• Title/Summary/Keyword: 연화현상

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Changes in the Enzyme Activities, Pectins and Structure of Persimmon Fruit during Softening (감과실의 연화중 효소활성, 펙틴 및 조직의 변화)

  • 신승렬;문광덕;이광희;김광수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.5
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    • pp.611-616
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    • 1993
  • This study was carried out to investigate change in the polygalacturonase and ${\beta}-galactosidase$ activities, pectins, cell wall structure of persimmon fruit during ripening and softening. Polygalacturonase and ${\beta}-galactosidase$ activities were not detected at turning stage. However polygalacturonase activities of mature and soft persimmon fruits were 55.01 and 206.70units/100g-fresh weight(fr. wt.), respectively. ${\beta}-Galactosidase$ activities of mature and soft persimmon fruits were 21.79 and 380.23unit/100g-fr. wt. respectively. The contents of total and insoluble pectins increased during maturation but decreased during softening. The content of water-soluble pectin increased during maturation and softening. The intercellular space was in larged during ripening, and middle lamella was degraded in mature persimmon fruit, and the cells of soft persimmon fruit were separated each other.

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The Change of Physical Properties of Epoxy Molding Compound According to the Change of Softening Point of ο-Cresol Novolac Epoxy Resin (올소 크레졸 노볼락 에폭시 수지 연화점 변화에 따른 에폭시 몰딩 컴파운드의 물성 변화)

  • Kim, Hwan Gun;Ryu, Je Hong
    • Journal of the Korean Chemical Society
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    • v.40 no.1
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    • pp.81-86
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    • 1996
  • The physical properties of epoxy molding compound (EMC) according to the change of softening point of epoxy resin have been investigated in order to study the relationship between the properties of o-cresol novolac epoxy resin, which is main component of EMC for semiconductor encapsulation, and EMC. The softening points of used epoxy resin are 65.1 $^{\circ}C$, 72.2 $^{\circ}C$, and 83.0 $^{\circ}C$, respectively. The flexural strength and flexural modulus as mechanical properties were measured, and thermal expansion coefficient, thermal conductivity and glass transition temperature (Tg) as thermal properties, and spiral flow as moldability have been investigated to see the change of physical properties of EMC. The flexural modulus, thermal expansion coefficients in the glass state (${\alpha}_1$), and thermal conductivity of EMC were found to be keep constant value irrespective of the change of softening point, but Tg increased with softening point of epoxy resin, and the spiral flow decreased with that. It can be considered that these phenomena are due to the increase of crosslinking density of EMC according to the increase of softening point. The transition points were found out in the thermal expansion coefficient data in the rubbery state (${\alpha}_2$) and the flexural strength data. These can show the decrease of filler dispersion according to increase of epoxy resin viscosity.

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Mechanical Model for Failure of Compressed Concrete in Reinforced Concrete Beams (철근 콘크리트 보에서 압축력을 받는 콘크리트의 파괴에 대한 역학적 모델)

  • 한국콘크리트학회
    • Magazine of the Korea Concrete Institute
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    • v.16 no.4 s.81
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    • pp.70-77
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    • 2004
  • 콘크리트 구조물에 대한 많은 기준들의 요건에 따르면, 휨을 받는 철큰 콘크리트(RC) 보의 압축부에서의 응력은 일반적으로 일축의 응력-변형을 관계를 이용하여 계산한다. 이와 같은 접근은 가끔씩 압축력을 받는 콘크리트에서 부서짐이 발성할 때 보의 구조적 거동을 재현하지 못할 수 있다. 결과적으로, RC 구조물의 지지력과 그들의 연성은 근사적으로 평가된다. 본 논문에서는 압축을 받고 있는 콘크리트의 postpeak 거동은 활동면을 이용하여 모델링되었다. 이 활동 면의 모멘트-곡률곡선에서 연화부분에 그 원인이 있다. 제안된 활동현상의 수학적 표현은 압축력을 받는 콘크리트(즉, 연화부분의 거동이 압축영역의 크기와 변형률구배(곡배)에 의존하는)에 있어서 특정한 응력-변형률 관계를 정의하는 것이 얼마나 어려운지를 보여주고 있다.

