• The Journal of the Petrological Society of Korea
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• v.14 no.3 s.41
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• pp.141-148
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• 2005

Lead isotopic compositions are analyzed from the sulfide minerals of the Yeonhwa, Janggun and Uljin deposits and from host limestone, intrusives, and basement rocks to reveal the source of Pb in these deposits. In the $^{206}Pb/^{204}Pb$ vs $^{207}Pb/^{204}Pb$ plot, Galenas from the Yeonhwa mine display relatively well defined positive linear array, similar to the Precambrian basement rocks of the Korean peninsula. A galena sample from the Uljin mine, Janggun limestone and the basement rocks also follow the variation of Yeonhwa mine. However, ore minerals from the Janggun mine, having relatively low $^{206}Pb/^{204}Pb$ values, reveal offset from such trend toward lower $^{207}Pb/^{204}Pb$ values. Considering the fact that Mesozoic igneous rocks and ores within the Gyeongsang basin display considerably lower $^{207}Pb/^{204}Pb$ values than basement rocks of the Korean peninsula, the deviation of Janggun ore minerals can be interpreted as to reflect mixing between leads from old continental crustal materials and from Mesozoic igneous rocks with more mantle signature. The lead of the Yeonhwa and Uljin mine, following trend of Precambrian basement rather well, seems to have been originated mostly from such basement. However, regarding that they occupy low $^{207}Pb/^{204}Pb$ side of the variation trend of the basement, the possibility of having some leads derived from the Mesozoic igneous rocks cannot be excluded.

• Proceedings of the KSEEG Conference
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• 2007.04a
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• pp.395-397
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• 2007

• Journal of the Mineralogical Society of Korea
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• v.7 no.2
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• pp.81-90
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• 1994

연화 광산 동점 및 묘봉 광체에서 산출되는 프라이버자이트는 후기 광화 시기에 방연석, 피라지라이트, 황철석, 자철석, 알라반다이트, 함망간, 자철석, 섬아연석, 황선석, 석영 등과 밀접하게 공존하고 있다. 화학조성을 보면 Ag가 최고 40.5 wt%까지 높은 함량을 보이고, Zn은 극소량 또는 microprobe의 측정 한계 이하이다. 어떤 입자들에서 Pb가 최고 1.70 wt% 함유되어 있다. 연화 프라이브자이트의 화학 조성상의 다소 고유한 특성은 Me12Sb4S13을 기준으로 할 때 S가 부족하고 Sb가 많이 포함되는 점이다.

• Economic and Environmental Geology
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• v.2 no.1
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• pp.81-82
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• 1969

• Economic and Environmental Geology
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• v.2 no.1
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• pp.82-90
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• 1969

• Economic and Environmental Geology
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• v.26 no.3
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• pp.279-287
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• 1993

In the zinc-lead (-silver) ores from the Yeonhwa 1 mine, stannite is widespread, though minor in amount It may be divided largely into two species on the basis of its chronological order during mineralization; i.e., stannite I formed in Stage I, and stannite II formed in Stage II. Also, the mineral may be classified into two types according to the difference of its associates; i.e., stannite 1 closely associated with sphalerite, and stannite 2 with galena. In general, the stannite 1 tends to predominate in the stannite I and the stannite 2 in the stannite II. The formation temperature and sulphur fugacity of stannite 1 deduced from stannite-sphalerite geothermometry are from 280 to $350^{\circ}C$ and from $10^{-11}$ to $10^{-8}$ atm.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.626-634
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• 2005

