• Journal of the Korean Institute of Gas
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• v.26 no.5
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• pp.28-34
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• 2022

Since semiconductor factories are located in densely populated areas, safe handling of hazardous materials handled in the manufacturing process is of utmost importance. In particular, the types of hazardous substances discharged after handling in the semiconductor manufacturing process are very diverse, and the treatment methods such as combustion, absorption and adsorption methods for each material are very complicated. Therefore, in recent semiconductor exhaust treatment processes, two or more treatment methods are applied to one treatment facility, and unexpected accidents occur due to the application of such a complex treatment method. In this study, the cause of accidents in treatment facilities that applied both the scrubber method and the electrostatic precipitation method, which are recent accident cases, are identified, and preventive measures are suggested to find out the points to be noted when applying the complex treatment method.

• Journal of Appropriate Technology
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• v.5 no.2
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• pp.118-125
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• 2019

Climate change is one part of 17 Sustainable Development Goals (SDGs). According to the Fifth Assessment Report by the Inter- governmental Panel on Climate Change(IPCC) published in 2014, global warming is caused by greenhouse gas (GHG) emissions. The most important GHG is carbon dioxide (CO₂), which is released by the burning of fossil fuels and, to a lesser extent, by land use practices, followed by nitrous oxide and methane. IPCC predicts that global temperatures will rise 3.7℃ and sea level will rise 0.63 m by 2099 in the case of no strong restraint. According to the report, we can expect a massive species extinctions, changes in storm and drought cycles, altered ocean circulation, and redistribution of vegetation by global warming. However, climate changes, especially global warming, are the largest potential threat to human health and the source of a number of diseases globally. If climate changes are continued uncontrolled, human health will be adversely affected by the accelerating climate change and the natural disaster induced by climate change. It means we will face more serious conditions of injury, disease, and death related to natural disasters such as flood, drought, heat waves, malnutrition, more allergy, air pollution and climate change related infections related to morbidity and mortality. This review emphasizes on the relationship between global climate changes and human health and provides some suggestions for improvement.

• Clean Technology
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• v.23 no.1
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• pp.80-89
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• 2017

The bubbling fluidized bed (BFB) reactor with a diameter of 0.1 m and a height of 1.2 m was used for experimental study of co-firing and emission characteristics fueled by sewage sludge (SS) and wood pellet (WP). The facility consists of a fluidized bed reactor, feeding system, cyclone, condenser and gas analyzer, The mean particle diameter and minimum fluidization velocity are $460{\mu}m$ and $0.21ms^{-1}$ respectively. SS produced from Korea and WP from Canada were examined. The various mixing ratios of WP were 20, 50, and 80% based on HHV. The equivalence ratio of 1.65, reactor temperature of $800^{\circ}C$, air flow rate of $100Lmin^{-1}$, and fluidization number of 4 were fixed in the BFB experiment. In TGA, the range of combustion temperature of SS was wider than that of WP. It represents that the combustibility of WP is higher than that of SS. The BFB reactor temperature was maintained between 800 and $900^{\circ}C$. CO emission of SS was high because of lower combustibility. $NO_X$ and $SO_X$ formation of SS were higher than that of WP since high nitrogen and sulfur contents of SS. CO, $NO_X$, and $SO_X$ formation were suppressed as the mixing ratio of WP was increased. The slagging and fouling tendencies show high in all test conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.106.2-106.2
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• 2010

