• Title/Summary/Keyword: 열분석적 특성

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Synthesis and Characterization of Epoxy Silane-modified Silica/Polyurethane-urea Nanocomposite Films (에폭시 변성 실리카 나노입자/폴리우레탄-우레아 나노복합체 필름의 제조 및 특성 연구)

  • Joo, Jin;Kim, Hyeon Seok;Kim, Jin Tae;Yoo, Hye Jin;Lee, Jae Ryung;Cheong, In Woo
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.371-378
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    • 2012
  • Hydrophilic silica nanoparticles (SNPs) were treated by using 3-glycidoxypropyltrimethoxy silane (GPTMS) and then they were blended with polyurethane-urea (PUU) emulsions to obtain SNPs/PUU nanocomposite films. Thermo-mechanical properties of the nanocomposite films were investigated by varying the grafted amount of GPTMS onto SNPs and the contents of SNPs in the PUU matrix. The thermo-mechanical properties of the nanocomposite films were also compared in terms of the dispersibility of SNPs in the PUU matrix and thermal curing of the GPTMS-grafted SNPs. The maximum amount of grafted GPTMS was $1.99{\times}10^{-6}\;mol/m^2$, and which covered ca. 53% of the total SNP surface area. $^{29}Si$ CP/MAS NMR analyses with the deconvolution of peaks revealed the details of polycondensation degree and patterns of GPTMS in the surface modification of SNPs. The surface modification did not significantly affect colloidal stability of the SNPs in aqueous medium; however, the hydrophobic modification of SNPs offered a favorable effect on the dispersibility of SNPs in the PUU matrix as well as better thermal stability. XRD patterns revealed that GPTMS-grafted SNPs broadened the reduced the characteristic peak of polyol in PUU matrix. The composite films became rigid and less flexible as the SNP content increased from 5 wt.% to 20 wt.%. Particularly, Young's modulus and tensile modulus significantly increased after the thermal curing reaction of the epoxy groups in the SNPs.

Automatic Extraction of Training Data Based on Semi-supervised Learning for Time-series Land-cover Mapping (시계열 토지피복도 제작을 위한 준감독학습 기반의 훈련자료 자동 추출)

  • Kwak, Geun-Ho;Park, No-Wook
    • Korean Journal of Remote Sensing
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    • v.38 no.5_1
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    • pp.461-469
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    • 2022
  • This paper presents a novel training data extraction approach using semi-supervised learning (SSL)-based classification without the analyst intervention for time-series land-cover mapping. The SSL-based approach first performs initial classification using initial training data obtained from past images including land-cover characteristics similar to the image to be classified. Reliable training data from the initial classification result are then extracted from SSL-based iterative classification using classification uncertainty information and class labels of neighboring pixels as constraints. The potential of the SSL-based training data extraction approach was evaluated from a classification experiment using unmanned aerial vehicle images in croplands. The use of new training data automatically extracted by the proposed SSL approach could significantly alleviate the misclassification in the initial classification result. In particular, isolated pixels were substantially reduced by considering spatial contextual information from adjacent pixels. Consequently, the classification accuracy of the proposed approach was similar to that of classification using manually extracted training data. These results indicate that the SSL-based iterative classification presented in this study could be effectively applied to automatically extract reliable training data for time-series land-cover mapping.

A Study on Mitigation Plan of Urban Heat Island Phenomenon Using Landsat Time Series Imagery - Focusing on Cheongna International City - (시계열 Landsat 위성영상을 활용한 도시 열섬 현상 완화 방안에 관한 연구 - 청라 국제도시를 중심으로 -)

  • BAEK, Seon-Uk;KIM, Dong-Hyun;KIM, Hung-Soo;GU, Bon-Yup;CHOUNG, Yun-Jae
    • Journal of the Korean Association of Geographic Information Studies
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    • v.25 no.3
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    • pp.1-16
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    • 2022
  • Areas developed through land reclamation projects have huge economic advantages in terms of supplying lands that can be used for farmlands, urban areas and etc., however have relatively small areas of grasslands and densely located buildings compared to inland cities. Hence, an urban heat island is occurring in these areas due to this characteristic, and in particular, the urban heat island in Cheongna International City is getting serious. In this study, the urban heat island in Cheongna International City was evaluated and analyzed by classified into the three periods after the reclamation project: farmland(2001-2008), development(2009-2013) and artificial grassland(2014-2020). The land cover map and Landsat time-series imagery were utilized for measuring the differences of the land surface temperatures between the urbanized areas and the grassland/forest areas in Cheongna International City. The statistical results showed that the differences in the land surface temperature between these areas were calculated to be at most 0℃ during the period of farmland, at most 3.60℃ during the period of development, and at most 2.51℃ during the period of grassland. This study proved that the urban heat island phenomenon increased when the urbanized areas increased, and the urban heat island phenomenon decreased when the artificial grassland areas increased in Cheongna International City where the reclamation project was carried out. The statistical results derived through this research can be used as the reference data for identifying the urban heat island problem in urban planning and establishing the reduction plan.

