• 제목/요약/키워드: 연소법

검색결과 743건 처리시간 0.03초

GNP 방식으로 제조한 ZnO : Zn의 산소분압에 따른 분말특성 및 형광특성 (Properties of Powder and Phosphor as function of ZnO : Zn Oxygen Partial Pressure Prepared by Glycine Nitrate Process)

  • 최우성;박성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1520-1522
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    • 1999
  • 저 전압용 형광체는 최근에 활발히 연구가 진행되고 있으며 가장 대표적인 형광체가 ZnO : Zn 녹색 형광체이다. ZnO : Zn 형광체는 자체발광형 형광체로써 ZnO을 환원분위기 하에서 열처리를 함으로써 얻을 수 있다. 본 연구에서는 자발착화 연소반응법(Glycine Nitrate Process)을 이용하여 ZnO : Zn 분말을 합성하고 형광특성 및 분말특성을 알아보았다. 출발물질로는 Zn Nitrate와 Glycine을 이용하였고 자발연소 반응이 발생하는데 적절한 글리신의 양을 확인하기 위해서 글리신과 양이온의 비를 변화시키며 ZnO를 합성하였다. 그리고 Zn Excess가 생겨난 양과 그에 따른 형광특성을 관찰하기 위해 $N_2$ 분위기에서 각기 $500^{\circ}C,\;750^{\circ}C,\;950^{\circ}C$의 온도에서 열처리를 행하였다. 제조된 ZnO 분말의 입자형태와 결정상태는 SEM과 XRD를 이용하여 분석하였고 TG-DTA를 측정하여 열처리 온도에 따른 질량감소(ZR excess)를 관찰하였다. 또 Particle size analyzer로 분말의 크기를 알아보았고 형광체로써의 발광특성을 살펴보기 위해 PL을 이용하여 발광피크를 관찰하였다.

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CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정 (I) -연료/공기 혼합정도가 위상별 온도에 미치는 영향- (Phase-Resolved CARS Temperature Measurement in a Lean Premixed Gas Turbine Combustor (I) -Effect of Equivalence Ratio on Phase-Resolved Gas Temperature-)

  • 이종호;전충환;박철웅;한재원;장영준
    • 대한기계학회논문집B
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    • 제28권10호
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    • pp.1184-1192
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    • 2004
  • Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane gas. The objective of this study was to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. CARS temperature measurements were made at several spatial locations under lean premixed conditions to get the information on temperature field within the combustor. Also the effect of incomplete fuel-air mixing on phase-resolved temperature fluctuation was investigated. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. Temperature PDFs gave an insight on the flame behavior. And strong correlation between phase-resolved temperature profile and pressure cycle was observed. Results of the phase-resolved high temperature gave an additional information on the perturbation of equivalence ratio at flame as well as the effect of mixing quality on NOx emission characteristics.

시간지연 모델을 이용한 비선형 연소불안정 해석기법 연구 (Numerical Analysis of Nonlinear Combustion Instability Using Pressure-Sensitive Time Lag Hypothesis)

  • 박태선;김성구
    • 대한기계학회논문집B
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    • 제30권7호
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    • pp.671-681
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    • 2006
  • This study focuses on the development of numerical procedure to analyze the nonlinear combustion instabilities in liquid rocket engine. Nonlinear behaviors of acoustic instabilities are characterized by the existence of limit cycle in linearly unstable engines and nonlinear or triggering instability in linearly stable engines. To discretize convective fluxes with high accuracy and robustness, approximated Riemann solver based on characteristics and Euler-characteristic boundary conditions are employed. The present procedure predicts well the transition processes from initial harmonic pressure disturbance to N-like steep-fronted shock wave in a resonant pipe. Longitudinal pressure oscillations within the SSME(Space Shuttle Main Engine) engine have been analyzed using the pressure-sensitive time lag model to account for unsteady combustion response. It is observed that the pressure oscillations reach a limit cycle which is independent of the characteristics of the initial disturbances and depends only on combustion parameters and operating conditions.

