• Journal of Adhesion and Interface
• /
• v.4 no.3
• /
• pp.33-40
• /
• 2003

In this work, diglycidyl ether of bisphenol A (DGEBA)/polyetherimide (PEI) blends were cured using 4,4-diaminodiphenyl methane (DDM). And the effects of addition of different PEI contents to neat DGEBA were investigated in the thermal properties and fracture toughness of the blends. The contents of contents of containing PEI were varied in 0, 2.5, 5, 7.5, and 10 phr. The cure activation energies ($E_a$) of the cured specimens were determined by Kissinger equation and the mechanical interfacial properties of the specimens were performed by critical stress intensity factor ($K_{IC}$). Also their surfaces were examined by using a scanning electron microscope (SEM) and the surface energetics of blends was determined by contact angles. As a result, $E_a$ and $K_{IC}$ showed maximum values in the 7.5 phr PEI. This result was interpreted in the increment of the network structure of DGEBA/PEI blends. Also, the surface energetics of the DGEBA/PEI blends showed a similar behavior with the results of $K_{IC}$. This was probably due to the improving of specific or polor component of the surface free energy of DGEBA/PEI blends, resulting in increasing the hydrogen bonding of the hydroxyl and imide groups of the blends.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.6
• /
• pp.670-675
• /
• 2016

Both melting temperature and enthalpy of MBCA/DMTDA mixtures were measured as a function of DMTDA compositions using DSC. The thermal properties of polyurethane elastomer samples prepared with MBCA, DMTDA, and 40/60 MBCA/DMTDA mixture as curing agents were also observed using TGA. MBCA and DMTDA showed good miscibility over the entire composition range, exhibiting individual DSC melting peaks. Peak temperatures were non-linearly reduced as DMTDA concentrations increased, being approximately $60^{\circ}C$ in the case of the 40/60 MBCA/DMTDA mixture. Furthermore, melting enthalpy of the mixture was calculated as 3.8 J/g, which was only 4.3% compared to 87.3 J/g of MBCA. Based on these results, crystallization of the mixture was considered to occur very slowly, and the fluidic gel-state of the mixture was visually confirmed to be maintained over 5 days at room temperature. Thermal decomposition of polyurethane elastomer prepared with 40/60 MBCA/DMTDA curative started at about $190^{\circ}C$, which is similar to that observed for DMTDA, only except decomposition behavior over higher temperature of $400^{\circ}C$.

• Applied Chemistry for Engineering
• /
• v.26 no.5
• /
• pp.538-542
• /
• 2015

In this work, effects of the blend composition composed of 0, 10, 20, 30 and 40 wt% of nylon 6 to epoxy (diglycidylether of bisphenol-A, DGEBA) resin were investigated in terms of cure kinetics and thermal stability by differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA). As the content of the nylon 6 increased, the maximum exothermic temperature ($T_{max}$) and the value of cure activation energy ($E_a$) decreased. The maximum exothermic temperature of the blending samples decreased with increasing in nylon 6 content, resulting in the decrease in curing activation energy of them due to the rapid curing reaction with epoxy resin in this system. From TGA analysis results of the DGEBA/nylon 6, the thermal stability based on the thermal stability index ($A^*{\cdot}K^*$) and integral procedure decomposition temperature (IPDT) increased with increase in the nylon 6 content. This was because of the combination of DGEBA and nylon 6 having good heat resistance, resulting in improving thermal stability of the DGEBA/nylon 6.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.16 no.10
• /
• pp.1841-1852
• /
• 1992

With the wide application of fiber-reinforced composite material in aircraft, space structures and robot arms, the design and manufacture of composite joints have become a very important research area because they are often the weakest areas in composite structures. In this study, the effects of the adhesive thickness, residual thermal stress on the torque capacity of the tubular single lap joints were studied. The torque capacity of the adhesive joints were experimentally determined and found to be inversely proprotional to the adhesive thickness. In order to match the experimental results to the theoretical analyses, the elastic-perfectly plastic material properties of the adhesive were used in the closed form solution. Also, the residual thermal stress of the joints were calculated by the finite element method and it was proved that the residual thermal stress could play an important role in the thick adhesive joints.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2018.06a
• /
• pp.94-94
• /
• 2018