Relation of Correlation about Rice quality related Characters in Condition storage of Unhulled rice (정조 저장조건에서 식미관련특성에 대한 상관성 정도)

  • Hwang, Pil-Seong;Lee, Jeom-Sig;Kim, Kee-Jong;Son, Jong-Rok;Chung, Won-Bok;Oh, Ju-Seong
    • Journal of Life Science
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    • v.17 no.4 s.84
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    • pp.510-514
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    • 2007
  • This study was carried on cool and RT(room temperature) storage of unhulled rice. In RT storage of an analysis of coefficient relation, high significant positive coefficients were observed in toyo index and breakdown, setback and protein content. high significant negative coefficients were showed setback and breakdown, breakdown and protein content. In cool storage of an analysis of coefficient relation, high significant positive coefficients were observed in toyo index and amylose content and gelatinization start temperature and protein content and high significant negative coefficients were showed toyo index and whiteness, toyo index and gelatinization start temperature, gelatinization start temperature and amylose content. In RT storage of a path coefficient analysis, a highest positive direct influence was observed in amylose content and a highest negative direct influence was protein content. Positive indirect influence was high revealed breakdown and protein content and negative indirect influence was gelatinization start temperature and Mg/K ratio. In cool storage of a path coefficient analysis, a highest positive direct influence was whiteness and a highest positive indirect influence was gelatinization start temperature. Positive indirect influence was high revealed gelatinization start temperature and amylose content, negative indirect influence was whiteness and gelatinization start temperature. In RT storage of Multiple regression equation of Toyo index based on physicochemical properties of unhulled rice, a highest coefficient of determination was revealed among five facters of whiteness, protein content, Mg/K ratio, amylose content and gelatinization start temperature. In cool storage of Multiple regression equation of toyo index based on physicochemical properties of unhulled rice, highest coefficient of determination was revealed among five facters of moisture content, amylose content, gelatinization start temperature, breakdown and setback.

Preparation and Quality Characterization of Apple Jam with Rosa rugosa Thunb. Fruit (해당화 열매 첨가 사과잼 제조 및 품질 특성)

  • Kim, Mi-Hyun;Kim, Myung-Hee;Yun, Sun-Ju;Lee, Byung-Yong;Lee, Chang-Won;Kim, Bo-Ae;Jang, Ki-Hyo;Lee, Jae-Cheol;Surh, Jeong-Hee
    • Korean journal of food and cookery science
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    • v.26 no.4
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    • pp.367-380
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    • 2010
  • Various contents of Rosa rugosa Thunb. fruit(0, 10, 20%), which is grown along the seashore of Gangwon province, were applied to apple jams having different sugar concentrations(20, 40, 60%). The resulting jams were analyzed using a sensory scoring test as well as a response surface methodology to identify the optimum conditions for the preparation of high-preference apple jams. The sensory properties based on sense of sight, smell and taste appeared to be linked to the sugar contents. It could be attributed to the presence of flavor compounds and pigments generated from the caramelization of sugar molecules during heat processing. On the other hand, rheological properties such as viscosity and spreadability were associated with Rosa rugosa fruit content, which was also verified by textural analysis of the jams. As the contents of Rosa rugosa increased, the hardness, gumminess, and chewiness of the jams decreased, which eventually might have contributed to the less thick and thus more spreadable sensory characteristics. Sensory evaluation revealed that apple jams were preferred when prepared with $\leq$10% of Rosa rugosa fruit and $\geq$55% of sugar contents. In particular, apple jams containing 10% Rosa rugosa and 60% sugar showed better mechanical qualities as well as higher sensory preference among 10 jams formulated using central composite design.

