• Title/Summary/Keyword: 연안 오염 퇴적물

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Adsorption of nitrate from contaminated sea water with activated dredged sediment (오염해수로부터 질산염의 제거를 위한 전처리 퇴적물의 흡착특성)

  • Song Young-Chae;Woo Jung-Hui;Jung Eun-Hye;Go Sung-Jung;Kim Dong-Geun
    • Journal of Navigation and Port Research
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    • v.29 no.6 s.102
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    • pp.589-593
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    • 2005
  • A laboratory study on the adsorption of nitrate in polluted coastal water using various materials including several types of dredged sediments(ST) and yellow c1ays(YC), which are activated by heat(HT), bioleaching for heavy metal removal(BL) and neutralization(NR) was performed. The equilibrium time of the adsorption for the sediment bioleached and treated by heat(BL-HT-ST) was only 17min which was faster than the sediment bioleached, neutralized and treated by heat(BL-NR-HT-S) (25min) or the sediment treated by the bioleaching process(BL -ST)(27min), but longer equilibrium times for yellow c1ay(YC) or heat treated yellow day(HT- YC) were required. The adsorption processes of nitrate in sea water for tested material could be described by Freundlich isotherm, but were significantly affected by surface characteristics of the materials. The adsorption capacities for raw sediment and heat treated sediment were 2.12 and 2.19mg NO3-N/g, respectively, which were higher than others, indicating that the sediment activated by heat could be used as a material for the improvement of nearshore water quality.

Distributions and Sources of Polycyclic Aromatic Hydrocarbons in the Tidal Flat Sediments from Incheon Coastal Area (인천연안 갯벌의 다환방향족탄화수소의 농도분포와 발생원 평가)

  • Park, Jung Hwan;Lee, Choong Dae;Kim, Jin Han
    • Journal of Wetlands Research
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    • v.15 no.4
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    • pp.441-451
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    • 2013
  • Samples for estimating concentrations of polycyclic aromatic hydrocargons(PAHs), total petroleum hydrocarbons(TPHs), and benzene-toluene-ethylbenzene-xylene(BTEX) were collected at the tidal flat sediments of 8 coastal sites in Incheon, at seventy-two sampling stations for the surface sediment and twenty-four stations for the sediment core, twice in the spring and fall in 2011. This study was performed to evaluate the distributions of seasonal and spatial concentrations of PAHs, TPHs, and BTEX in the tidal flat sediments. The source origin of PAHs were carried out. The total average concentration of PAHs in the tidal flat sediment was $95.62{\mu}g/kg$. The characteristic of PAHs concentration distributions was observed that the average concentration in the autumn was lower than that in the spring, and higher concentration in the sediment core than the surface sediment, and greater vertical concentration at the top rather than the bottom in the sediment core. The total average concentration of TPHs at all sampling sites was in the value of 46 mg/kg. The characteristic of the TPHs concentration distribution was observed that the average concentration in the fall was much higher than that in the spring, and higher concentration in the surface sediment than the sediment core. The possible source of PAHs inputs were mainly derived from both pyrogenic and petrogenic origin at the surface sediment at Janghwari site and the sediment cores of both Sorae and Okyeon sites, while the rest sites of study areas originated with pyrogenic combustion.

A Pilot Scale Biostimulation Study for In-situ Remediation of Organic Pollutants and PAHs contained in Coastal Sediment (연안 해역퇴적물에 함유된 유기오염물과 PAHs의 현장정화를 위한 파일럿 규모의 생물활성촉진연구)

  • Bae, Byung-Uk;Woo, Jung-Hui;Subha, Bakthavachallam;Song, Young-Chae
    • Journal of Navigation and Port Research
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    • v.40 no.6
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    • pp.441-450
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    • 2016
  • A pilot scale biostimulation experiment was performed under field conditions to degrade organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment. During the experiment, the seawater temperature around the sediment varied from $16.5^{\circ}C$ to $21^{\circ}C$, while the sediment pH was stable at 8.4-8.5. The experiment was conducted over a one year period with a control group and a sample group with a applied biostimulant composed of acetate, sulfate, and nitrate. Chemical oxygen demand decreased 39% in the control group and 79% in the sample group. Volatile solids were reduced from 15 to 7 g/kg in the control group and 2.5 g/kg in the sample group. Out of the 2-, 3- ,4- ,5-, and 6-rings of the 16 vital PAHs, the compound including naphthalene (2-ring), took 2 months to degrade completely, while the degradation efficiency was 55.6% in the control group during the same period. In the case of the 3-ring and 4-ring PAHs, complete degradation in the sample and 46% - 100% degradation in control was observed after one year of the experiment. The 5-ring and 6-ring PAHs were degraded to about 77%-100% in the sample group and 26%-87% in the control group during the one year of the experiment. The study results show that biostimulation is a very effective method to improve the degradation rate of organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment.

