation energy (E$\_$d/) as thermal stability factors were increased with increasing the DGEBA content. These results could be explained by mean of decreasing viscosity, stable aromatic ring structure, and grafted interpenetrating polymer network with increasing of DGEBA content. Also, the maximum $_{4}$ value showed at mixing ratio of 40:60 wt% in this blend system. in this blend system.

Evidence for Hydrothermal Plume in Manus Basin, SW Pacific: Distribution of Transparency and Hydrogen Sulfide (남서태평양 마누스분지 해역의 열수 plume 증거: 투명도 및 황화수소 분포)

  • Lee, Kyeong-Yong;Park, Yong-Chul;Son, Seung-Kyu
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.363-373
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    • 2000
  • To understand and investigate chemical characteristics of thermal environment in the southwestern Paciflc, we have measured hydrological and chemical parameters such as temperature, salinity, transparency, pH, nutrients and hydrogen sulfide (H$_2$S). Samples were collected with CTD-casting at 12 station, in Manus Basin including PACMANUS, DESMOS and Susu Knolls, Hydrothermal systems consist of circulation zones where seawater interacts with rock, thereby changing chemical and physical characteristics of both the seawater and the rock. The altered seawater, called hydrothermal fluid, is injected back into the ocean from the hydrothermal vent fields and forms hydrothermal plumes. Consequently, we detected hydrothermal plume with transparency and sulfide anomalies at PACMANUS and Susu Knolls. Sulfide, as geochemical tracer of hydrothermal plume, ranged 0-3.31 ${\mu}$M, and averaged 0.63 ${\mu}$M in the study area. The height, flux and activity of the plume are affected by circulations in the deep water and the spread of plume follows along the isopycnal surface. Therefore the observed H$_2$S anomaly can provide important clue for the source location and it appears that the targestsource in the PACMANUS is aligned in the north-south direction.

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Evaluation of Multivariate Stream Data Reduction Techniques (다변량 스트림 데이터 축소 기법 평가)

  • Jung, Hung-Jo;Seo, Sung-Bo;Cheol, Kyung-Joo;Park, Jeong-Seok;Ryu, Keun-Ho
    • The KIPS Transactions:PartD
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    • v.13D no.7 s.110
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    • pp.889-900
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    • 2006
  • Even though sensor networks are different in user requests and data characteristics depending on each application area, the existing researches on stream data transmission problem focus on the performance improvement of their methods rather than considering the original characteristic of stream data. In this paper, we introduce a hierarchical or distributed sensor network architecture and data model, and then evaluate the multivariate data reduction methods suitable for user requirements and data features so as to apply reduction methods alternatively. To assess the relative performance of the proposed multivariate data reduction methods, we used the conventional techniques, such as Wavelet, HCL(Hierarchical Clustering), Sampling and SVD (Singular Value Decomposition) as well as the experimental data sets, such as multivariate time series, synthetic data and robot execution failure data. The experimental results shows that SVD and Sampling method are superior to Wavelet and HCL ia respect to the relative error ratio and execution time. Especially, since relative error ratio of each data reduction method is different according to data characteristic, it shows a good performance using the selective data reduction method for the experimental data set. The findings reported in this paper can serve as a useful guideline for sensor network application design and construction including multivariate stream data.

Thermal Stability and Mechanical Interfacial Properties of DGEBA/PMR-15 Blend System Initiated by Cationic Latent Thermal Catalyst (잠재성 양이온 개시제를 이용한 DGEBA/PMR-15 블렌드계의 열안정성 및 기계적 계면 특성에 관한 연구)