TMCP 강의 용접열영향부 인성에 관한 연구

  • 신민태;윤중근;김희진
    • Journal of Welding and Joining
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    • v.4 no.3
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    • pp.43-49
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    • 1986
  • Weldability of the TMCP steel manufactured by controlled rolling followed by accelerated cooling process was investigated. For comparison, two other steel plates produced by different manufacturing processes were selected; normalized and controlled rolled. Tandem submerged arc welding with both side one run technique was carried out. The results of this study can be summarized as follows; TMCP steel having the lowest carbon equivalent shows the best combination of mechanical properties, not only in the base metal but also in the heat affected zone. In the HAZ, the accelerated colling effect imarted on the trengthis releved by the weld thermal cycles, and thus the strength of the welded joint decrease substantially accompanied with the fracture in the HAZ. On the other hand, not only the softening but the fine microstructure can preserve the high toughness of TMCP steel in the HAZ.

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Yielding behavior and yield strength of plate structure containing softened region (연화부를 포함한 판재의 항복거동과 항복강도)

  • 배강열;김희진;이태열;엄동석
    • Journal of Welding and Joining
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    • v.8 no.3
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    • pp.79-88
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    • 1990
  • Welded joint often contains soft or softened regions such as the HAZ of TMCP steel welded with high heat input. In this study, the equivalent yield strength of plate structure containing softened region was predicted by FEM analysis, and its incremental behavior was explained with the results of the analysis. The calculated results of yield strength indicated the following for the plate structures. 1) As the softened region starts to yield, shear stress begins to build up along the boundary between base metal and softened region. This results in multi-axial stress condition which gives restraint on the softened region. 2) Restraint effect has a significant influence on the distribution of the shear stress, the nominal stress, and the strain. 3) The yielding behavior of softened region becomes the same as that of base metal when both ratios of length to width and thickness to width of softened region are larger than 30 and 13 respectively.

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Material Degradation and Life Assessment in Mechanical Equipment and Structure (기계.구조물의 경년열화와 수명평가기술)

  • Kim, K.Y.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.2
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    • pp.129-144
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    • 1999
  • 플랜트와 같은 장치산업은 내구성 구조물이므로 사용중에 열화가 발생하는 것은 필연적이다. 특히 고온, 고압의 부식환경하에서 사용되는 설비는 손상이 심하므로 가동중에 돌발적인 고장이 발생하여 플랜트의 가동을 중지하거나 파손사고가 일어나 생산손실은 물론 경우에 따라서는 안전사고의 발생, 환경오염 등 사회적인 문제를 일으키므로 이들 설비의 경년열화 실체를 충분히 이해하고 대책을 수립하는 것은 대단히 중요하다. 따라서 본고에서는 장치산업에서 발생하는 열화현상(재료의 연화, 경화 및 취화, 크리프, 피로, 부식, 마모 등)중 손상의 주류를 이루는 연화, 경화 및 취화, 크리프 피로에 대하여 기본적인 손상기구(damage mechanism)와 비파괴적 진단 및 평가 방법에 주안점을 두어, 현재 국내의 각종 플랜트 진단에 실용화된 기술을 해설하여 이 분야에 종사하는 관계자 여러분의 이해에 조금이라도 기여코자 한다.

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The softening behavior of Mg-Li-Al(-Zr) alloys (Mg-Li-Al(-Zr) 합금의 연화현상)

  • Kim, Y.W.;Kwang, Y.H.;Lim, Y.J.;Kim, D.H.;Hong, C.P.
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.1
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    • pp.10-16
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    • 1998
  • The softening behavior of squeeze cast Mg-Li-Al and Mg-Li-Al-Zr alloys have been investigated. The highest hardness values of Mg-Li-Al and Mg-Li-Al-Zr alloys were obtained after solution treatment at $400^{\circ}C$ for 1 hour. The hardness value, however, decreased as the aging temperature and time increased. Microstructural and calorometric analyses showed that quenched-microstructure changed from primary (${\alpha}$ and ${\beta}$)+secondary ${\alpha}$ to primary(${\alpha}$ and ${\beta}$)+secondary ${\alpha}+{\theta}$ after aging. The softening during aging was due to the coarsening of ${\theta}$ precipitates.