Experiments and Numerical Analysis on a System for Collecting Organic Sediment from Seabed (해저유기퇴적물 수거시스템의 실험 및 수치해석)

  • Kim, Do-Jung;Park, Je-Woong;Jeong, Uh-Chul;Kim, Seoung-Gun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.1
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    • pp.15-20
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    • 2008
  • Contaminated sediments are the actual cause for deterioration of coastal-ecosystem. So the developed countries have been in the process of making an effort to develop new techniques for monitoring and solving this problem since 1960. In this research, suction type pump dredging system of pilot size for collecting the filth from the seabed has been designed and manufactured that can prevent or minimize the secondary pollution by filth diffusion. For the practical use, the application possibility of the developed system has been checked through a system performance test. And, the evaluation of system performance according to the underwater body type has been carried out for system optimization by using CFD. The performance tests for checking the efficiency of sediment collecting system are done under two conditions i.e. when the system is non-operational and when the system is self-propelled. The results of this research showed the possibility of the development of dredging system to remove just the upper parts of filth from seabed.

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거제 북부해역의 저질환경 특성

  • 정우건;김용술;조상만
    • Proceedings of the Malacological Society of Korea Conference
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    • 2001.11a
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    • pp.39-40
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    • 2001
  • 연안과 천해의 저질은 그 상층 해수의 변화에 영향을 받으며, 또한 반대로 상층의 수질을 변화시키기도 한다. 저질은 지질학적 기원을 갖는 기부위에 상층의 물에서 가라앉는 부유현탁물질과 수중생물의 배설물, 생물의 사체 등의 유기질이 층을 이루면서 형성된다. 저질은 화학적, 생물적 변화나 물의 유동에 의한 영향을 받지만 변화속도가 비교적 작고, 상층 수질의 변화 결과를 누적적으로 받기 때문에 수질변화의 평균적 이력(履歷)을 간직하며, 수역의 오염의 진행경향이나 그 속도에 대해서 수질만으로는 알 수 없는 장기간의 영향에 대한 적산적(積算的)관점에서의 정보를 보유하고 있다. 이 조사해역은 굴을 비롯한 패류 양식장이 밀집분포하고 있는 해역이며, 진해만에서 수하식 양식장의 분포비중이 가장 큰 해역으로서 양식의 역사도 30년이 넘는다. 이 해역은 외해와의 해수교류가 원활하지 못하여 양식생물의 배설물과 양식장의 탈락물이 이 육지로부터 유입되는 오염부하물질과 더불어 그대로 해저에 퇴적되고 있는 곳이라고 할 수 있다. 이 연구는 양식장 저질의 유기오염의 수준을 평가하여 양식장 및 연안해역의 관리를 위한 자료로 제공하고자 하였다.

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Background Concentration and Contamination Assessment of Heavy Metals in Korean Coastal Sediments (한반도 연안 퇴적물의 중금속 배경농도 및 오염도 평가)

  • WOO, JUNSIK;LEE, HYOJIN;PARK, JONGKYU;PARK, KYOUNGKYU;CHO, DONGJIN;JANG, DONGJUN;PARK, SOJUNG;CHOI, MANSIK;YOO, JEONGKYU
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.1
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    • pp.64-78
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    • 2019
  • The background concentrations of heavy metals in Korean coastal sediments were estimated using heavy metal data for 495 sediments obtained from 'National Marine Ecosystem Survey (Coastal ecosystem) in 2016-2017' and the extent of contamination was assessed. Al, Cs, and Li are chosen as appropriate indicators for sediment grain size. In the relationships between heavy metal and indicators concentrations, the lowest slope data were selected through the outlier removal and residual analysis, and the background concentrations were presented as a linear regression line between metal and indicator. Comparing the previous studies for the background concentrations of heavy metals in Korean coastal sediments, concentration levels were generally consistent but those for As and Cd were presented for the first time, and the background concentration using Li as the indicator was presented for the first time.