The objectives of this study was to assess pollution level and contamination status on tailings and soil in the vicinity of four disused metal mines in Kangwon province. As the result of total metal concentrations analysis, the pollution degree of tailings and soil decreased in the order of Wondong > Second Yeonhwa > Sinyemi ${\fallingdotseq}$ Sangdong mines. Total metal concentrations of mine tailings in this study were $1.2{\sim}78.2$ and $1.1{\sim}80.6$ times higher than those in the background soil and the tolerable levels suggested by Kloke, respectively. From these results, we found that tailings served as contamination source of nearby soil. According to sequential extraction of metals, large proportion of heavy metals in all mine tailings existed in the form of a residual fraction, and heavy metals in non-residual form was mainly associated with Fe-Mn oxide fraction and sulfidic-organic fraction. Fe-Mn oxide fraction and sulfidic-organic fraction of heavy metals may be released into and contaminated the nearby environment under the oxidation or reduction condition in long-term. In particular, the proportions of the exchangeable and carbonate fraction of Cd in mine tailings from Second Yeonhwa mine were relatively high. This suggests that Cd may be easily released into and contaminated the nearby environment in the near time. Concentrations of heavy metals in mine tailings and the nearby soil exceeded the standard (agricultural area) of Soil Environment Conservation Law. So it was thought that remediation for mine tailings and the nearby soil is needed. The pollution indices of the samples in this study were for higher than 1.0 and the pollution degree was very serious. Priority remediation site for these mines was Wondong. As Results of danger indices, it was showed that exchangeable form in Wondong and Fe-Mn oxide form in the rest mines should be removed preferentially.

• Economic and Environmental Geology
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• v.2 no.3
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• pp.47-57
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• 1969

The Yeonhwa Lead and Zinc Mine is located in northern part of Kyeongsang-Buk-Do, Korea, and is economically most important mine because it produces most part of the output of lead and zinc minerals in the country. Ore deposits of the mine are localized in the Pungchon Formation and several limestone seams of upper Myobong Formation in Cambrian Age. Ore solution ascended along the fractures of N-S, NE-SW or NW-SE trends and along slate and limestone boundary, and then replaced selectively limestone to make ore bodies. Skarn minerals are consisted of hedenbergite, diopside, and main sulfide mineral orebodies are composed of galena, zincblende, pyrrhotite, pyrite and a minor amounts of arsenopyrite and chalcopyrite. Metal ratio, ${\rho}_{Pb}={\frac{Pb(%)}{Pb(%)+Zn(%)}}{\times}100$, illustrates the zona I arrangements of some ore bodies. It will be inferred the flow trending of ore solution and the process reaction with adjacent country rocks. The sub-divided formations of the Pungchon limestone and Myobong slate are very useful as a criteria for detecting probable ore location. Rhodochrosite veins are good evidence for searching of ore location, especially on Pb-rich ore bodies.

• Journal of the Mineralogical Society of Korea
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• v.4 no.2
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• pp.141-146
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• 1991

Minerals of system Ag-Sb have been found in iead-zinc (-silver) ores from the Dongjeom and the Taebaeg ore deposits, which were formed at later stage of the Yeonhwa 1 mine mineralization. The Ag-Sb minerals are intergrown intimately with galena, pyrargyrite and alabandite. Their chemical compositions as determined by electron microprobe analyser show that they are chracterized by relatively high content of S, up to 5.89 atomic percent. Also the composition of the minerals may be separated into two: Ag3.89 Sb1.00-Ag7.19 Sb1.00 and Ag2.96 Sb1.00-Ag4.00 Sb1.00.

• Defense and Technology
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• no.2 s.276
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• pp.30-39
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• 2002

화공기술이란 연소와 폭발성을 갖는 단일 또는 복합 물질을 기제로 하여 제품을 사용 목적에 맞도록 제조와 응용하는 기술을 의미하며, 화약의 에너지 물질로서 제조된 다양한 제품을 화공품(Pyrotechnics)이라고 한다. 우리 주변에서 흔히 볼 수 있는 것은 산업용으로 성냥, 딱총약, 엽총화약, 연화, 광산용의 도화선, 도폭선, 각종 뇌관류 등이 있고, 군용으로는 발사화기와 로케트 추진기관의 점화계열, 탄두/탄약의 폭발계열, 신호탄, 연막, 조명탄 등을 들 수 있다.