액체로켓엔진을 이용한 Graphite 노즐의 삭마 거동 연구 (A Study on Ablation Behavior of Graphite Nozzle using Liquid Rocket Engine)

  • 조남춘;박희호;금영탁
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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    • pp.119-122
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    • 2005
  • 고온과 고속의 열악한 환경 속에서 발생하는 비행체의 삭마현상은 일반적으로 상변화를 수반하는 유체의 유동, 에너지 전달, 질량전달, 화학반응이 수반되기 때문에 해석과정이 복잡하다. 본 연구에서는 액체로켓엔진의 흑연노즐에 대하여 1차원적으로 삭마현상을 수치해석하고, 실험을 통하여 이를 비교 검토하였다. 낮은 연소압력과 산화제/연료비에서는 삭마가 거의 이루어지지 않았으며, 연소압력과 혼합비가 낮은 경우에는 해석결과의 신뢰도는 낮고 정상작동 구간에서의 해석결과와 실험결과가 차이가 많은 것으로 보아 화학적 삭마 외에 기계적 삭마도 상당하다.

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정적연소기에서 점화에너지와 점화장치가 화염전파속도에 미치는 영향에 관한 연구 (A Study on the Effects of Ignition Energy and Systems on the Flame Propagation in a Constant Volume Combustion Chamber)

  • 송정훈;서영호;선우명호
    • 한국자동차공학회논문집
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    • 제9권1호
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    • pp.45-56
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    • 2001
  • A constant volume combustion chamber is employed to investigate the initial flame kernel development and flame propagation of gasoline-air mixtures with various ignition systems, ignition energy and spark plug electrodes. To do this research, four ignition systems are designed and manufactured, and the ignition energy is controlled by varying the dwell time. Several kinds of spark plugs are also made to analyze the effects of electrodes on flame kernel development. The velocity of flame propagation is measured by the laser deflection method. The output laser beam from He-Ne laser is divided into three parallel beams by a beam splitter. The splitted beams pass through the combustion chamber. They are deflected when contacted with flame front, and the voltage signals from photodiodes change due to deflection. The results show that higher ignition energy raises the flame propagation speed especially under the fuel lean operation. The wider electrode gap, smaller electrode diameter and sharper electrode tip make the speed of the initial flame propagation faster. The speed of the initial flame propagation is affected by electrode material as well. Electrode material with lower melting temperature help the initial flame propagation.

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상호상관 PIV를 이용한 예혼합 분무화염의 계측에 관한 연구 (A Study on Measurement of Premixed Spray Flame using Cross-correlation PIV)

  • 양영준;김봉환
    • 에너지공학
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    • 제14권4호
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    • pp.259-267
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    • 2005
  • 예혼합 분무화염의 상세한 연구기구를 관찰하기 위하여 예혼합 분무화염 중의 분무단면상의 확대촬영과 또한 연소시의 순간적 이차원 유동장을 얻기 위해 미소시간차를 가진 2연속 분무단면 화상에 대해 상호 상관 PIV를 적용하였다. PIV에 통상 사용되어지는 펄스 레이저가 아닌 연속발진 레이저를 PIV에 적용하는 기법 등을 나타내었다. 또한 통계적 PIV 해석법을 이용하여 얻은 상호상관 PIV의 결과를 PDA에 의해 측정된 결과와 비교하여, 상호상관 PIV는 PDA의 계측에 의한 결과와 잘 일치한다는 결론에 이르렀다. 연속발진 레이저를 이용한 상호상관 PIV를 예혼합 분무화염에 적용하여 본 연구에서 적용한 기법이 분무화염의 구조를 관찰하는데 매우 유용함을 검증하였다.