  • Park, Soo-Jin;Lee, Hwa-Young;Han, Mijeong;Hong, Sung-Kwon
    • Journal of Adhesion and Interface
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    • v.5 no.1
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    • pp.3-11
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    • 2004
  • In this work, the cure behaviors of the DGEBA/PMR-15 blends initiated by N-benzylpyrazinium hexafluoroantimonate (BPH) as a cationic latent catalyst were performed in DSC and DMA analyses. And, the thermal stabilities were carried out by TGA analysis and their mechanical interfacial properties of blends were measured in the context of critical stress intensity factor ($K_{IC}$). As a result, the curing activation energy ($E_a$) determined from Ozawa's equation in DSC and the relaxation activation energy ($E_r$) from DMA were increased with increasing PMA-15 content. Also, the thermal stabilities obtained from the integral procedural decomposition temperature (IPDT) and the glass transition temperature ($T_g$) were highly improved with increasing the PMR-15 content, which were probably due to the high heat resistance. And, the $K_{IC}$ showed a similar behavior with $E_a$, which was attributed to the improving of the interfacial adhesion or hydrogen bondings between intermolecular chains.

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Natural Rubber-Clay Nanocomposites by Latex Method : Morphology and Mechanical Properties (라텍스법에 의한 천연고무-클레이 나노 복합재료: 모폴로지와 기계적 물성)

  • Kim, W.H.;Kang, J.H.;Kang, B.S.;Cho, U.R.
    • Elastomers and Composites
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    • v.41 no.1
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    • pp.27-39
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    • 2006
  • In this study, modified DA-MMT filled NR/DA-MMT nanocomposites were manufactured by a latex method and a compounding method. Cure characteristics and mechanical properties of the Cloisite 15A, carbon black, Na-MMT filled NR compounds and the DA-MMT filled NR compound by a latex method were also evaluated. The filler content of all compounds was 10phr except the carbon black filled compound. Degree of intercalation and dispersion was characterized by X-ray diffraction (XRD) and transmission electron microscope (TEM). According to the XRD diffraction pattern and TEM analysis, extensive intercalation and homogeneous dispersion of the clay were obtained after the two-roll milling. Although the layer distance was increased, some parts of DA-MMT showed the layer distance of Na-MMT after vulcanization. DA-MMT filled NR compounds showed the highest ODR torques, tensile strength, modulus, and tear energy. The NR/DA-MMT nanocomposite (by a latex method) compared with a NR/DA-MMT nanocomposite (by a compounding method) was found that the improvement of the mechanical properties was mainly due to the degree of dispersion of the clay.

Short-term Prediction of Travel Speed in Urban Areas Using an Ensemble Empirical Mode Decomposition (앙상블 경험적 모드 분해법을 이용한 도시부 단기 통행속도 예측)

  • Kim, Eui-Jin;Kim, Dong-Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.4
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    • pp.579-586
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    • 2018
  • Short-term prediction of travel speed has been widely studied using data-driven non-parametric techniques. There is, however, a lack of research on the prediction aimed at urban areas due to their complex dynamics stemming from traffic signals and intersections. The purpose of this study is to develop a hybrid approach combining ensemble empirical mode decomposition (EEMD) and artificial neural network (ANN) for predicting urban travel speed. The EEMD decomposes the time-series data of travel speed into intrinsic mode functions (IMFs) and residue. The decomposed IMFs represent local characteristics of time-scale components and they are predicted using an ANN, respectively. The IMFs can be predicted more accurately than their original travel speed since they mitigate the complexity of the original data such as non-linearity, non-stationarity, and oscillation. The predicted IMFs are summed up to represent the predicted travel speed. To evaluate the proposed method, the travel speed data from the dedicated short range communication (DSRC) in Daegu City are used. Performance evaluations are conducted targeting on the links that are particularly hard to predict. The results show the developed model has the mean absolute error rate of 10.41% in the normal condition and 25.35% in the break down for the 15-min-ahead prediction, respectively, and it outperforms the simple ANN model. The developed model contributes to the provision of the reliable traffic information in urban transportation management systems.