무인자동차 및 전기자동차 등 전장부품 및 메인보드에서의 오염 방지와 전자파에 의한 신호 간섭 현상에 따른 기기의 오작동을 방지하고자 MWCNT의 clustering 및 tangling현상을 활용하여 self cleaning 기능을 갖는 super hydrophobic 표면과 high aspect ratio에 의한 percolation 현상을 활용하여 전자파 차폐를 위한 낮은 표면저항을 만족하는 복합 재료로 구성된 코팅에 관하여 연구하였다. 이를 위해 isopropyl alcohol(IPA)을 용매로 산처리 한 MWCNT와 무기바인더, 불소계 실란을 첨가하여 초음파 분산을 함으로써 코팅액을 제조하였다. 이를 full cone nozzle type, 흡상식 스프레이 조건으로 알루미늄 시편위에 스프레이 코팅 후 열경화 하여 접촉각측정기로 측정 결과 $160^{\circ}$이상의 초발수 표면과 Low Resistivity Meter로 표면저항을 측정한 결과 $10^3{\Omega}/cm^2$ 이하의 낮은 코팅막을 구현하였으며 내구성 실험을 위한 항온항습 장비로 $80^{\circ}C$의 내열테스트 및 80%와 $80^{\circ}C$조건하에서의 내습테스트 결과 표면에 이상 없음을 확인하였고 열전도율 측정을 위해 밀도 측정 결과 $2.68g/cm^3$, 비열 측정 결과 $0.85J/g^{\circ}C$가 열확산율 측정결과 $88.64mm^2/s$가 측정 되었으며 밀도, 비열, 열확산율을 곱한 값인 $201.9W/m{\cdot}K$의 열전도를 갖는 코팅막을 구현하였다.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1999.10a
• /
• pp.69-72
• /
• 1999

In this study, we blended 2 grades of ultra fine cement using the results of previous stud. And the cement slurry was produced by water each water/cement ratio. The slurries were observed hydration phenomena during 28 days with SEM, XRD and DSC. The specimen made by slurry were evaluated with the hardened properties such as compressive strength, flexural strength length change and water absorption. And were tested the adhesive strength of specimen made by injecting the slurry between mortar bars.

• Proceedings of the Korean Institute of Industrial Safety Conference
• /
• 1997.11a
• /
• pp.289-294
• /
• 1997

매스콘크리트 구조물에서는 이미 경화된 콘크리트가 새로이 타설된 콘크리트의 변형을 제한하여 시공직후에 부재의 길이방향에 수직한 균열이 발생하는 경우가 자주 보고 되고 있다. 이 균열은 먼저 타설된 바닥에 대하여 벽체의 변위가 제한될 때 구속인장응력에 의해 발생된다. 이러한 균열의 발생원인은 몇 가지로 살펴볼 수 있는데, 그 하나는 먼저 타설한 바닥 콘크리트와 새로 타설한 벽체 콘크리트와의 수화열 발생의 차이에 의한 것이며, 두번째 이유로 바닥과 벽체사이의 건조수축의 차이를 들 수 있다. (중략)

• Proceedings of the Korean Vacuum Society Conference
• /
• 2001.07a
• /
• pp.27-28
• /
• 2001

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.17 no.6
• /
• pp.251-255
• /
• 2007

We made $(1-x)BCB-xBNT(BaNd_2Ti_4O_{12})$ (x=20, 30, 40, 50 vol%) composite thick film with a high dielectric constant and low loss by the hand casting method. Dielectric constant and dielectric loss of prepared thick film are measured at 1MHz and curing behavior of the film are observed through thermal analysis such as DSC. We investigated the effect of contents of BNT filler and curing behavior of film on dielectric properties of BCB-BNT composite. Dielectric constant increased with increasing BNT filler from 20 to 50 vol% and dielectric loss ($tan{\delta}$) decreased with increasing BNT filler. Dielectric constant and loss ($tan{\delta}$) of composite material was not nearly dependent on the curing behavior. But as a result of TCC (Temperature Characteristics of Coefficient) decreased with increasing the curing temperature, we confirmed that the curing of these composite system is most stable above $250^{\circ}C$.

• International Journal of Highway Engineering
• /
• v.8 no.1 s.27
• /
• pp.45-54
• /
• 2006

The Construction policy of government ever since 1970s have brought the economical growth, but has been causing environmental problems. Most roads were paved either asphalt concrete or portland cement concrete. These types of pavements has caused to rise temperature by making local heat islands in urban during summer time. Recently the wet-mixing solidified soil pavement, a kind of soil-cement, has developed and has been applied to the environment-oriented pavement. The solidified soil wet-mixed is placed on the subgrade along with asphalt concrete and portland cement concrete. Thermistors are laid in these field test pavements. The temperature gradients of these pavements are automatically measured with time. As the results of this test, the equation estimating surface temperature of pavement is proposed by analyzing measured temperature data. It is shown that the temperature change within the surface layer due to the change of air temperature is the greatest in the asphalt mixture and the least in the solidified soil mixture. Since it is proven that this wet-mixing solidified soil pavement emit less radiant heat than other existed pavements. Therefore this type of pavement can be successfully applied to the roads, such as walks, parkways, and bikeways, which are required to be human-friendly and environment-oriented.