중형 엔진 터보차져의 원심압축기에 관한 공력학적 3차원 형상 및 구동용 연소기 설계 (Aerodynamic Three Dimensional Geometry and Combustor Design for the Compressor of the Medium Speed Diesel Engine Turbocharger)

  • 류승협;갈상학;하지수;김승국;김홍원
    • 한국유체기계학회 논문집
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    • 제9권2호
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    • pp.30-38
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    • 2006
  • An aerodynamic design for centrifugal compressor which was applied to medium speed diesel engine has been done. First of all, exact compressor specifications must be defined by accurate engine system matching. This matching program has been developed. Using the meanline prediction method, geometric design and performance curves for compressor were established and verified by comparing three dimensional viscous CFD results. The deviation at the design point was about 2.3%. Combustor has been designed and manufactured for the performance test of medium speed diesel engine turbocharger. Fuel nozzle of combustor was designed and its characteristics was analyzed by PIV and PDPA test equipment. Through these results, spray characteristics were studied and flow coefficient equation was deduced.

졸겔 연소법에 의한 nano crystalline ITO제작 및 특성 (Synthesis of nano porous indium tin oxide by sol-gel combustion hybrid method)

  • 정기영;곽동주;성열문;박차수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2009년도 제40회 하계학술대회
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    • pp.1328_1329
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    • 2009
  • Nano porous indium tin oxide (ITO) powder was synthesized employing a new route sol-gel combustion hybrid method using Ketjen Black as a fuel. The nano porous ITO powder was composed of $SnCl_4$-98.0% and $In(NO_3)_3{\cdot}XH_2O$-99.999%, produce with a $NH_4OH$ with sol-gel method as a catalyst [1,2]. Crystal structures were examined by powder X-ray diffraction (XRD), and those results show shaper intensity peak at $25.6^{\circ}(2{\Theta})$ of $SnO_2$ by increased sintering temperature. A particle morphology as well as crystal size was investigated by scanning electron microscopy(FE-SEM), and the size of the nano porous powder was found to be in the range of 20~30nm. ITO films could controlled by nano porous powder at various sintering temperature in this paper[3,4]. The sol-gel combustion method was offered simple and effective route for the synthesis of nano porous ITO powder[5].

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이상 회체가스 가중합산모델을 적용한 미분탄 연소의 수치적 연구 (Numerical Study on Pulverized Coal Combustion Applying Two-Phase WSGGM)

  • 유명종;강신재;백승욱
    • 대한기계학회논문집B
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    • 제24권10호
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    • pp.1368-1379
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    • 2000
  • A numerical study on swirling pulverized coal combustion in an axisymmetric enclosure is carried out by applying the 2-phase weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard and RNG k-${\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase. The eddy-dissipation model is employed for the reaction rate for gaseous mixture, and the single-step and two-step first-order reaction model for the devolatilization process for coal. Special attention is given to establish the thermal boundary conditions on radiative transfer equation By comparing the numerical results with experimental ones, the radiation model used here is confirmed and found to provide an alternative for simulating the radiative transfer.

전통사찰 문화재의 화재안전 관리방안에 관한 고찰 (Fire Safety Administration Way of Tradition Buddhist Temple Cultural Heritage)

  • 신민섭;공하성
    • 보존과학회지
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    • 제23권
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    • pp.119-124
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    • 2008
  • 우리나라의 전통 사찰은 대부분 목조로 되어 있고 국가 중요 전통사찰의 건축 구조는 대부분이 목재로서 연소성이 높기 때문에 일단 착화되면 빠른 속도로 화재가 전파되고 산중에 있는 지리적인 특성으로 인해 효과적으로 화재를 진압하는데 어려운 문제점을 가지고 있다. 본 논문에서는 전통사찰 문화재의 화재안전관리 개선방안으로 법 제도적인 측면, 건축방화적인측면, 재난 방재 기본 시스템구축 및 유관기관 합동점검, 훈련 등 예방활동 강화를 제시하였다.

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