Characteristics of Recycled Fine Aggregate by Sodium Carbonated Water (탄산나트륨을 이용하여 제조한 순환잔골재의 품질 특성)

  • Hong, Sung-Rog;Kim, Ha-Seog;Kwak, Eun-Gu;Park, Sun-Gyu;Kim, Jin-Man
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.97-102
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    • 2011
  • Amount of disposed construction materials like waste concrete is growing fast and use of the recycled aggregate for concrete has been seriously considered. But the use of the recycled aggregate is very limited because recycled aggregate has very low quality. Therefore, quality of recycled aggregate is very important in the manufacturing of recycled aggregate concrete. We have studied a series of research according to chemical processes and investigate the alkaline elimination effect of recycled aggregate and quality variation of recycled aggregate by sodium carbonate. Thereafter we have evaluated quality of recycled fine aggregate and experimented quality of this aggregate. As a results, we find that it is easy to eliminate the calcium hydroxide in recycled aggregate by sodium carbonate and the quality of recycled aggregate increase by elimination of alkaline.

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Rainfall Variations of Temporal Characteristics of Korea Using Rainfall Indicators (강수지표를 이용한 우리나라 강수량의 시간적인 특성 변화)

  • Hong, Seong-Hyun;Kim, Young-Gyu;Lee, Won-Hyun;Chung, Eun-Sung
    • Journal of Korea Water Resources Association
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    • v.45 no.4
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    • pp.393-407
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    • 2012
  • This study suggests the results of temporal and spatial variations for rainfall data in the Korean Peninsula. We got the index of the rainfall amount, frequency and extreme indices from 65 weather stations. The results could be easily understood by drawing the graph, and the Mann-Kendall trend analysis was also used to determine the tendency (up & downward/no trend) of rainfall and temperature where the trend could not be clear. Moreover, by using the FARD, frequency probability rainfalls could be calculated for 100 and 200 years and then compared each other value through the moment method, maximum likelihood method and probability weighted moments. The Average Rainfall Index (ARI) which is meant comprehensive rainfalls risk for the flood could be obtained from calculating an arithmetic mean of the RI for Amount (RIA), RI for Extreme (RIE), and RI for Frequency (RIF) and as well as the characteristics of rainfalls have been mainly classified into Amount, Extremes, and Frequency. As a result, these each Average Rainfall Indices could be increased respectively into 22.3%, 26.2%, and 5.1% for a recent decade. Since this study showed the recent climate change trend in detail, it will be useful data for the research of climate change adaptation.

Effect of Hydrothermal and Enzymatic Treatments on the Physicochemical Properties of Waxy Maize Flour (열수 및 효소 처리에 의한 찰옥수수가루의 물리화학적 특성)

  • Lee, Dong-Jin;Choi, So-Mang;Lim, Seung-Taik
    • Korean Journal of Food Science and Technology
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    • v.48 no.2
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    • pp.165-171
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    • 2016
  • Physicochemical properties of waxy maize flours prepared by hydrothermal and enzymatic treatments were evaluated. Waxy maize flours were hydrothermally treated using heat-moisture treatment (HMT) and annealing (ANN) and enzymatically treated using commercial enzymes (cellulase, proteinase, and pectinase). The HMT-modified waxy maize flours had low water absorption index (WAI), melting enthalpy, viscosity, and crystallinity. However, ANN-modified and enzymatically modified waxy maize flours had high WAI, melting enthalpy, and viscosity. X-ray diffraction analysis of ANN-modified and enzymatically modified waxy maize flours revealed a typical A-type pattern and displayed sharper crystalline peaks than those observed for the control groups (native waxy maize flours). In contrast, the crystallinity of HMT-modified waxy maize flours were decreased by hydrothermal treatment.

Characteristics of Hydraulic Head Variation at Multi-packer Wells in a Coastal Area (해안지역 다중패커공에서의 수리수두 변화 특성)

  • Cheong, Jae-Yeol;Hamm, Se-Yeong;Ok, Soon-Il
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.291-298
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    • 2015
  • For hydrogeological studies, it is of importance to observe hydraulic head in order to interpret groundwater flow, characterize aquifers, and calibrate groundwater flow model. This study analyzed the zonal variation of hydraulic heads at the eight monitoring wells (GM-1~GM-8) installed with multi-packers in a coastal area and verified vertical and lateral trends of the hydraulic gradients. Hydraulic heads were expressed as the depth of water because the monitoring wells have different depths. The hydraulic gradient at the nearest well (GM-5) shows 0.0142 with increasing trend of hydraulic gradient along depth. This fact indicates typical phenomenon of the discharge area. On the other hand, GM-1 and GM-2 wells in coastal area demonstrate constant hydraulic gradient down to the depth of 100 meters while at the zone of deeper than 100 m the hydraulic gradients illustrate 0.0196 and 0.0735, respectively. This indicates that horizontal flow is dominant at shallower zone than 100 m whereas upward flow is dominant at the zone deeper than 100 m. GM-3 well located farther than the other wells from the coast shows a small hydraulic gradient of 0.0046 that evidences a prevalent horizontal flow between the recharge area and the discharge area.