동식물성 기름과 메탄올의 전이에스테르화 반응에 의해 생산되는 바이오디젤은 환경친화성과 지속가능성이 인정됨에 따라 그 생산량이 급격히 증가하고 있어 대두유, 유채유, 팜유 등의 원료유 부족과 가격 상승, 수급 불안정 등의 문제가 대두되고 있다. 이를 해결하기 위한 방안으로 유리지방산 함량이 높은 저가유지 자원(폐식용유, 폐돈지, 폐우지, soapstock, trapped grease)과 새로운 오일 작물을 이용한 생산 기술 연구가 활발히 진행되고 있다. 본 연구에서는 비활용 해외 열대작물 씨앗에서 착유한 식물성 오일을 정제하여 바이오디젤 원료유를 생산하는 과정에서 발생하는 폐기물(폐유, 폐수)의 경제적 처리 방안으로 유화유 제조 원료(벙커C유, 물)와 유화유 제조 첨가제(무기계, 유기계)로 활용 가능성을 검토하였다. 열대작물 오일의 물성 분석 결과 고형물, 수분, 인지질(phospholipid), 유리지방산(free fatty acid) 함량이 기존 원료유보다 매우 높게 나타났다. 인지질은 바이오디젤 제조 반응후 에스테르와 글리세린의 층분리를 방해하고 유리지방산은 염기촉매와 결합하여 지방산염을 생성해 생산 수율을 감소시킨다. 고형물과 수분 역시 촉매반응에 악영향을 가지나 여과와 감압증발에 의해 쉽게 제거가 가능하다. 유리지방산은 산촉매 에스테르화 반응에 의해 제거가 가능하다. 인지질은 탈검(degumming) 과정을 통해 제거하며 탈검은 수용성 탈검, 산 탈검, 세정 공정으로 구성된다. 착유한 원료유의 고형물을 제거 후 물과 수세하여 수용성 인지질을 수화하여 층 분리해 제거하고 상층의 오일은 추가적인 산 탈검을 수행한다. 그 뒤 세정을 통해 사용된 탈검제인 산과 추가적으로 수화된 인지질을 제거하게 된다. 이러한 3단계의 탈검 과정에서 하층으로 오일과 물이 폐기물로서 배출되며 본 연구에서는 배출 폐기물을 다시 층분리하여 오일층과 물 층으로 구분하여 유화유 제조에 사용되는 벙커C유, 물, 그리고 기존 유기계 및 무기계 유화제의 대체 가능성을 조사하였다. 유화 연료유는 기름과 물을 균일한 분산상으로 혼합한 연료유로 연소시 오일계 성분의 미연분을 감소시켜 연료 효율 제고와 배출가스 성상을 개선하기 위해 개발되어 왔다. 본 발표에서는 다양한 종류의 상용 첨가제 및 바이오디젤 원료유 생산 폐기물을 활용해 유화 연료유를 제조하였으며 각 유화유의 장시간의 상(phase) 안정성을 비교하였다. 바이오 폐기물 중에는 천연 계면활성제(surfactant)인 인지질이 다량 함유되어 있어 기존의 무기계 및 유기계 유화제보다 상 안정성이 우수하게 나타났으며 바이오디젤 원료유 생산 공정의 폐기물인 폐유과 폐수의 활용이 가능한 것으로 나타났다.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.89-96
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• 2015

Recently, much research has been put into finding the causes and solutions of slagging/fouling problems that occur at the end of the boiler. This slagging/fouling, caused by low-rank coal's ash, disturbs the thermal power and greatly reduces efficiency. In environmental aspects, such as NOx pollution, governments have been implementing restrictions on the quantity of emission gases that can be released into the atmosphere. To solve these problems, research on Ash Free Coal (AFC), which eliminates ash from low-rank coal, is in progress. AFC has advantages over similar high-rank coals because it increases the heating value of the low grade coal, reduces the contaminants that are emitted, and decreases slagging/fouling problems. In this study, using a DTF, the changes of NOx emissions, unburned carbon, and the characteristics of ash deposition were identified. KCH raw coal, AFC extracted from KCH, residue coal, Glencore, and Mixed Coal (Glencore 85wt% and residue coal 15wt%) were studied. Results showed that AFC had a significantly lower emission of NOx compared to that of the raw coal and residue coal. Also, the residue coal showed a higher reactivity compared to raw coal. And finally, In the case of the residue coal and mixed coal, they showed a lower ash deposition than that of low-rank coal.