새만금 갯벌의 중금속 분포 특성

  • 김종구;유선재;조은일;안욱성
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2002.10a
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    • pp.146-148
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    • 2002
  • 국내에서는 많은 간척사업이 이루어졌으며 이로 인한 환경에 미치는 영향을 아주크게 작용하고 있다. 연안 매립 및 간척사업으로 인한 환경오염 중에서도 부영양화나 중금속오염 문제가 중요한 요인으로 제기되었고, 대부분의 중금속은 환경중에서 지속성을 가지며 수계로 유입된 중금속은 퇴적물에 축적되거나 여러 과정을 거쳐 수중에 재용해 되기도 한다. 또한 먹이사슬을 거쳐 사람에게 다량 축적될 경우 독성을 일으키는 물질로써 세계 각국에서 일부 중금속에 대해서는 유해물질로 규정하여 규제하고 있으며, 우리나라에서도 일부 중금속 항목은 환경기준에 지정되어 있다. (중략)

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Heavy Metal Contamination in Sediments by Herbei Sprit Oil Spill (허베이 스피리트 원유 유출 사고에 의한 퇴적물의 중금속 오염)

  • Song, Yun Ho;Choi, Man Sik;Woo, Jun Sik;Sim, Won Joon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.2
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    • pp.70-79
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    • 2013
  • Since crude oil contains various pollutants including heavy metals, the environmental impact should be assessed for heavy metals as well as oil itself. In order to estimate the extent of heavy metal contamination, surface sediments were collected at the intertidal and coastal zone around the Herbei sprit oil spill area during December 2007 and January 2008. Organic carbon, sulfur and heavy metals were determined to assess heavy metal contamination in sediments. The crude oils contained C, S, V and Ni, but little toxic metals such as As, Cd, etc. From organic carbon content, the highest contaminated site was estimated that oils contributed to sediments up to 10%, and this site showed high V concentration. Potentially contaminated sediments by crude oil could be differentiated from unaffected sediments through V/Al and Ni/Al ratios, which can be used as indicators of oil contamination even after the oils were fully degraded.

A Two-dimensional Numerical Simulation of Cohesive Sediment Transport in the Mokpo Coastal Zone (목포해역의 점착성 퇴적물 이동에 관한 2차원 수치모의)

  • Choi, Jong-Hwa;Jung, Tae-Sung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.4
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    • pp.287-294
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    • 2012
  • Sedimentary environment in coastal zone has been changing due to a large number of coastal structures and continuous coastal development. As a result, the environment has been changing. In particular, the economic and environmental damage can occur due to cohesive sediment transport closely related with the fate of pollutants. Due to large sea wall construction the ebb dominance in the Mokpo coastal waters has been clearer. Cohesive sediment transport was simulated by the EFDC model. The simulated SS showed good agreements with the observed SS. From the sensitivity analysis of sediment parameters, we found out that the erosion rate, the critical shear stresses for erosion and deposition, and the settling velocity are important factors in cohesive sediment transport modeling.

해양 퇴적물 내 납의 흡/탈착 거동

  • 곽문용;박준형;신원식
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.248-251
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    • 2004
  • 일반적으로 유기오염 물질의 경우 sequestration 또는 aging 현상에 의해 탈착저항성을 띠게 되는 것으로 알려져 있다. 그러나 중금속의 경우 흡/탈착반응은 탈착저항성이 없는 가역적 반응이라는 보고가 있는 반면 홉/탈착 반응은 비가역적이며 탈착저항성이 존재한다는 보고도 있다. 본 연구에서는 해양 연안 퇴적물에 대한 납의 흡/탈착 실험을 통하여 탈착 저항성을 화인하고 연속추출 실험을 수행함으로써 탈착 저항성 부분의 크기를 규명하고자 하였다. 그리고 각기 다른 pH(4, 6)에서 흡착 실험을 수행함으로써 pH에 따른 흡착친화도를 규명하였다. 그 결과 퇴적물에 대한 납의 흡착량은 높은 pH(6)에서 더 많았고, 각 pH 범위에서 납은 탈착저항성을 가지는 것으로 나타났으며, 연속추출결과 Organic Material bound부분에 66% 정도가 흡착되어 있음을 알 수 있었다.

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