Electrical and Magnetic Properties of Magnetite Powder during a Verwey Transition (Verwey 전이와 마그네타이트의 전기적 및 자기적 특성)

  • Yoon, Sunghyun
    • New Physics: Sae Mulli
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    • v.68 no.12
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    • pp.1302-1307
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    • 2018
  • The crystallographic, electrical and magnetic behaviors of magnetite powder in the vicinity of its Verwey transition were investigated in this study. Magnetite was prepared by synthesizing a nanoparticle precursor and then annealing it at $800^{\circ}C$ for 1 h under a dynamic vacuum. Crystallographic and morphology analyses were done by using scanning electron microscope (SEM) and X-ray diffraction (XRD). The electrical and the magnetic properties were examined by using $M{\ddot{o}}ssbauer$ spectroscopy, vibrating sample magnetometer (VSM) and resistivity measurement. Both the magnetic moment and the resistivity showed discontinuous changes at the Verwey transition temperature ($T_V$). The temperature dependence of magnetic anisotropy constant showed a monotonic decrease with increasing temperature, with slight dip near $T_V$. $M{\ddot{o}}ssbauer$ spectra showed the superposition of two sextets, one from the tetrahedral (A) and the other from the octahedral (B) sites. The results revealed that identical charge states existed in the B site at temperatures both above and below $T_V$. A coordination crossover resulted in a transition from an inverse to a normal spinel at or close to $T_V$.

Degradation of the Pd catalytic layer electrolyte in dye sensitized solar cells (염료감응태양전지에서 Pd 촉매층의 전해질과의 반응에 따른 특성 저하)

  • Noh, Yunyoung;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.2037-2042
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    • 2013
  • A TCO-less palladium (Pd) catalytic layer on the glass substrate was assessed as the counter electrode (CE) in a dye sensitized solar cell (DSSC) to confirm the stability of Pd with the $I^-/I_3{^-}$electrolyte on the DSSC performance. A 90nm-thick Pd film was deposited by a thermal evaporator. Finally, DSSC devices of $0.45cm^2$ with glass/FTO/blocking layer/$TiO_2$/dye/electrolyte(10 mM LiI + 1 mM $I_2$ + 0.1 M $LiClO_4$ in acetonitrile solution)/Pd/glass structure was prepared. We investigated the microstructure and photovoltaic property at 1 and 12 hours after the sample preparation. The optical microscopy, field emission scanning electron microscopy (FESEM), cyclic voltammetry measurement (C-V), and current voltage (I-V) were employed to measure the microstructure and photovoltaic property evolution. Microstructure analysis showed that the corrosion by reaction between the Pd layer and the electrolyte occurred as time went by, which led the decrease of the catalytic activity and the efficiency. I-V result revealed that the energy conversion efficiency after 1 and 12 hours was 0.34% and 0.15%, respectively. Our results implied that we might employ the other non-$I^-/I_3{^-}$electrolyte or the other catalytic metal layers to guarantee the long term stability of the DSSC devices.

Development the Geostationary Ocean Color Imager (GOCI) Data Processing System (GDPS) (정지궤도 해색탑재체(GOCI) 해양자료처리시스템(GDPS)의 개발)

  • Han, Hee-Jeong;Ryu, Joo-Hyung;Ahn, Yu-Hwan
    • Korean Journal of Remote Sensing
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    • v.26 no.2
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    • pp.239-249
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    • 2010
  • The Geostationary Ocean Color Imager (GOCI) data-processing system (GDPS), which is a software system for satellite data processing and analysis of the first geostationary ocean color observation satellite, has been developed concurrently with the development of th satellite. The GDPS has functions to generate level 2 and 3 oceanographic analytical data, from level 1B data that comprise the total radiance information, by programming a specialized atmospheric algorithm and oceanic analytical algorithms to the software module. The GDPS will be a multiversion system not only as a standard Korea Ocean Satellite Center(KOSC) operational system, but also as a basic GOCI data-processing system for researchers and other users. Additionally, the GDPS will be used to make the GOCI images available for distribution by satellite network, to calculate the lookup table for radiometric calibration coefficients, to divide/mosaic several region images, to analyze time-series satellite data. the developed GDPS system has satisfied the user requirement to complete data production within 30 minutes. This system is expected to be able to be an excellent tool for monitoring both long-term and short-term changes of ocean environmental characteristics.