• Title/Summary/Keyword: 연속식 반응조

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제강분진을 반응촉매로 이용한 침출수의 연속산화처리공정

  • 강정우;장윤석;지원현;김성용;배범한;장윤영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.164-167
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    • 2001
  • 본 연구에서는 포항제철소에서 제철부산물로 발생되는 제강분진을 전처리 없이 산화촉매로 사용하여 김포 수도권 매립지의 침출수 처리공정에서 펜톤산화조에 유입되는 원수를 대상으 로 과산화수소를 이용한 연속식 산화처리 실험을 수행하였다. 먼저 회분식 실험결과를 바탕 으로 최적 반응조건에서 lab-scale 연속식 기초반응실험과 자체 설계.제작한 연속산화공정에서의 처리실험을 수행하였다. 또한 기존의 펜톤산화공정에서 Fe 공급원으로 사용되고 있는 FeSO$_4$.7($H_2O$)와의 반응성 비교실험도 수행하였다. 반응기간동안 일정 pH를 유지하기 위해 pH controller를 사용하였으며 침출수 수질은 CODcr로 나타내었다. 반응 pH 3.5, 체류시간 1 hr, 과산화수소 주입량 1,500mg/1에서 제강분진과 FeSO$_4$.7($H_2O$)를 각각 주입하여 수행한 연속처리 기초실험에서는 제강분진을 산화반응촉매로 사용한 경우에 침출수CODcr 처리율 62%, 과산화수소의 분해율 52%를 나타내었다. FeSO$_4$.7($H_2O$)를 산화반응 촉매로 사용한 경우에는 약 65-70%정도의 다소 높은 처리효율을 나타낸 반면에 과산화수소의 소비량은 제강분진의 경우보다 약 20%이상의 높은 값을 나타내었다. 연속산화공정 실험에서는 운전 3시간 이후에 유출수 중의 CODcr과 $H_2O$$_2$의 농도가 안정된 값을 나타내었다. 이 때 산화 반응조의 침출수 CODcr 제거효율은 약 43%이었으며, 처리수의 농도는 현재의 침출수 방류기준 이하로 나타났다. 결론적으로 침출수의 연속식 산화처리 실험결과, 처리효율과 경제성에서 제강분진의 산화촉매활용 공정의 개발 가능성이 매우 높은 것으로 나타났다.ell에 의해 완전분해 되었으며, 함께 존재시 TC는 Fe$^{\circ}$만으로는 분해가 되지 않았지만 cell에 의해 완전분해 되었으며, 함께 존재시 TCE분해에 저해작용을 미치는 것으로 나타났다.술의 첨가가 요구되고 있다. 따라서, 산성광산배수 오염지대에 대해 획일적으로 같은 처리방법을 채택하여 사용하는 것보다 각 지역 또는 광산산성폐수가 유출되어 나오는 광산폐기물의 특성 등을 고려하여 거기에 맞는 기술들을 복합적으로 또는 단독으로 사용하되 처리방법 채택 시 신중을 기할 것이 요망된다.정시에는 SeaWiFS 위성과 관련된 global algorithms 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서던지 NH$_{4}$$^{+}$의 경우 Dv값이 제일 작았다. 바. 본 연구의 목적중의 하나인 인체유해 중금속이온인 Hg(II), Cd(II)등이 NaCl같은 염화물

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갈치 채낚기의 연속식 자동 어구 어법 개발 2. 집어등의 수중 조도

  • 김고환;박용석;이창헌;정용진;서두옥
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2000.10a
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    • pp.21-22
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    • 2000
  • 생물의 특성 중 하나는 외부나 내부의 자극에 대하여 반응한다는 것이다. 이러한 환경의 변화를 감각기관에서 수용하여 그 환경의 변화에 적절하게 대응하는데 이러한 반응은 작게는 운동, 크게는 행동이라는 형태로 나타난다. 동물에 있어서 이와 같이 자극에 대하여 특이한 반응행동을 일으키는 성질들을 주성(Taxis)이라 한다. 주성에는 자극에 따라 주광성, 주촉성, 주류성, 주온성 등이 있으나 어업에 있어서 가장 광범위하게 이용하고 있는 것이 어류의 주광성이라 할 수 있다. (중략)

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Adaptive Control of Denitrification by the Extended Kalman Filter in a Sequencing Batch Reactor (확장형칼만필터에 의한 연속회분식반응조의 탈질 적응제어)

  • Kim, Dong Han
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.6
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    • pp.829-836
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    • 2006
  • The reaction rate of denitrification is primarily affected by the utilization of organics that are usually limited in the anoxic period in a sequencing batch reactor. It is necessary to add an extemal carbon source for sufficient denitrification. An adaptive model of state-space based on the extended Kalman filter is applied to manipulate the dosage rate of extemal carbon automatically. Control strategies for denitrification have been studied to improve control performance through simulations. The normal control strategy of the constant set-point results in the overdosage of external carbon and deterioration of water quality. To prevent the overdosage of external carbon, improved control strategies such as the constrained control action, variable set-point, and variable set-point after dissolved oxygen depletion are required. More stable control is obtained through the application of the variable set-point after dissolved oxygen depletion. The converging value of the estimated denitrification coefficient reflects conditions in the reactor.