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TMCP 강재와 그 용접부의 강도특성

  • 김영식
    • Journal of the KSME
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    • v.30 no.2
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    • pp.146-154
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    • 1990
  • 수냉형의 Bo kg/$\textrm{mm}^2$1급 TMCP 고장력 강재를 중심으로, 이 강재 모재의 기계적 특성 및 용접부의 각종 사용특성에 관해 종래의 압연제법에 의한 동일강도레벨의 고장력강판과 비교하여 고찰하고 이 강재의 유효이용에 대하여 설명하였다. TMCP 고장력 강판은 탄소당량이 낮고 결 정립 미세화가 달성되기 때문에 파괴인성이나, 용접부의 내외화, 내용접균열성 면에서 탁월한 특 징을 가지나 용접조립시 용접열사이클로 인한 연화현상 때문에 용접부의 사용특성이 문제로 될 수 있다. 그러나 용접조건이나, 강판의 강도, 화학성분의 배려, 선택에 따라 실용상 별로 문제가 되지 않음이 확인하고 있다. 이와 같은 특징으로 인해 TMCP강은 조선용 소재뿐만 아니고, 북해, 북극해와 같은 한냉빙해역의 가혹한 환경에서 작동되는 해양구조물용이나 라인 파이프용 소재 로서도 그 활용이 확대되어 갈 것으로 생각된다.

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Quantitative Evaluation of Machinability of Free-Cutting Phosphor Bronze Alloy by using a Piezoelectric Tool Dynamometer

  • Cho, Hoon;Lee, Byoung-Soo;Ryu, Ho-Yeun;Jo, Hyung-Ho
    • Journal of Korea Foundry Society
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    • v.27 no.5
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    • pp.217-220
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    • 2007
  • 절삭특성은 재료를 원하는 형상으로 가공하기 위해 재료의 불필요한 부분을 제거할 경우 그 가공성이 쉽거나 어려움에 대한 정도로 전의될 수 있는데 동합금 소재의 절삭특성은 절삭시 발생된 칩의 형상이나 길이를 측정하거나 또는 공구계에 부착된 토오크 미터에 의해 절삭력을 간접적으로 측정하는 방법 등이 사용되어 오고 있다. 상기의 평가방 법은 절삭특성의 간접적인 평가방법이라는 한계와 정확도에 문제가 있는 실정이다. 본 연구에서는 압전형 공구동력계(Piezoelectric Tool Dynamometer)를 쾌삭인청동합금 피절삭물에 직접 부착하여 절삭가공시 절삭력은 정량적으로 직접 측정하고자 하였다. 쾌삭인청동합금의 소둔 열처리 시간이 증가할수록 결정립의 성장에 의한 연화현상과 납입자의 군집화(Clustering)는 관찰되었으나 그로 인한 절삭력 및 절삭에 필요한 에너지의 변화는 뚜렷하지 않았다.

A review on the softening of the fermented vegetables and the fruits (침채류와 과실의 연화현상에 관한 고찰)

  • 이희섭
    • Journal of the Korean Home Economics Association
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    • v.34 no.4
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    • pp.403-414
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    • 1996
  • The softening of the femented vegetables and the fruits was resulted from the degradation of pectin substances, cellulose, hemicellulose by polygalacturonase(PG), pectinesterase(PE), Cx-cellulase, $\beta$-galctosidase. The conversion of insoluble pectin to soluble pectin in cell wall-middle lamella was a major factor in the changes of firmness. Ca2+ was substantially increased firmness. However, Ca2+ could be removed from cell wall by chelating agents such as oxalic acid and citric acid. And Ca2+ was replaced with Na+ by ion exchange reaction. Ca2+ deficient tissue was vulnerable to attack by PG. Preheating treatment and Ca2+ addition is most effective in inhibiting the vegetable food softening and in increasing middle lamella-cell wall regidity, which PE activation by preheating treatment and Ca2+ addition could created more anionic carboxyl groups for cationic materials binding such as Ca2+ and chitosan and for polypectategel formation. Excessive demethylation by PE was associated with loosening of middle lamella cell wall components and softening.

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