• Prospectives of Industrial Chemistry
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• v.24 no.2
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• pp.31-37
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• 2021

일반적으로 cross-link된 열경화성 에폭시수지는 유기용매에 용해되지 않고 열에 용융되지 않는 특성이 있다. 따라서 에폭시수지가 사용된 물질, 특히 탄소섬유강화플라스틱(carbon fiber reinforced plastic, CFRP)은 재활용이 어렵고, 사용 후 폐기물 처리에 막대한 비용이 소비되고 있다. 본 원고는 열경화성 에폭시수지 응용물 중 CFRP의 재활용을 중심으로 한 친환경적 재활용 기술에 관하여 정리하였다. 특히, CFRP의 구성요소인 탄소섬유(CF)와 기지재인 에폭시수지를 모두 재활용 할 수 있는 화학적 방법에 관하여 보고한다. 더 나아가 열경화성 에폭시수지의 화학적 분해물의 재이용기술에 관한 예를 소개한다.

• Polymer Science and Technology
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• v.11 no.5
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• pp.603-607
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• 2000

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.04a
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• pp.103-108
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• 1999

A synthesized model of pultrusion process considering thermally induced deformatiion was established. The model was composed of liquid resin flow model thermo-chemical analysis and linear elastic analysis. in order to verify the above-mentioned models several experiments were performed. A laboratory scale pultrusion line was established and glass/polyester composites were fabricated. the experimental results were compared with the calculated ones. The model successfully could estimate degree of cure pulling force and amount of process-induced deformation.

• Composites Research
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• v.20 no.5
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• pp.13-19
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• 2007

Fiber-reinforced thermoplastic composites not only approach almost near to the strength of thermosetting composite but also has excellent productivity, recycling property, and impact resistance, which are pointed as weaknesses of thermosetting composites. The study for strength calculation of one direction fiber-reinforced thermoplastic composites and the study measuring precisely fiber orientation distribution were presented. Need the systematic study for the data base that can predict mechanical properties of composite material and fiber orientation distribution by the fiber content ratio was not constructed. Therefore, this study was investigated what affect the fiber content ratio and fiber orientation distribution have on the strength of composites. Fiber-reinforced thermoplastic composites by changing fiber orientation distribution and the fiber content ratio were made. Tensile strength ratio of $0^{\circ}$ direction of fiber-reinforced composites increased being proportional the fiber content and fiber orientation function as change from isotropy(J=0) to anisotropy(J=1). But, tensile strength ratio of $90^{\circ}$ direction by separation of fiber filament decreased when tensile load is imposed fur width direction of reinforcement fiber length direction.

• Polymer(Korea)
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• v.35 no.2
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• pp.176-182
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• 2011

Liquid crystalline aromatic polyesters (LCPs) are representative examples of thermotropic liquid crystalline polymers, whose structure-property relationships have been the subject of many researches. In this study, we synthesized organo-soluble liquid crystalline aromatic polyesters, and their composites with acetylene-terminated thermoset resins were prepared and characterized. Soluble LCPs were synthesized by employing 6-hydroxy-2-naphthoic acid, terephthalic acid, isophthalic acid, and 4-aminophenol as monomers via condensation polymerization based on transesterfication and transamidation. Acetylene-terminated thermoset resins were synthesized by the reaction of 4-ethynylaniline with terephthaloyl dichloride, isophthaloyl dichloride or 4,4'-biphenyldicarbonyl dichloride. We prepared the soluble LCP/thermoset composites by solution blending followed by thermal treatment. The thermal stability, thermal expansion coefficient, and dielectric properties of the composite were studied.

• Journal of the Korean Society for Nondestructive Testing
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• v.23 no.5
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• pp.409-417
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• 2003

Cure monitoring can be used to improve the quality and productivity of thermosetting resin matrix composite products during their manufacturing process. In this work, the sensitivity of dielectrometry was improved by adequate separation the efforts of sensor and externals on the measured signal. A new algorithm to obtain the degree of cure during dielectric cure monitoring of glass/polyester and glass/epoxy composites was developed by employing a function of both temperature and dissipation factor, in which five cure monitoring parameters were used to calculate the degree of cure. The decreasing pattern of dissipation factor was compared with the relationships between the degree of cure and the resin viscosity. The developed algorithm might be employed for the in situ cure monitoring of thermosetting resin composites.

• Composites Research
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• v.28 no.3
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• pp.99-103
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• 2015

This paper presents the cure kinetics studies on the cure reaction of thermosetting resin. Above all, change in degree of cure and specific heat capacity according to temperature are observed using DSC and MDSC. The results are analyzed by cure kinetics and specific heat capacity model. Glass transition temperature was also measured to apply to the specific heat capacity model. Model parameters were gained from the modeling result. As a result, behavior of specific heat capacity can be calculated mathematically.

• Composites Research
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• v.17 no.2
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• pp.15-20
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• 2004

It is a primary object of the present study to test and evaluate the shear load carrying capability of a carbon fiber reinforced thermoses composite structure with buttress grooves for military applications. The buttress form of groove is an effective structure in any applications where high shear loads are transferred in one direction between structural components. Inverse ballistics methodology was introduced to investigate the high strain rate properties of composite groove specimens. In comparison with the conventional methods, inverse ballistics technique is a proper one under dynamic environment.

• 한국정보통신설비학회:학술대회논문집
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• 2008.08a
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• pp.545-548
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• 2008

불포화 폴리에스테르 수지를 결합재로 사용하여 제작되는 폴리머 콘크리트 맨홀은 조기 고강도 발현, 접착성. 수밀성, 내동결융해성, 내약품성, 내마모성, 전기절연성이 우수하여 프리캐스트로 제작되는 많은 통신용 맨홀에 적용되고 있다. 폴리머 콘크리트의 결합재로 사용되는 불포화 폴리에스테르 수지는 열경화성수지로써, 자체 발열에 의해 거푸집을 탈형할 정도의 초기 경화 반응이 나타나지만, 구조물로서 요구되는 소요 강도를 발휘하기 위해서는 적정 온도에 의한 추가 양생이 반드시 필요하다. 이에 본 논문에서는 폴리머 콘크리트의 휨 강도 시험용 공시체를 사용하여, 다양한 양생 온도 조건 및 양생기간에 따른 휨 강도를 측정하였으며, 이를 가열 촉진 양생에 의한 휨 강도와 비교하여 콘크리트가 소요 강도를 발휘하는데 요구되는 적정 온도와 기간을 도출하였다. 이를 통해 폴리머 큰크리트 맨홀의 품질 확보를 위한 생산 관리와 제품 검사를 체계적이고 효율적으로 수행할 수 있도록 하였다.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.422-425
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• 1998

섬유강화 복합재료는 고성능 섬유와 고분자 수지를 조합하여 재료의 물성 향상 및 고기능화를 목적으로 만들어지는 재료이며, 사용되는 고분자 매트릭스의 종류에 따라 열가소성 복합재료와 열경화성 복합재료로 나뉘어진다. 이 중 열경화성 복합재료에 관한 연구 및 그의 실용화는 오래 전부터 활발히 진행되어 산업재료 및 군사, 우주용 재료로 각광을 받아 왔으나 최근 지구 환경문제가 심각해지면서 사용 후 분해 및 재활용이 가능한 열가소성 복합재료에 관한 연구에 관심을 가지게 되었다. (중략)