Analysis of two-stage Continuous Culture System by Transient Response of Single-stage Continuous Culture System (일단 연속 생물반응기의 과도상태 거동을 이용한 이단 연속 생물반응기의 해석)

  • 박성훈;공인수
    • KSBB Journal
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    • v.7 no.4
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    • pp.308-316
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    • 1992
  • Two-stage continuous culture system has been studied intensively to maximize the productivity of a cloned gene product in unstable recombinant microorganism. As an effort to optimize the two-stage process, transient behavior of the second-stage was studied theoretically as well as experimentally using Escherichia coli Kl2$\delta$Hl$\delta$trp. A mathematical model describing the transient response to a step change in dilution rate was developed based on the assumption that the adaptation rate of cell growth is proportional to the available growth potential, which is defined as the difference in dilution rates between before and after shift-up. The kinetic parameters appearing in the model equations were the dimensionless step increase in growth rate($\alpha$) and the adaptation rate constant(k). These parameters were evaluated for various dilution rates and temperatures by washout method. This relatively simple adaptation model could predict the specific growth rate of the second-stage successfully. Advantage and disadvantage of the proposed model are also discussed.

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Relationship between Toxicity of Heavy Metals and Sludge Retention Time in Sequencing Batch Reactor Process (연속회분식반응조 공정에서 슬러지 체류시간과 중금속 독성의 관계)

  • Kim, Keum-Yong;Cho, Young-Cheol;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.3
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    • pp.283-288
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    • 2007
  • In order to elucidate the relationship between the sludge retention time(SRT) and the toxicity of heavy metals, such as copper (Cu), cadmium(Cd), and zinc(Zn), in sequencing batch reactor(SBR) process, IC50 was estimated with measuring of INT-dehydrogenase activity in variable SRTs. When the concentrations of heavy metals were increased, the activity of INT-dehydrogenase was gradually decreased indicating the heavy metals inhibit bacterial activity. Cu showed higher toxicity than Zn and Cd. $IC_{50}$ of Cu, Cd, and Zn ranged from $0.37\sim1.96$ mg/L, $15.4\sim16.9$ mg/L, and $9.70\sim23.4$ mg/L, respectively. The toxicity of Cu and Zn was reversely proportional to the length of SRT. It is probably caused by the increased concentration of extracellular polymeric substances in longer SRT which absorb heavy metals. Therefore, the operation of SBR with increased SRT is desirable in treatment of industrial wastewater containing heavy metals.

Development of a Continuous Electrolytic System for pH-control with Only One Discharge of Electrolytic Solution by Using Non-equilibrium Steady State Transfer of Ions across Ion Exchange Membranes (이온 교환막에서 이온의 비 평형 정상상태 이동을 이용한 단일 전해액의 배출만을 가지는 pH 조절용 연속식 전해 반응기 개발)

  • Kim Kwang-Wook;Lyu Je-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.101-109
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unused solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through other counter chamber with its pH being controlled as acid or base. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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Treatment of Corn Starch Wastewater Using an UASB Reactor (UASB 반응조를 이용한 옥수수 전분폐수의 처리)

  • Shin, Hang-Sik;Bae, Byung-Uk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.269-275
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    • 1993
  • The performance of Upflow Anaerobic Sludge Blanket(UASB) reactor for treatment of corn starch wastewater was investigated using continuous and batch experiment. Results showed that the corn starch wastewater had different characteristics in terms of biodegradability and methane potential, depending on the manufacturing precess. COD removal efficiencies were maintained over 70% up to the loading rate of 3.2 kg $COD/m^3{\cdot}day$ and the maximum gas production rate was about 55 l/day, equivalent to 3.5 l/day per liter of reactor volume, at the loading rate of 8.4 kg $COD/m^3{\cdot}day$. In the anaerobic serum bottle test(SBT) carried out along with continuous operation, the sludge activity was found to increase from 0.03 to 0.53 g $COD-CH_4/g\;VSS{\cdot}day$ as granular sludges were developed in 130 days operation. SBT gave valuable informations on the characteristics of wastewaters to be treated as well as on the sludge activity. The overall morphological characteristics of granular sludges cultivated on corn starch wastewaters were similar to those cultivated on various organic industrial wastewaters such as distillery and sugar.

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Development of a continuous electrolytic system with an ion exchange membrane for pH-control with only one discharge of electrolytic solution and its characteristics (단일 전해액 배출만을 가지는 pH조절용 연속식 이온 교환막 전해 시스템의 개발과 그 특성)

  • Kim Kwang-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.269-278
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unwanted solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through the other counter chamber with its pH being controlled. The internal circulation of the pH-adjustment reservoir solution through the anodic chamber in the case of using a cation exchange membrane and that through the cathodic chamber in the case of using an anion exchange membrane could make the solution discharged from the other counter chamber effectively acidic and basic, respectively. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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Design Parameters of Sequencing Batch Reactor treating ship sewage (연속 회분식 공정(SBR)을 이용한 선박 오 ${\cdot}$ 폐수처리 설계인자 도출)

  • Park, Sang-Ho;Kim, In-Soo
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.29 no.1
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    • pp.293-298
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    • 2005
  • Lab scale experimental study was carried out for SBR process, to investigate the effects of influent ship sewage organic compound removal and Bacillus sp. state on design parameters. This process was able to remove nitrogen and phosphorus as well as organic matter efficiently. More than 95% of chemical oxygen demand(COD) were removed. In addition, about 97% of total nitrogen (T-N) was reduced. The total phosphorus(T-P) reduction averaged 93%. The performance load of SBR process was shown to be 0.095kg ${\cdot}$ TOC/$m^{3}$ ${\cdot}$ day. The pH was decreased from 8.1 to 7.0 within 30 min and increased to 7.3 at the end of anoxic stage, and these phenomena were explained. The sluge produced in the SBR process is characterized by low generation rate (about 0.36kg ${\cdot}$ MLSS/kg ${\cdot}$ TOC) and excellent settleability. The number of Bacillus sp. in the SBR was 24.2%, indicating that Bacillus sp. was a predominant species in the reactor.

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