Fire and explosion risk of metal particles with the same mean diameter (동일 입경 조건에서의 금속분진의 화재.폭발위험성)

  • Han, Ou-Sup;Lee, Keun-Won
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.376-377
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    • 2011
  • 최근 Mg, Mg-Al합금, Al은 전자제품의 케이스, 차량의 휠 등의 신소재로서 활용성이 높아 사회적 수요가 급격히 늘고 있다. 이러한 수요 증가와 함께 관련 사업장에서는 취급 과정에서 폭발사고 위험성이 높아지고 있는데, 2010년도에는 국내 사업장에서 금속 분진에 의한 폭발사고가 4건이 발생하여 인명 및 재산피해가 발생하였다. Mg-Al합금의 폭발사고로 사망 1명과 부상 2명이 발생하였으며, Al분진의 폭발사고는 3건이 발생하여 사망 2명과 부상 3명의 인명피해로 이어졌다. 사고조사를 통하여 사업장에서의 금속분진에 대한 위험인식이 매우 낮은 것이 유사 사고가 반복되고 있는 가장 큰 이유로 알려지고 있는데, 이는 금속분진에 대한 부족한 안전기술정보와 밀접한 관련이 있다. 본 연구에서는 Mg, Mg-Al합금, Al등을 취급하는 관련 사업장에서 폭발사고 예방대책을 위하여 활용할 수 있는 폭발특성에 관한 안전기술정보 제공을 목적으로 하고 있다. 보다 구체적으로는 사고 다발 금속분진에 대한 위험성 이해에 도움을 될 수 있도록 동일 입경분포 조건에서의 위험성을 정량적으로 평가하였으며, 이를 위하여 각 금속분진의 동일 입경 조건에서 최대폭발압력, 폭발하한계 등의 폭발위험성 데이터를 실험적으로 조사 하였다. 조사한 시료는 평균입경 200 mesh의 Al, Mg, Mg-Al(60:40 wt%)로서 입도분석기(Beckman Coulter LSI 3320)를 사용하여 측정한 결과 평균입경은 약 $155{\mu}m$로 나타났다. Al분진의 농도변화에 따른 폭발압력을 조사한 결과, 최대폭발압력(Pmax)은 7.9 bar였으며 최대폭발압력상승속도 (dt/dP)max는 농도 $1500[g/m^3]$에서 322 [bar/s]로 최대가 되었으며 폭발 하한계(LEL)는 $70[g/m^3]$가 얻어졌다. 반면에 순수한 Mg의 LEL은 $30[g/m^3]$였으며 Pmax는 6.4 bar, (dP/dt)max는 100 [bar/s]가 얻어졌다. 이러한 결과로부터 LEL이 낮은 Mg는 Al보다 연소성이 큰 것으로 나타났으며, Al은 화염을 유지하는데 필요한 최저 열분해 가스농도를 확보하는데 Mg보다도 고농도의 분진이 필요함을 알 수 있었다. 또한 Mg-Al(60:40 wt%)의 LEL은 $50g/m^3$이었으며 Pmax는 9.4 bar, (dP/dt)max는 472 [bar/s]가 얻어졌다. 이러한 결과로부터 Mg-Al(60:40 wt%)합금의 연소성을 살펴보면 착화하기 쉬운 정도는 Mg와 Al의 성분비에 의해 변화하지만 Mg와 Al의 중간 정도로 나타나는 반면, Pmax는 Mg 또는 Al의 단독 물질 성분보다도 매우 큰 것을 알 수 있었다. 본 연구를 통하여 단일 성분의 Mg와 Al보다도 Mg와 Al이 일정 비율로 구성된 Mg-Al합금의 경우가 화재폭발 위험성이 증가한다는 사실을 알 수 있었으며, 이와 같은 폭발위험특성 자료를 활용하여 분진의 보관, 취급, 폐기 등의 지속적 관리가 필요하며 사업장 특성에 적합한 안전대책을 통한 사고예방대책이 요구된다.

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