• Journal of the Korean Society of Marine Environment & Safety
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• v.19 no.5
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• pp.525-530
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• 2013

In this study, the generator engine of training ship M/S "HAE RIM" of Kunsan National University which is being operated for 20 years was used in the experiment. The experiment was carried out under the engine speed of 1200rpm, then the load was varied 30 kW intervals from 0 to 90 kW and the injection timing was varied $2^{\circ}$CA intervals from BTDC $19^{\circ}$ to $23^{\circ}$CA. In the case of advancing fuel injection timing from BTDC $21^{\circ}$CA to $23^{\circ}$CA, specific fuel consumption is decreased by 1.37%, NOx is increased by 11.59 %, soot is decreased by 23.5 % and $SO_2$ is decreased by 2.8 %. Accoring to the analysis of effects of fuel injection timing on combustion & exhaust emissions characteristics on an old marine diesel engine, it is proved that the optimum fuel injection timing is BTDC $23^{\circ}$ which is $2^{\circ}$ faster than that of original injection timing.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.521-527
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• 2007

To investigate the relationship between PCB sources and concentration level in soil, PCBs concentration of 8 soil samples around Shiwa industrial complex were measured. The concentration of PCBs in soil samples were ranged from 2.43 to 274 ng/g dry (0.116 to 60.5 pg WHO-TEQ/g dry) md off-gas were ranged from 48.6 to $2872ng/m^3(0.00150\sim15.2ng\;WHO-TEQ/m^3)$; these are similar levels with results of previous study in Korea. The homologue patterns in soil samples were varied from sample to sample, but isomer patterns were very similar with each other. The two principal components were extracted by Principal Component Analysis(PCA) of 8 soil samples and cumulative factor loading was 95.7%. As the result of PCA, it could be expected that PCBs in soil samples of this study were more affected by PCB products than combustion process and mostly affected by already-known sources.

• Journal of Korean Tunnelling and Underground Space Association
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• v.23 no.6
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• pp.439-449
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• 2021

The recent reduction in greenhouse gases, interest in environmental pollution such as low-carbon emission policies is increasing. Accordingly, the penetration rate of eco-friendly vehicles, including hydrogen battery vehicles capable of reducing carbon emission, is increasing, and thus it is required for disaster prevention and safety-related measures. In this study, the degree of risk for the concentration distribution of hydrogen when leaking hydrogen fuel vehicles according to ventilation conditions was analyzed through numerical analysis, limited to places in parking lots. As a result, when only one hydrogen tank was released, the combustible volume ratio of hydrogen in the underground parking lot was up to 8.6%, and as ventilation continued, the volume ratio of combustible hydrogen decreased to less than 1% after 150 seconds, indicating that mechanical ventilation is essential. In the case of simultaneous release or stage release of three hydrogen tanks, the final combustible volume ratio of hydrogen is similar, but the increase in the combustible volume ratio of hydrogen in the early stage of release is low, and further research is expected.

• Clean Technology
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• v.7 no.1
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• pp.51-63
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• 2001

In this study, PSA, known as the most economic process, was used to recover $CO_2$ from the power-plant flue gas. Activated carbon and zeolite molecular sieve 13X were used as adsorbent. Activated carbon has been deemed inadequated adsorbent for separating $CO_2$ from the flue gas. However, highly concentrated $CO_2$ could be obtained as a product on the activated carbon adsorbent using the new operating cycle modifying the rinse step. Also, the recovery of $CO_2$ was improved using double-layered adsorption column packed with the activated carbon and the zeolite 13X simultaneously. Adsorption column was filled with the activated carbon in the feed-end side, and the zeolite 13X in the product-end side. The recovery of $CO_2$ increased about 40% with only 25% zeolite, and increased 67% with 50% zeolite at the experimental conditions of 13% $CO_2$ concentration, 10 SLPM flow rate and 2.2 atm adsorption pressure.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.